Compressibility of the calcium aluminosilicate, CAS, phase to 44 GPa

In situ X-ray diffraction measurements on a calcium aluminosilicate (CAS) phase have been carried out using a laser-heated diamond anvil cell up to a pressure of 44 GPa, employing a synchrotron radiation source. CAS is the major mineral formed from sediments subducted into the Earth's mantle. The sample was heated using a YAG laser after each pressure increment to relax the deviatoric stress in the sample. X-ray diffraction measurements were carried out at T = 300 K using an angle-dispersive technique. The pressure was calculated using an internal platinum metal pressure calibrant. The Birch–Murnaghan equation of state for the CAS phase obtained from the experimental unit cell parameters showed a density of ρ₀ = 3.888 g/cm³ and a bulk modulus of K₀ = 229 ± 9 GPa for K^′₀ = 4.7 ± 0.7. When the first pressure derivative of the bulk modulus was fixed at K^′₀ = 4, then the value of K₀ = 239 ± 2 GPa. From the experimental compressibility, the density of the CAS phase was observed to be lower than the density of co-existing Al-bearing stishovite, calcium perovskite, calcium ferrite-type phases, and (Fe,Al)-bearing Mg-perovskite in subducted sediments in the lower mantle. Therefore, the density of subducted sediments in the lower mantle decreases with increasing mineral proportion of the CAS phase.     

Accuracy of gravimetric deflections of the vertical and optimization of gravity networks

In order to solve the problems of determining the shape of a part of the earth of national or continental extent, that is, of rigorous constituting and computing of the astrogeodetic network, it is required to determine gravimetric deflections of the vertical with an accuracy of, say, 0″.3. For this it is adequate to carry out additional gravity surveys in the neighborhoods of computation points, in addition to a given uniform gravity survey (normal density gravity survey). The study offers a method to determine the optimal distribution of gravity stations in such a gravity survey, which guarantees a given accuracy of computed gravimetric deflections of the vertical for a given statistical condition which characterizes the variation of the gravity field. The approach used here is based on the concept of the error of representation and the error propagation of Vening Meinesz integrals.     

Spatio-temporal estimation of shallow landslide hazard triggered by rainfall using a three-dimensional model

A shallow landslide triggered by rainfall can be forecast in real-time by modeling the relationship between rainfall infiltration and decrease of slope stability. This paper describes a promising approach that combines an improved three-dimensional slope stability model with an approximate method based on the Green and Ampt model, to estimate the time–space distribution of shallow landslide hazards. Once a forecast of rainfall intensity and slope stability-related data, e.g., terrain and geology data, are acquired, this approach is shown to have the ability to estimate the variation of slope stability of a wide natural area during rainfall and to identify the location of potential failure surfaces. The effectiveness of the estimation procedures described has been tested by comparison with a one-dimensional method and by application to a landslide-prone area in Japan.     

On the importance of accurately ray-traced troposphere corrections for Interferometric SAR data

Numerical weather models offer the possibility to compute corrections for a variety of space geodetic applications, including remote sensing techniques like interferometric SAR. Due to the computational complexity, exact ray-tracing is avoided in many cases and mapping approaches are applied to transform vertically integrated delay corrections into slant direction. Such an approach works well as long as lateral atmospheric gradients are small enough to be neglected. But since such an approximation holds only for very rare cases it is investigated how horizontal gradients of different atmospheric constituents can evoke errors caused by the mapping strategy. Moreover, it is discussed how sudden changes of wet refractivity can easily lead to millimeter order biases when simplified methods are applied instead of ray-tracing. By an example, based on real InSAR data, the differences of the various troposphere correction schemes are evaluated and it is shown how the interpretation of the geophysical signals can be affected. In addition, it is studied to which extend troposphere noise can be reduced by applying the exact ray-tracing solution.     

Style of fluid flow and deformation in and around an ancient out-of-sequence thrust: An example from the Nobeoka Tectonic Line in the Shimanto accretionary complex, Southwest Japan

To understand the characteristics of deformation of an out-of-sequence thrust (OST) and the style of fluid flow along it, we investigated the Nobeoka Tectonic Line, which has been interpreted as a deep OST (7–9 km), in the Shimanto accretionary complex, Southwest Japan. The shear zone in the footwall differs significantly in the along-strike direction not only in thickness, which varied from 100 to 300 m, but also in lithology and mineral vein development. These variations might reflect primarily differences in lithology; that is, the sandstone-dominant shear zone with a large amount of mineral veins precipitated in microcracks is relatively thick, whereas the shale-dominant shear zone with a small amount of veins and with textures indicating highly pressurized pore fluid, is thinner. By comparison with characteristics of a shallow OST (3–5 km), we conclude that the shallow OST has experienced repeated brittle failure with rapid slip and focused fluid flow whereas the deep OST has experienced both brittle and ductile deformation, followed by fluid flow of various styles, depending on the lithology.     

