Hydrologic inferences from ring widths of flood-damaged trees,Potomac River,Maryland

Year-to-year variability in the ring widths of trees on flood plains along two reaches of the Potomac River near Washington, D.C., seems in large part to be related to differences in flood-flow regimes. Trees directly exposed to high flood velocities are damaged more often than sheltered trees and thus exhibit more variable ring-width patterns. The ring-width variability of unsheltered trees on low levels of flood plains is greater than that of trees on high levels, indicating that variability values are positively correlated with flood frequency. Sheltered trees, however, have less variable ring-width patterns than those of unsheltered trees, and variability is not correlated with flood frequency. As a result, ring-width variations may be used to estimate the probability of flood damage along local channel reaches of a stream. Growth responses after hydrologic catastrophies in 1948 and 1972 indicate that rings of flood-plain trees can be used to document the occurrence and crest altitude of high-magnitude floods.     

Untersuchungen am Rhein von schaffhausen bis kaiserstuhl 1938–1939 und 1940–1941

Ohne Zusammenfassung     

Hydrogeological and hydrochemical characterization of two karstic discharge areas in San Luis Potosí, Mexico

Two karstic discharge areas, Río Verde (RV) and Ciénega de Cabezas (CC), located in a distance of 80 km to each other are chosen to determine the influence of local variations in geology and climatic condition on water chemistry and to examine if the groundwater, supplying the discharge areas, undergoes the same evolution and has a common source. Both study areas are situated on the carbonate platform Valles-San Luis Potosí and comprise a similar geological setting, but despite of their spatial vicinity the climate is semiarid in RV and humid in CC presenting an important factor on the amount of discharge and the concentrations of ions in the discharge. The investigation encompasses discharge, hydrochemical and physico-chemical parameter evaluations as well as the determination of saturation indices, hydrochemical modelling and water type characterization of surface water samples to derive knowledge of the groundwater systems. Scatterplots and saturation indices were used to proof the influence of lithological variability. Both study areas represent normal alkaline water, marked by high concentrations of calcium and magnesium with varying concentrations of bicarbonate and sulphate. In RV, the water interacts with dolomite rocks and gypsum layers, whereas in CC the dolomite content is depleted and the influence of limestone rocks increases. The climatic impact on the groundwater in RV is noticeable by the increase in ionic concentrations due to higher evaporation. In CC the higher amount of precipitation dilutes the groundwater and causes decreasing ionic concentrations.     

Determination of zircon/melt trace element partition coefficients from SIMS analysis of melt inclusions in zircon

Partition coefficients (^zircon/meltD_M) for rare earth elements (REE) (La, Ce, Nd, Sm, Dy, Er and Yb) and other trace elements (Ba, Rb, B, Sr, Ti, Y and Nb) between zircon and melt have been calculated from secondary ion mass spectrometric (SIMS) analyses of zircon/melt inclusion pairs. The melt inclusion-mineral (MIM) technique shows that D_REE increase in compatibility with increasing atomic number, similar to results of previous studies. However, D_REE determined using the MIM technique are, in general, lower than previously reported values. Calculated D_REE indicate that light REE with atomic numbers less than Sm are incompatible in zircon and become more incompatible with decreasing atomic number. This behavior is in contrast to most previously published results which indicate D > 1 and define a flat partitioning pattern for elements from La through Sm. The partition coefficients for the heavy REE determined using the MIM technique are lower than previously published results by factors of ≈15 to 20 but follow a similar trend. These differences are thought to reflect the effects of mineral and/or glass contaminants in samples from earlier studies which employed bulk analysis techniques.D_REE determined using the MIM technique agree well with values predicted using the equations of Brice (1975), which are based on the size and elasticity of crystallographic sites. The presence of Ce⁴⁺ in the melt results in elevated D_Ce compared to neighboring REE due to the similar valence and size of Ce⁴⁺ and Zr⁴⁺. Predicted ^zircon/meltD values for Ce⁴⁺ and Ce³⁺ indicate that the Ce⁴⁺/Ce³⁺ ratios of the melt ranged from about 10⁻³ to 10⁻². Partition coefficients for other trace elements determined in this study increase in compatibility in the order Ba < Rb < B < Sr < Ti < Y < Nb, with Ba, Rb, B and Sr showing incompatible behavior (D_M < 1.0), and Ti, Y and Nb showing compatible behavior (D_M > 1.0).The effect of partition coefficients on melt evolution during petrogenetic modeling was examined using partition coefficients determined in this study and compared to trends obtained using published partition coefficients. The lower D_REE determined in this study result in smaller REE bulk distribution coefficients, for a given mineral assemblage, compared to those calculated using previously reported values. As an example, fractional crystallization of an assemblage composed of 35% hornblende, 64.5% plagioclase and 0.5% zircon produces a melt that becomes increasingly more enriched in Yb using the D_Yb from this study. Using D_Yb from Fujimaki (1986) results in a melt that becomes progressively depleted in Yb during crystallization.