Chromium solubility in MgSiO3 ilmenite at high pressure

The crystal structure and chemical composition of crystals of (Mg_1?x Cr _x )(Si_1?x Cr _x )O₃ ilmenite (with x = 0.015, 0.023 and 0.038) synthesized in the model system Mg₃Cr₂Si₃O₁₂–Mg₄Si₄O₁₂ at 18–19 GPa and 1,600 °C have been investigated. Chromium was found as substitute for both Mg at the octahedral X site and Si at the octahedral Y site, according to the reaction Mg²⁺ + Si⁴⁺ = 2Cr³⁺. Such substitutions cause a shortening of the <X–O> and a lengthening of the <Y–O> distances with respect to the values typically observed for pure MgSiO₃ ilmenite and eskolaite Cr₂O₃. Although no high Cr contents are considered in the pyrolite model, Cr-bearing ilmenite may be the host for chromium in the Earth’s transition zone. The successful synthesis of ilmenite with high Cr contents and its structural characterization are of key importance because the study of its thermodynamic constants combined with the data on phase relations in the lower-mantle systems can help in the understanding of the seismic velocity and density profiles of the transition zone and the constraining composition and mineralogy of pyrolite in this area of the Earth.     

大气季节内振荡对印度洋—西太平洋地区热带低压/气旋生成的影响

文中利用EOF分析大气季节内振荡 (MJO)的时空变化的方法 ,研究了 1996年 9月～ 1997年 6月间的MJO活动对生成在印度洋—西太平洋海域的热带低压 /气旋的影响。结果发现 ,除西北太平洋之外 ,发生在其他区域的热带低压 /气旋有半数以上生成在向东移动的MJO的湿位相中。伴随MJO的向东传播 ,热带低压 /气旋平均生成位置也随之向东移动 ,而生成在西北太平洋的热带低压 /气旋分别受到向东和向西传播的MJO影响     

Analytical methods for error propagation in planar space–time prisms

The space–time prism demarcates all locations in space–time that a mobile object or person can occupy during an episode of potential or unobserved movement. The prism is central to time geography as a measure of potential mobility and to mobile object databases as a measure of location possibilities given sampling error. This paper develops an analytical approach to assessing error propagation in space–time prisms and prism–prism intersections. We analyze the geometry of the prisms to derive a core set of geometric problems involving the intersection of circles and ellipses. Analytical error propagation techniques such as the Taylor linearization method based on the first-order partial derivatives are not available since explicit functions describing the intersections and their derivatives are unwieldy. However, since we have implicit functions describing prism geometry, we modify this approach using an implicit function theorem that provides the required first-order partials without the explicit expressions. We describe the general method as well as details for the two spatial dimensions case and provide example calculations.     

Melt inclusion analysis of the Unzen 1991–1995 dacite: implications for crystallization processes of dacite magma

Dacitic magma, a mixture of high-temperature (T) aphyric magma and low-T crystal-rich magma, was erupted during the 1991–1995 Mount Unzen eruptive cycle. Here, the crystallization processes of the low-T magma were examined on the basis of melt inclusion analysis and phase relationships. Variation in water content of the melt inclusions (5.1–7.2 wt% H₂O) reflected the degassing history of the low-T magma ascending from deeper levels (250 MPa) to a shallow magma chamber (140 MPa). The ascent rate of the low-T magma decreased markedly towards the emplacement level as crystal content increased. Cooling of magma as well as degassing-induced undercooling drove crystallization. With the decreasing ascent rate, degassing-induced undercooling decreased in importance, and cooling became more instrumental in crystallization, causing local and rapid crystallization along the margin of the magma body. Some crystals contain scores of melt inclusions, whereas there are some crystals without any inclusions. This heterogeneous distribution suggests the variation in the crystallization rate within the magma body; it also suggests that cooling was dominant cause for melt entrapment. Numerical calculations of the cooling magma body suggest that cooling caused rapid crystal growth and enhanced melt entrapment once the magma became a crystal-rich mush with evolved interstitial melt. The rhyolitic composition of melt inclusions is consistent with this model.Editorial responsibility: H Shinohara     

Seasonal variation in water column conditions in the upper Gulf of Thailand

Seasonal variation in water column conditions in the upper Gulf of Thailand (UGoT) was analyzed by considering four major factors including surface heat flux, freshwater discharge, tidal and wind stirrings. The coincidence of surface heat loss, low river discharge and strong wind resulted in vertical well-mixing in December. Strong stratification developed in September and October due to large river discharge and moderate heat flux. Strong surface heating in April and May has a potential to generate strong stratification, although not as large as that in September and October due to low river discharge. Although no factors are prominent during January and March, and June and August, weak to moderate stratification results, because the influences of river discharge and surface heating are still larger than those of tidal and wind stirrings. The results of water column analysis based on monthly average data agree well with analyses derived from cruise data in the same months. Most analytical results correspond to the distributions of temperature and salinity from field observations. Disagreement, however, was found in December 2003 (cruise CU-2) when stratification in some small regions occurs in the distribution of water properties, but the water column analysis suggests vertical well-mixing. This phenomenon is triggered by non-uniform distribution of freshwater over UGoT, which is related to river discharge, monsoonal wind and current. Compared to a previous study regarding surface chlorophyll dynamics, water column conditions may be used to explain the occurrence of phytoplankton bloom in this region.     

