40Ar/39Ar ages of blueschist facies pelitic schists from Qingshuigou in the Northern Qilian Mountains, western China

Abstract   Pelitic schists from Qingshuigou in the Northern Qilian Mountains of China contain mainly glaucophane, garnet, white mica, clinozoisite, chlorite and piemontite. Isotopic age dating of these schists provides new constraints on the formation of the high-grade blueschists at Qingshuigou. White mica ⁴⁰Ar/³⁹Ar ages range from 442.1 to 447.5 Ma (total fusion age of single grain) and from 445.7 to 453.9 Ma (integrated age of white mica concentrates). These ages (442.1–453.9 Ma) represent the peak metamorphic ages or cooling ages of the blueschists during exhumation shortly after peak metamorphism. The ⁴⁰Ar/³⁹Ar dates in the present study are similar to ages previously reported for eclogites and blueschists in the area; this suggests that both the eclogites and pelitic sediments underwent high-grade metamorphism during the same subduction event. From this chronological evidence and the presence of well-developed Silurian remnant-sea flysch and Devonian molasse, it is concluded that the Northern Qilian Ocean had closed by the end of the Ordovician, and rapid orogenic uplift followed in the Devonian.     

Tidal Winds on Titan Caused by Saturn

The influence of Saturn's gravitational tide on the atmosphere of Titan is investigated by means of a three-dimensional general circulation model. Titan's orbital eccentricity of 0.0292 gives rise to time-dependent radial and librational tide whose potential circles eastward on Titan. Unlike atmospheric tides on terrestrial planets, Saturn's tide on Titan has a large impact on the dynamic meteorology down to the surface. The surface pressure oscillates by up to 1.5 hPa through the orbit. Near the surface the tidal wind dominates the atmospheric flow and exhibits strong temporal and spatial variation. The superposition of the annually present, thermally forced latitudinal pressure gradient and tidally caused pressure variation produces a unique wind pattern near the surface characterized by equatorward flow and high-latitude whirls. At higher levels the tidal wind manifests itself as eastward traveling planetary-scale wave of wavenumber 2 superposed on the background wind. In general tidal winds are more significant in the troposphere, where other forcing mechanisms are weak. Meridional tidal winds become as fast as 5 m s⁻¹ in the troposphere and change direction periodically through the orbit and along the parallel of latitude. Except in the lower troposphere, zonal winds always remain prograde because the tidal wind amplitude is usually smaller than the mean zonal wind. The tide also has a large impact on the mean zonal circulation in the stratosphere. A meridional drift of the descending Huygens Probe in the troposphere would be the easiest way to verify the tidal wind on Titan, but more complete observations of tropospheric wind and surface pressure by a future mission would be required to unveil the complete details of the tidal wind.     

Pitch angle scattering of solar particles: Comparison of ‘particle’ and ‘field’ approach

In the quasi-linear theory of pitch angle scattering the power spectrum of magnetic field fluctuations is related to the shape of the pitch angle diffusion coefficient D(), the absolute value of the mean free path , and the rigidity dependence of the mean free path (R). We discuss these relations in detail during the solar particle event of 11 April, 1978 which was observed on HELIOS-2 at a distance of 0.49 AU from the Sun. Magnetic field measurements obtained during the time of the event are used as a basis for the layer model in which the method of particle trajectories in an actually measured field is used to simulate pitch angle diffusion. The values of D() and based on the trajectory simulation for 100 MeV protons (field approach) are compared with results obtained from solar proton data (particle approach) and with predictions from quasi-linear theory based on the additional assumption of the slab model for magnetic field fluctuations (QLT approach). The time of the event is characterized by a high level of field fluctuations, the observed mean free path of about 0.03 AU for 100 MeV protons is smaller than the average value near 1 AU. Results from the field and particle approaches agree surprisingly well. The remaining difference in the mean free path of about a factor of 2 could be due to tangential discontinuities which are measured by the magnetometer, but not seen by the real particles traveling along the average field. The results from the field and QLT approaches based on the same set of magnetic field measurements differ by about a factor of 4. One of the reasons for this discrepancy is that the conditions for resonance scattering are only marginally valid. In addition, the wave vectors representing Alfvén-type fluctuations may not be totally field aligned. This deviation from the slab model would cause an increase of the theoretically predicted mean free path and lead to better agreement with the other two approaches.     

