Behavior of Titan's atmosphere during a total eclipse

The edge-on presentation of Saturn's rings and satellites system has provided a rare opportunity to observe total eclipses of Titan. During its emersion from the Saturnian shadow (1980, June 28), Titan has been observed simultaneously in the visible and the infrared ranges (6000–9000 Å, 11.8 μm and 20 μm). No change has been recorded in these three spectral ranges. Our observations tend to support the thick-atmosphere model, which has been shown to be valid by Voyager a few months later.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Depleted lithosphere from the mantle wedge beneath Tres Lagos, southern Patagonia, Argentina

Anhydrous spinel lherzolite and harzburgite xenoliths from Tres Lagos, situated inboard of the Volcanic Arc Gap (VAG) in southernmost Patagonia, are samples of a depleted lithospheric mantle and can be divided into two major groups: metasomatized and non-metasomatized. Metasomatized samples, which are the minority, are partly mylonitized and their metasomatism is related to this tectonic process. A group of non-metasomatized samples have enriched whole rock LREE-abundances that are not consistent with the depleted LREE-abundances in their clinopyroxenes. Intergranular host basalt infiltration could be responsible for the whole rock LREE enrichments. Their Sr- and Nd-isotopic ratios have also been affected by host basalt infiltration, whereas their high Sr-isotopic ratios point to subsequent contamination by ground-water and/or Ca-rich surface solutions. Similar contamination is thought to cause the decoupling of Sr- and Nd-isotopes (high Sr- and Nd-isotopic ratios) observed in the non-metasomatized samples with depleted whole rock LREE. A two-stage partial melting process could be responsible for the origin of the Tres Lagos xenoliths. Model calculations have shown that in the first stage, 2% of batch melting took place in the garnet peridotite field and subsequently the residue experienced 2–8% batch melting in the spinel peridotite field. The Tres Lagos peridotites have not been affected by subduction-related metasomatic processes and they could represent an old lithospheric mantle.     

Shallow gas in the muddy sediments of Eckernförde Bay, Germany

The seafloor of central Eckernförde Bay is characterised by soft muddy sediments that contain free methane gas. Bubbles of free gas cause acoustic turbidity which is observed with acoustic remote sensing systems. Repeated surveys with subbottom profiler and side scan sonar revealed an annual period both of depth of the acoustic turbidity and backscatter strength. The effects are delayed by 3–4 months relative to the atmospheric temperature cycle. In addition, prominent pockmarks, partly related to gas seepage, were detected with the acoustic systems. In a direct approach gas concentrations were measured from cores using the gas chromatography technique. From different tests it is concluded that subsampling of a core should start at its base and should be completed as soon as possible, at least within 35 min after core recovery. Comparison of methane concentrations of summer and winter cores revealed no significant seasonal variation. Thus, it is concluded that the temperature and pressure influences upon solubility control the depth variability of acoustic turbidity which is observed with acoustic remote sensing systems. The delay relative to the atmospheric temperature cycle is caused by slow heat transfer through the water column. The atmospheric temperature cycle as ‘exiting function’ for variable gas solubility offers an opportunity for modelling and predicting the depth of the acoustic turbidity. In practice, however, small-scale variations of, e.g., salinity, or gas concentration profile in the sediment impose limits to predictions. In addition, oceanographic influences as mixing in the water column, variable water inflow, etc. are further complications that reduce the reliability of predictions.     

A note on the feldspars in the granite xenoliths of the nyiragongo magma

The lavas of the Nyiragongo volcano in Eastern Zaire contain partially fused granite xenoliths. The relictic feldspars found in these xenoliths were studied by microprobe analysis and by X-ray diffraction methods. Some xenoliths represent originally two-feldspar granites, in others only alkali feldspars or those of an anorthoclase composition were detected. All feldspars are homogeneous without perthitic textures detectable under the microscope. In thebc-diagram of Stewart and Wright all feldspars plot on the analbite-high sanidine join. These feldspars have been perfectly disordered through heating in the melilite-nephelinite magma of the volcano.     

On the thermal stability of Rb-Sr and K-Ar biotite systems: Evidence from coexisting Sveconorwegian (ca 870 Ma) and Caledonian (ca 400 Ma) biotites in SW Norway

The Caledonian orogeny has imposed a zone of greenschist facies metamorphism on the high-grade Sveconorwegian basement along the front of the Caledonian nappe system in S.W. Norway. In this zone a Caledonian generation of green biotite (ca 400 Ma old) has developed, indicating a metamorphic temperature of about 400° C. This Caledonian biotite occurs side by side with relicts of a Sveconorwegian generation of brown biotite (ca 870 Ma old). The somewhat younger ages obtained from a number of brown biotites can be related to a partial transformation of the old biotite to titanite+green biotite during the Caledonian metamorphic recrystallization. Loss of radiogenic Ar and Sr from the biotite by volume diffusion apparently has not been operative, even at a temperature as high as 400° C. The Sveconorwegian biotite appears to have remained virtually closed to K-Ar and Rb-Sr up to the break-down due to metamorphic recrystallization.     

Genesis of the Nyiragongo lavas

Mt. Nyiragongo is one of the eight major volcanoes of the large Virunga volcanic field in the Lake Kivu area in the Eastern Congo. The lavas of Nyiragongo are rather unique. Starting from the top of the mountain, the rocks are nephelinites with some leucite and melilite. The molten material of the present-day lava lake belongs to this type of lava. Under the nephelinites, there is a thin series of leucite-rich lava beds. The main part of the volcano consists of bergalitic melitite lavas alternating with pyroclastics of similar composition. The nephelinitic material is considered to constitute the main portion of the pre-volcanic magma under the future volcano. It is pointed out that the Nyiragongo represents just the type of volcano with which the African volcanic carbonatites are associated. It is concluded that the Nyiragongo nephelinite must be interpreted in a way accepted for the Central African volcanic nephelinites in general. The bergalitic melilitite material is interpreted as a product of carbonation of the nephelinitic magma.