The origin of refractory minerals in comet 81P/Wild 2

Refractory Ti-bearing minerals in the calcium-, aluminum-rich inclusion (CAI) Inti, recovered from the comet 81P/Wild 2 sample, were examined using analytical (scanning) transmission electron microscopy (STEM) methods including imaging, nanodiffraction, energy-dispersive spectroscopy (EDX) and electron energy loss spectroscopy (EELS). Inti fassaite (Ca(Mg,Ti,Al)(Si,Al)₂O₆) was found to have a Ti³⁺/Ti⁴⁺ ratio of 2.0 ± 0.2, consistent with fassaite in other solar system CAIs. The oxygen fugacity (logf_O2) of formation estimated from this ratio, assuming equilibration among phases at 1509 K, is −19.4 ± 1.3. This value is near the canonical solar nebula value (−18.1 ± 0.3) and in close agreement with that reported for fassaite-bearing Allende CAIs (−19.8 ± 0.9) by other researchers using the same assumptions. Nanocrystals of osbornite (Ti(V)N), 2–40 nm in diameter, are embedded as inclusions within gehlenite, spinel and diopside in Inti. Vanadium is heterogeneously distributed within some osbornite crystals. Compositions range from pure TiN to Ti_0.36V_0.64N. The possible presence of oxide and carbide in solid solution with the osbornite was evaluated. The osbornite may contain O, but C is not present at detectable levels. The presence of osbornite, likely a refractory early condensate, together with the other refractory minerals in Inti, indicates that the parent comet contains solids that condensed closer to the proto-sun than the distance at which the parent comet itself accreted. The estimated oxygen fugacity and the reported isotopic and chemical compositions are consistent with Inti originating in the inner solar system like other meteoritic CAIs. These results provide insight for evaluating the validity of models of radial mass transport dynamics in the early solar system. The oxidation environments inferred for the Inti mineral assemblage are inconsistent with an X-wind formation scenario. In contrast, radial mixing models that allow accretion of components from different heliocentric distances can satisfy the observations from the cometary CAI Inti.     

Effect of ocean acidification on coastal phytoplankton composition and accompanying organic nitrogen production

The effect of ocean acidification, caused by the increase in pCO₂ in seawater, on phytoplankton population and on related organic nitrogen production was experimentally examined by use of a natural coastal microbial population. pCO₂ and pH were controlled by aeration with air in which pCO₂ was at the current level (control), for which ambient air was used, and with air in which pCO₂ was ??800?? and ??1200?? ppm, in 500-L culture vessels. The experiment was continued for 15?days after addition of the inorganic nutrients such as nitrate, phosphate, and silicate. During most of the experimental period, a minor increase in phytoplankton biomass was noted, probably because of low irradiance, an increase in phytoplankton biomass was observed at the end of the experiment. Flow cytometric and microscopic observations revealed that this increase was because of Chrysochromulina sp. (Haptophyceae). The growth of Chrysochromulina sp. was most obvious in the control vessel, and tended to be obscured by increasing pCO₂ (decrease in pH), indicating the possibility that ocean acidification inhibits the growth of specific phytoplankton groups, for example Chrysochromulina sp. Production of particulate organic nitrogen (PON), determined by the ¹⁵N tracer method, also diminished under acidified conditions compared with that at the current level.     

The early Miocene (~25 Ma) volcanism in the northern Kyushu-Palau Ridge,enriched mantle source injection during rifting prior to the Shikoku backarc basin opening

The northern Kyushu-Palau Ridge (KPR), remnant conjugate arc of the Izu-Ogasawara (Bonin)-Mariana (IBM) active arc, is dominated by basalt-andesite except for the Komahashi-Daini Seamount where acidic plutonic rocks of 38 Ma were recovered. These mafic to intermediate volcanics are produced by the rifting volcanism in the proto-IBM arc associated with spreading of the Shikoku Basin. The HFSE and HREE contents and ratios of these volcanics indicate enriched source mantle composition compared to recent volcanic front. The LILE ratios exhibit similar characteristics to reararc volcanism of the recent Izu arc, and some enriched volcanics exhibit high abundance of sediment melt inputs. Based on these observations and compilations of the published data set, the replacement event of the wedge mantle under the IBM arc occurred two times. The first event occurred between 45 and 38 Ma, with Pacific type mantle being replaced by depleted Indian type mantle. The second event occurred between 36 and 25 Ma, enriched mantle flowed from reararc side. The slab component during the proto-IBM arc rifting was a similar characteristic to recent reararc volcanism of the Izu arc, and sediment melt added in a local area.     