High-pressure phase transformations of FeS: Novel phases at conditions of planetary cores

Iron sulfide (FeS) was investigated using first-principles calculations up to a pressure of 400 GPa. A number of new phase transitions were found. An antiferromagnetic MnP-type structure, FeS II, was confirmed to be stable at low pressures, whereas at high pressures (40–135 GPa) we find a new stable phase, with a non-magnetic MnP-type structure, FeS VI. The observed first-order change in the cell shape between the two phases can be explained by the difference in magnetic configurations. The calculated cell parameters, atomic coordinates, and bulk modulus of non-magnetic MnP-type phase are consistent with those determined from experiment. The upper pressure limit of the stability of the non-magnetic MnP-type phase was calculated to be 135 GPa. A hitherto unsuspected phase transition from the non-magnetic MnP-type to a phase with Pmmn symmetry, FeS VII, was identified using the evolutionary crystal structure prediction (USPEX) method. The structure of the Pmmn phase has no known analogues, but can be described as a distortion of the NaCl-type structure. The Pmmn phase with the distorted NaCl-type structure is stable from 135 GPa at least up to 400 GPa. According to previous experiments and the present study, the transition sequence of FeS at low temperatures is as follows: troilite ➔ antiferromagnetic MnP-type phase ➔ monoclinic phase ➔ non-magnetic MnP-type phase ➔ Pmmn phase. The calculated volume reduction from the monoclinic to the non-magnetic MnP-type phase is 1.0% at 40 GPa, which is in good agreement with experimental observations. The calculated volume reduction from the non-magnetic MnP-type to the Pmmn phase is 3.7% at 135 GPa.     

Contamination status and accumulation profiles of organotins in sea otters (Enhydra lutris) found dead along the coasts of California, Washington, Alaska (USA), and Kamchatka (Russia)

Organotin compounds (OTs) including mono- to tri-butyltins, -phenyltins, and -octyltins were determined in the liver of adult sea otters (Enhydra lutris) found dead along the coasts of California, Washington, and Alaska in the USA and Kamchatka, Russia. Total concentrations of OTs in sea otters from California ranged from 34 to 4100ng/g on a wet weight basis. The order of concentrations of OTs in sea otters was total butyltins>total octyltins> or = total phenyltins. Elevated concentrations of butyltins (BTs) were found in some otters classified under 'infectious-disease' mortality category. Concentrations of BTs in few of these otters were close to or above the threshold levels for adverse health effects. Total butyltin concentrations decreased significantly in the livers of California sea otters since the 1990s. Based on the concentrations of organotins in sea otters collected from 1992 to 2002, the half-lives of tributyltin and total butyltins in sea otters were estimated to be approximately three years.     

Arsenic species and their accumulation features in green turtles (Chelonia mydas)

Total arsenic (As) and its compounds were determined in liver, kidney, muscle, and stomach contents of green turtles (Chelonia mydas). Total As concentrations in the muscle were higher than those in the kidney and liver. Arsenobetaine (AB) was the predominant compound in all the three tissues and its levels were positively correlated with total As concentrations. This indicates that AB greatly contributes to As accumulation in green turtles. Higher concentrations of remaining As in the sample after extraction were detected in the liver, implying that lipid-soluble or protein bound As compounds accumulate in the liver of green turtles. Total As levels in tissues showed significant negative correlations with standard carapace length. The size-dependence of As accumulation in green turtles may be related to their feeding habit, shifting from carnivore to herbivore at different growth stages. Concentrations of AB and dimethylarsinic acid (DMA) were low in the stomach contents but high in the tissues, implying bioaccumulation of these arsenicals in green turtles.     

Seasonal change of oceanographic conditions and chlorophyll <Emphasis Type="Italic">a</Emphasis> vertical distribution in the southwestern Okhotsk Sea during the non-iced season

Seasonal changes in oceanographic conditions related to primary productivity was investigated in the southwestern Okhotsk Sea during non-iced seasons, using the observation data conducted in 2000∼2006. Based on hydrographic characteristics, the studied area could be classified into two regions, the Coastal Region which is influenced under the Soya Warm Current and the Forerunner Water of the Soya Warm Current, and the Offshore Region where the Intermediate Cold Water was located in the subsurface layer. This study is the first report on seasonal change of nutrient and chlorophyll a concentrations in the offshore region of the southwestern Okhotsk Sea. Variability of concentrations of chlorophyll a and nutrients is temporally and regionally high in the Coastal Region. The maximum chlorophyll a concentration in April was observed at the surface layer of both regions. The most remarkable feature on the vertical structure in the Offshore Region was the consistent existence of the Intermediate Cold Water and the development of seasonal thermocline in the subsurface layer during summer and autumn. The stratification formed within the euphotic zone in the Offshore Region resulted in the formation of the subsurface chlorophyll a maximum (SCM) from May to October. Throughout the research period, although less amplitude of nutrients at the surface was observed in the Coastal Region than that in the Offshore Region, comparable amplitude of chlorophyll a concentration was observed between regions. These results suggested differences of environmental conditions for primary production between the two regions. Depending on the presence of SCM, relationships between chlorophyll a concentration at the sea surface and chlorophyll a standing stock within the euphotic layer were different. At most stations with SCM, the surface chlorophyll a concentration was lower than 0.6 mg m-3. This suggests that the presence of SCM and the chlorophyll a standing stock within the euphotic layer may be estimated using the surface chlorophyll a concentration from spring to autumn in the studied area.