Analysis of change of red tide species in Yodo River estuary by the numerical ecosystem model

Occurrence number of red tides in Osaka Bay in Japan is more than 20 cases every year. Diatom red tide was dominant in Osaka Bay, but the non-diatom red tide was dominant in early 1990s. Therefore, the material cycling in Yodo River estuary in Osaka Bay during August from 1991 to 2000 was analyzed by using the numerical ecosystem model and field observation data to clarify the reasons of change in red tide species. Year-to-year variation in calculated concentration ratio of diatom to non-diatom corresponds to the variation in observed ratio of red tide days of diatom to non-diatom. Limiting nutrient of primary production is phosphate over the period. Diatom dominated from 1991 to 1993, but it was difficult for non-diatom to grow due to the limitation by physical condition. Non-diatom was able to grow because of good physical and nutrient conditions from 1994 to 1996. And diatom dominated again under the good physical condition, and phosphorus supply was not enough for non-diatom to grow from 1998 to 2000. Phosphate concentration in the lower layer of Yodo River estuary was important to the variation in red tide species in the upper layer of Yodo River estuary.     

Water exchange between Tokyo Bay and the Pacific Ocean during winter

Variability in water-exchange time between Tokyo Bay and the Pacific Ocean during winter is investigated based on the results of intensive field observation from November 2000 to March 2001. Water-exchange time between Tokyo Bay and the Pacific Ocean during winter mainly depends on the strength of northerly monsoon, being about 16 days under the weak monsoon and about 12 days under the strong monsoon. Moreover, it becomes longer by about 1 day in spring tide and shorter in neap tide due to the coupling effect of estuarine circulation and vertical mixing. Water-exchange time also varies depending on the open-ocean condition. When the warm water mass approaches from the Pacific Ocean to the mouth of Tokyo Bay through the eastern channel of Sagami Bay, which connects Tokyo Bay and the Pacific Ocean, water-exchange time becomes longer by about 2 days because the warm water mass is blocked in the surface layer at the bay mouth. On the other hand, when the warm water mass approaches to the mouth of Tokyo Bay through the western channel of Sagami Bay, water-exchange time becomes shorter by about 1 day because the warm water mass intrudes into the middle or lower layers of Tokyo Bay. Such different behavior of warm water mass at the mouth of Tokyo Bay is due to the difference in density of approaching warm water masses, that is, the density of the warm water mass through the eastern channel is smaller than that of the warm water mass through the western channel of Sagami Bay.Responsible Editors: Yens Kappenberg     

Measurements of wave normal direction of whistler mode signals in the ionosphere by means of the Rocket-Doppler technique

Wave normal directions of VLF signals propagating through the ionosphere can be determined by measuring Doppler frequency shift of the signals by means of rocket borne receivers. Two rockets were launched to detect the NWC signal of 22.3 kHz which was transmitted from Australia and propagated on two completely different paths, one being propagated through the Earth-ionosphere waveguide and up to the rocket, the other propagated down to the rocket by the whistler mode directly from the source in the opposite hemisphere. The wave normal directions of the latter mode were almost vertically downward in the ionosphere in the northern hemisphere, although substantial error was involved in the determination of the wave normal direction for a part of the upgoing flight of the rockets, due to the relative geometry of the directions of the rocket flight and the geomagnetic field. The effect of the horizontal gradients of the ionosphere on the above results were found to be not significant. From the experimental results it is concluded that field aligned ducts stretching down to the rocket altitudes did not exist, at least, during the rocket flights.     

Baroclinic eddies south of Cheju Island in the East China Sea

The detailed structures of baroclinic eddies, that is, an anticlockwise circulation in the upper layer and a clockwise one in the lower layer south of Cheju Island in the East China Sea have been revealed by intensive field observation. Such baroclinic eddies are accompanied by the southward spreading of the Yellow Sea Bottom Cold Water.     

Variation in the thermohaline front at the mouth of Tokyo Bay

The generation, variation, and disappearance of the thermohaline front at the mouth of Tokyo Bay were investigated using water temperature data obtained by a commercial ferry boat in 1987. The thermohaline front was generated south of Kan-non-zaki in mid November 1987 after the beginning of sea-surface cooling. It moved northward to Kan-non-zaki until the end of the year. The thermohaline front was most intense in February and March and disappeared in late March 1987 when sea-surface warming began.