Toward policy integration: Assessing carbon capture and storage policies in Japan and Norway

The objective of this paper is to develop independent and systematic criteria for assessing CCS policy in terms of its level of policy integration. We believe that we should assess CCS policy in terms of the distance to an ideal integrated CCS policy in order to keep track of its trajectory toward sustainable development. After reviewing the existing literature of environmental policy integration, an assessment framework for integrated CCS policy is developed based on Arild Underdal's notion of ‘integrated policy’ then, its usefulness is demonstrated by applying it to CCS policies in Japan and Norway. In the final part, we summarize the findings of the cases and conclude with some observations regarding explanatory factors of the difference in terms of the achieved level of policy integration between Japan and Norway's CCS policies, and some policy implications derived from the analysis based on the framework.     

Uptake mechanism of anthropogenic CO<Subscript>2</Subscript> in the Kuroshio Extension region in an ocean general circulation model

The uptake mechanism of anthropogenic CO₂ in the Kuroshio Extension is examined by a Lagrangian approach using a biogeochemical model embedded in an ocean general circulation model. It is found that the uptake of anthropogenic CO₂ is caused mainly by the increase of pCO₂ dependency of seawater on temperature, which is caused by greater dissolved inorganic carbon concentration in the modern state than in the pre-industrial state. In contrast with the view of previous studies, the effect of the vertical entrainment, which brings waters that last contacted the atmosphere with the past lower CO₂ concentration, is comparatively small. Winter uptake of anthropogenic CO₂ increases with the rise of the atmospheric CO₂ level, while summer uptake is relatively stable, resulting in a larger seasonal cycle of the uptake. This increase is significant, especially in the Kuroshio Extension region. It is newly suggested that this increase in the Kuroshio Extension region is largely caused by the combined effects of the increased pCO₂ dependency of the sea water on the temperature and the seasonal difference in cooling.     

Layout design of rockbolts for natural ground reinforcement

The present study addresses a layout design of rockbolts for reinforcing natural ground structures applying a special optimization method, called multiphase layout optimization. Rockbolts are used to tighten loosed natural ground, and the layout of rockbolts are determined without sufficient information about the physical properties of the ground materials. Because of this uncertainty, unexpected deformation often occurs at the excavation surface of natural ground. In that case, it is requested to determine an effective layout of the additional rockbolts promptly with respect to the actual deformation at the construction site. However, it is not easy to determine the optimal layout because of its complexity, and consequently, it has no choice but to determine the layout in an empirical way. This study introduces a numerical approach to determine an optimal layout of rockbolts with respect to arbitrarily possible deformation of natural ground. The objective is to maximize the stiffness of the overall ground structure reinforced with rockbolts. For optimization, a gradient‐based optimization scheme is applied because of its numerical efficiency. It was verified from a series of numerical examples that this method has great potential to improve the stiffness of the overall ground structure and shows a certain applicability to a practical design. Copyright © 2013 John Wiley & Sons, Ltd.     

Box model analysis on phytoplankton production and grazing pressure in a eutrophic estuary

To determine the quantitative relationship between phytoplankton production and zooplankton grazing pressure in Atsumi Bay, a eutrophic and partially-mixed estuary, a series of investigations, including measurements of hydrographic conditions, dissolved oxygen, dissolved total nitrogen, particulate organic nitrogen, and phyto- and zooplankton biomass were conducted 13 times at intervals of 2–7 days in June and July 1984. Continuous measurements of water flow and salinity were also carried out to examine transverse flow and horizontal diffusivity. The supply of freshwater and nitrogen was estimated from given data. The changes of hydrographic condition, net photosynthetic rate and community primary production were calculated by a two-layered box model analysis. The grazing rate on phytoplankton obtained as the difference between net photosynthetic rate and community primary production was compared to the one estimated from zooplankton biomass and sardine,Sardinops melanosticta, biomass. The agreement between the data was remarkable in the upper layer, showing the grazing pressure on phytoplankton followed phytoplankton production, suggesting that a large part of produced phytoplankton was immediately grazed by zooplankton. Consequently, the community primary production was depressed to a fairly lower level. An important role of nutrient supply and water circulation, to limit phytoplankton production, was also confirmed. Dynamic response observed between the calculated grazing pressure and the biomass of phytoplankton and protozoa was also analyzed.