A study of lignin degradation in leaf and needle litter using C-labelled tetramethylammonium hydroxide (TMAH) thermochemolysis: Comparison with CuO oxidation and van Soest methods

We studied the degradation of lignin in leaf and needle litter of ash, beech, maple, pine and spruce using ¹³C-labelled tetramethylammonium hydroxide (¹³C TMAH) thermochemolysis. Samples were allowed to decompose for 27 months in litter bags at a German spruce forest site, resulting in a range of mass loss from 26% (beech) to 58% (ash). In contrast to conventional unlabelled TMAH thermochemolysis, ¹³C-labelling allows thermochemolysis products from lignin, demethylated lignin and other polyphenolic litter compounds (e.g. tannins) to be distinguished. Proxies for lignin degradation (phenol yield; acid/aldehyde ratio of products) changed considerably upon correction for the contribution of non-lignin sources to the thermochemolysis products. Using the corrected values, we found increasing acid/aldehyde values as well as decreasing or constant yield of lignin derived phenols normalised to litter carbon, suggesting pronounced lignin degradation by wood-rotting fungi. No indication for build up of demethylated lignin through the action of brown rot fungi on ring methoxyls was found. The results were compared with those of other analytical techniques applied in previous studies. Like ¹³C-TMAH thermochemolysis, CuO oxidation showed increasing lignin oxidation (acid/aldehyde ratio) and no/little enrichment of lignin derived phenols in the litter. Molecular lignin degradation patterns did not match those from analysis of total acid unhydrolysable residues (AURs). In particular, the long assumed selective preservation of lignin during the first months of litter decomposition, based on AUR analysis, was not supported by results from the CuO and ¹³C TMAH methods.     

Mineral chemistry of a Cenozoic igneous complex,the Urumieh–Dokhtar magmatic belt,Iran: Petrological implications for the plutonic rocks

The Niyasar plutonic complex, one of the Cenozoic magmatic assemblages in the Urumieh‐Dokhtar magmatic belt, was the subject of detailed petrographic and mineralogical investigations. The Niyasar magmatic complex is composed of Eocene to Oligocene mafic rocks and Miocene granitoids. Eleven samples, representing the major rock units in the Niyasar magmatic complex and contact aureole were chosen for mineral chemical studies and for estimation of the pressure, temperature, and oxygen fugacity conditions of mineral crystallization during emplacement of various magmatic bodies. The analyzed samples are composed of varying proportions of quartz, plagioclase, K‐feldspar, hornblende, biotite, titanite, magnetite, apatite, zircon, garnet, and clinopyroxene. Application of the Al‐in‐hornblende barometer indicates pressures of around 0.2 to 0.4 kbar for the Eocene–Oligocene mafic bodies and around 0.5 to 1.7 kbar for the Miocene granitoids. Hornblende‐plagioclase thermometry yields relatively low temperatures (661–780 °C), which probably reflect late stage re‐equilibration of these minerals. The assemblage titanite–magnetite–quartz as well as hornblende composition were used to constrain the oxygen fugacity and H₂O content during the crystallization of the parent magmas in the Miocene plutons. The results show that the Miocene granitoids crystallized from magmas with relatively high oxygen fugacity and high H₂O content (~5 wt% H₂O). The Miocene granitoids show similar range of oxygen fugacity, H₂O contents and mineral chemical compositions, which indicate a common source for their magmas. Although the crystallization pressures of the Miocene plutons discriminate various categories of plutonic bodies emplaced at depths of about 5.7–6.5 km (Marfioun pluton), about 4.2 km (Ghalhar pluton) and 1.9–2.3 km (Poudalg pluton), they were later uplifted to the same level by vertical displacement of faults. The emplacement depths of the Niyasar plutons suggest that the central part of the Urumieh‐Dokhtar magmatic belt has experienced an uplift rate of ca. 0.25–0.4 mm/yr from the Miocene onwards.     

