Polarization measurements using the Bragg crystal spectrometers on Hinotori

The two Bragg crystal spectrometers on board Hinotori provide a new technique for measuring linear polarization of the soft X-ray line emission from solar flares. The results of the measurements of large (X class) flares are given in this paper, and the polarization degree averaged over the soft X-ray maximum phases is estimated to be less than 4%.     

Effect of the development of notches and tension cracks on instability of limestone coastal cliffs in the Ryukyus, Japan

Notches cut by waves are currently developing at the base of vertical coastal limestone cliffs in Okinawa, Japan. The cliff height varies from 3.0–22.1 m, and the maximum notch depth is 8.8 m. Many rectangular or cubic blocks, which appear to have originated from cliff failures, are found on platforms in front of the cliffs. On the flat top surface of the cliff, tension cracks often run parallel to the cliff face. The vertical face of the cliffs displays small undulations but no sliding striation, suggesting that cliff failures have been caused by toppling rather than by shearing or sliding. We use slope stability analysis to determine the critical condition for toppling failure. Physical and mechanical properties of the cliff material were first obtained from laboratory tests. The results indicate that the strength of limestone shows a scale effect, such that the strength decreases with increasing size of the test specimens. Based on this result, we estimated the strength of a rock mass corresponding to the size of the coastal cliff. Cliff stability was then analyzed using a cantilever beam model. Comparison of the stability analysis and the dimension of fallen blocks indicates that toppling failure is strongly associated with the development of notches and tension cracks.     

Nonlinear sloshing in a floating‐roofed oil storage tank under long‐period seismic ground motion

A hybrid analytical and FEM is proposed to investigate the nonlinear sloshing in a floating‐roofed oil storage tank under long‐period seismic ground motion. The tank is composed of a rigid cylindrical wall and a flat bottom, whereas the floating roof is treated as an elastic plate undergoing large deflection. The contained liquid is assumed to be inviscid and incompressible, and the flow is assumed to be irrotational. The method of analysis is based on representation of the liquid motion by superposing the analytical modes that satisfy the Laplace equation and the rigid wall and bottom boundary conditions. The FEM is then applied to solve the remaining kinematic and dynamic boundary conditions at the moving liquid surface coupled with the nonlinear equation of motion of the floating roof. This requires only the discretization of the liquid surface and the floating roof into finite elements, thus leading to a computationally efficient and accurate method compared with full numerical analysis. As numerical examples to illustrate the applicability of the proposed method, two oil storage tanks with single‐deck type floating roofs damaged during the 2003 Tokachioki earthquake are studied. It is shown that the nonlinear oscillation modes with the circumferential wave numbers 0, 2 and 3 caused by the finite liquid surface elevation as well as the membrane action due to large deflection of the deck produce excessively large stresses in the pontoon, which may cause the catastrophic failure of pontoon followed by the submergence of the roof. Copyright © 2012 John Wiley & Sons, Ltd.     

Desorption kinetics of hydrophobic organic contaminants from marine plastic pellets

This study investigated the desorption behavior of polychlorinated biphenyls (PCBs) from marine plastic pellets. Long-term desorption experiments were conducted using field-collected polyethylene (PE) pellets. The results indicate that the desorption kinetics highly depends on the PE-water partition coefficients of PCB congeners. After 128 d of the experiment, the smallest congener considered (CB 8) had desorbed nearly completely (98%), whereas major fractions (90–99%) of highly chlorinated congeners remained in the pellets. An intraparticle diffusion model mostly failed to reproduce the desorption kinetics, whereas an aqueous boundary layer (ABL) diffusion model well approximated the data. The desorption half-lives are estimated to 14 d to 210 years for CB 8 to CB 209 in an actively stirred solution (ABL thickness: 30 μm). Addition of methanol to water enhanced the desorption to a large extent. A need for further work to explore roles of organic matter in facilitating solute transfer is suggested.     

In situ X-ray diffraction measurements of the <Emphasis Type="Italic">fcc</Emphasis>–<Emphasis Type="Italic">hcp</Emphasis> phase transition boundary of an Fe–Ni alloy in an internally heated diamond anvil cell

The phase transition boundary between the face-centered cubic (fcc) structure and hexagonal close-packed (hcp) structure in an Fe–Ni alloy was determined at pressures from 25 to 107 GPa by using an internally resistive-heated diamond anvil cell (DAC), combined with in situ synchrotron X-ray diffraction measurements. The fcc–hcp phase transition boundary in Fe–9.7 wt% Ni is located at slightly lower temperatures than that in pure Fe, confirming the previous understanding that the addition of Ni expands the stability field of the fcc phase. The dP/dT slope of the boundary was determined to be 0.0426 GPa/K, which is slightly larger than that of pure Fe. The pressure interval of the two-phase region is about 6 GPa at a constant temperature, implying that the previous estimates by laser-heated DAC experiments of 10–20 GPa were overestimated. The two-phase region of fcc + hcp would be limited to a pressure of about 120 GPa even in Fe–15 wt%Ni, excluding the possibility of the existence of the fcc phase in the inner core if the simple linear extrapolation of the two-phase region is applied. The pressure and temperature dependences of the c/a axial ratio of the hcp phase in Fe–9.7 wt% Ni are generally consistent with those in pure Fe, suggesting that Ni has minor effects on the c/a ratio.     

Structural architecture and low‐grade metamorphism of the Mikabu‐Northern Chichibu accretionary wedge,SW Japan

To understand tectono‐metamorphic processes within or close to the brittle–ductile transition of quartz‐rich crustal rocks in an accretionary wedge, an integrated field, petrological, geochronological and Raman spectroscopic study was conducted on the Mikabu‐Northern Chichibu belt in SW Japan. Field mapping in central Shikoku reveals that the Northern Chichibu belt is comprised of a pile of four tectono‐stratigraphic units, referred to as A, B, C and D units. The A unit (dominated by pelagic sedimentary rocks) represents the structurally lowest and youngest accretionary complex that forms a composite unit with the Mikabu ophiolitic suite. The B unit (consisting of chert‐clastic rock sequences) overlies the A unit and is overlain by the C and D units (mudstone‐matrix mélange units). Raman spectroscopy of carbonaceous material constrains the peak temperature of each unit to be ~290°C for the A unit, 270–290°C for the B unit, 230–250°C for the C unit and ~220°C for the D unit. Ductile deformation and pervasive metamorphism are limited to rocks in the Mikabu, A and B units. Alkali pyroxene and sodic amphibole occur in metabasite from the Mikabu, A and B units, and the widespread occurrence of prograde veins containing lawsonite+quartz pseudomorphs after laumontite was newly recognized from the C unit. Phase petrological data constrain the peak pressure of each unit to be ~0.65 GPa for the Mikabu‐A unit (aragonite stable), ~0.45–0.6 GPa for the B unit (jadeite+albite stable in the structurally lower part), and ~0.35 GPa for the C unit (prehnite+lawsonite stable). The peak metamorphic pressure increases towards structurally lower and younger accretionary complexes, but the thickness of the preserved strata is insufficient to account for the inferred pressure range. The structural–metamorphic relations imply thickening of the accretionary wedge by underplating was followed by a significant phase of thinning by both ductile and brittle processes.