U–Pb dating, Hf-isotope characteristics and trace-REE-patterns of zircons from Medet porphyry copper deposit, Bulgaria: implications for timing, duration and sources of ore-bearing magmatism

Precise U–Pb geochronology, Hf isotope compositions and trace element distributions in zircons are combined in the present study to define the timing and sources of the magmatism forming the Medet porphyry copper deposit, Bulgaria. ID-TIMS U–Pb-zircon dating demonstrates that ore-bearing magmatism extended for less than 1.12 Ma. As inferred from the field relationships, it started with the intrusion of a quartz-monzodiorite at 90.59?±?0.29 Ma followed by granodiorite porphyries at 90.47?±?0.30 and 90.27?±?0.60 Ma and by crosscutting aplite dykes at 90.12?±?0.36 Ma. These units were overprinted by potassic alteration and host economic copper-(Mo–Au) mineralization. The main magmatic–hydrothermal activity ceased after that, and a later quartz-granodiorite porphyry dyke, dated at 89.26?±?0.32 Ma, only contains an uneconomic quartz–pyrite mineralization. Assimilation of Lower Paleozoic rocks with a mantle to mantle–crust signature is characteristic of the fertile magma in the Medet deposit, as defined by positive ?-Hf values of the inherited zircons. The positive Ce-anomalies and the higher Eu/Eu* ratios of the zircons in the mineralized Cretaceous rocks of Medet deposit argue for crystallization from a generally more oxidized magma compared to the later quartz-granodiorite porphyry dyke. A change in paleostress conditions occurred during the intrusion of the Medet pluton and its dykes. The initial stage reveals E–W extension associated with N–S compression, whereas the younger granodiorite dyke was emplaced during subsequent N–S extension. The large-scale switch of the extensional stress regime during the mineralization was favourable for ore deposition by channelling the fluids and increasing the effective permeability.     

Monitoring Cenozoic climate evolution of northeastern Tibet: stable isotope constraints from the western Qaidam Basin,China

Carbon and oxygen stable isotopic composition of Cenozoic lacustrine carbonates from the intramontane Qaidam Basin yields cycles of variable length and shows several distinct events driven by tectonics and climate changes. From Eocene to Oligocene, the over-all trend in the δ¹³C composition of lacustrine carbonates shows a shift toward higher values, possibly related to higher proportions of dissolved inorganic carbon transported to the lake or lower input of soil derived CO₂. At the same time, the δ¹⁸O composition of lacustrine carbonates is decreasing in accordance with the global cooling trend and northwards drifting of the whole region. During the Miocene, distinct isotopic events can be recognized, although their interpretation and linkage to a certain tectonic event remains difficult. These events may be related to uplift in the Himalayas, to the strongest phase of uplift in the Altyn Mountains, to pronounced subsidence of the Qaidam Basin or to the expansion of C4 plants on land. Generally cold, highly evaporative conditions can be deduced from enrichment of δ¹⁸O isotopic compositions during Pliocene and Quaternary times.     

基于透射电镜的香肠构造流变计研究

采用透射电镜(TEM)对采自奥地利东阿尔卑斯和北京西山的香肠构造中的香肠体和相应基质的样品进行了超微构造分析。结果表明细粒基质中的位错密度较粗颗粒香肠体中的位错密度明显低很多。故认为香肠体的变形机制以位错蠕变为主,而基质的变形机制则以扩散蠕变为主。这从一个侧面为香肠构造流变计的这一假设提供了超微观研究的依据。     

Tertiary to recent oblique convergence and wrenching of the Central Dinarides: Constraints from a palaeostress study

The late Eocene to Neogene tectonic evolution of the Dinarides is characterised by shortening and orogen-parallel wrenching superposed on the late Cretaceous and Eocene double-vergent orogenic system. The Central Dinarides exposes NW-trending tectonic units, which were transported towards the Adria/Apulian microcontinent during late Cretaceous–Palaeogene times. These units were also affected by subsequent processes of late Palaeogene to Neogene shortening, Neogene extension and subsidence of intramontane sedimentary basins and Pliocene–Quaternary surface uplift and denudation. The intramontane basins likely relate to formation of the Pannonian basin. Major dextral SE-trending strike-slip faults are mostly parallel to boundaries of major tectonic units and suggest dextral orogen-parallel wrenching of the whole Central Dinarides during the Neogene indentation of the Apulian microplate into the Alps and back-arc type extension in the Pannonian basin. These fault systems have been evaluated with the standard palaeostress techniques. We report four palaeostress tensor groups, which are tentatively ordered in a succession from oldest to youngest: (1) Palaeostress tensor group 1 (D₁) of likely late Eocene age indicates E–W shortening accommodated by reverse and strike-slip faults. (2) Palaeostress tensor group 2 (D₂) comprises N/NW-trending dextral and W/WSW-trending sinistral strike-slip faults, as well as WNW-striking reverse faults. These indicate NE–SW contraction and subordinate NW–SE extension related to Oligocene to early Miocene shortening of the Dinaric orogenic wedge. (3) Palaeostress tensor group 3a (D_3a) comprises mainly NW-trending normal faults, which indicate early/middle Miocene NE–SW extension related to syn-rift extension in the Pannonian basin. The subsequent palaeostress tensor group 3b (D_3b) includes NE-trending, SE-dipping normal faults indicating NW–SE extension, which is likely related to further extension in the Pannonian basin. (4) Palaeostress tensor group 4 (D₄) is characterised by mainly NW-trending dextral and NE-trending sinistral strike-slip faults. Together, with some E-trending reverse faults, they indicate roughly N–S shortening and dextral wrenching during late Miocene to Quaternary. This is partly consistent with the present-day kinematics, with motion of the Adriatic microplate constrained by GPS data and earthquake focal mechanisms. The north–north-westward motion and counterclockwise rotation of the Adriatic microplate significantly contribute the shortening and present-day wrenching in the Central Dinarides.     

Ar/Ar mineral ages from basement rocks in the Eastern Kunlun Mountains, NW China, and their tectonic implications

⁴⁰Ar/³⁹Ar dating and estimates of regional metamorphic P–T conditions were carried out on the basement rocks of the Eastern Kunlun Mountains, Western China. Samples from the Jinshuikou, Xiaomiao, Kuhai, Wanbaogou, and Nachitai groups revealed distinct metamorphic events and four age groups. The age group in the range from 363 to 439 Ma is interpreted to represent cooling after Middle Silurian–Late Devonian granulite(?) and amphibolite facies metamorphism, which is dominated by low–middle pressure/high temperature conditions. This tectono-thermal event is related to the closure of an oceanic basin or marginal sea. An age group of 212–242 Ma represents cooling after Triassic metamorphic overprint, which is probably associated with magmatic intrusions. This thermal event, together with the Permo-Triassic ophiolite zone along the South Kunlun Fault, relates to the closure of a major ocean (between India and Eurasia) and the eventual N-ward accretion of the Qiangtang block in Permo-Triassic times. The significance of the age group of 104–172 Ma may be related to the ductile deformation along the Xidatan fault due to the northward-directed accretion of the Lhasa block. Biotites from Nachitai record a partial isotopic resetting at ca. 32 Ma that is interpreted to represent a late-stage exhumation caused by further crustal shortening.