Structure and lattice vibrations of Mg-Al spinel solid solution

X-ray structure refinements have been made for nonstoichiometric (MgO · 3Al₂O₃) and stoichiometric Mg-Al spinels. Several structure variations with chemical composition have been observed and are discussed in relation to Al substitution in tetrahedral sites. Infrared reflection and Raman spectra of the single crystal of the nonstoichiometric spinel (MgO · 3Al₂O₃) have been measured and analyzed. The results obtained are compared with those reported for the stoichiometric sample. From the infrared and Raman frequencies reported for the stoichiometric Mg-Al spinel, which are partly complemented with our results, the effective ionic charges of the ions in MgAl₂O₄ have been estimated on the basis of the rigid ion model.     

Characteristics of vertical land movement and microearthquake activity in the northeastern Japan arc

Methods have been devised for analyzing vertical land movement and seismicity data using two-dimensional Chebychev functions and oblique projections. A filtering operation in the space domain is made possible by use of a two-dimensional Chebychev function. The oblique projections give an intuitive understanding of land deformation. Characteristic aspects of vertical land movement obtained by precise levelling and of the energy release of microearthquakes with depths shallower than 20 km in the northeastern Japan arc were investigated in detail applying these methods.Lineations with wavelength of about 20–60km trending towards NE—SW were found for both the land deformation and the seismicity. It should be noted that this trend is almost perpendicular to the direction of the strain migration and is related to other geophysical information.     

Multicomponent observation of crustal activity in the DPRI 800 m borehole close to the Nojima Fault

Abstract An 800 m borehole was drilled near the Nojima Fault, on which a strike–slip larger then 1 m occurred during the 1995 Hyogo-ken Nanbu earthquake ( M = 7.2). Crustal activity near the fault has been observed since May 1996 using a multicomponent instrument installed at the bottom of the borehole. Data of three components of strain, two components of tilt and temperature observed from May 1996 to December 1998 were analyzed. Long-term changes of strain and tilt show a north-east–south-west extension and southwards subsidence. As for the Earth tides and atmospheric effect, orientation of the principal axis of strain was mainly east-west and orientation of the maximum subsidence was mainly north-south. The observational data of strain had variations corresponding to a change in temperature at a depth of 800 m. The thermal expansion coefficient of the crust was calculated to be approximately 2.0 × 10⁻⁶/°K.     

Distribution of maximum water levels due to the Japan Sea Tsunami on 26 May 1983

By measuring the maximum water level of the traces attained by the Japan Sea Tsunami on 26 May 1983, we obtained the distribution along the west coast of the northeast Japan. The level reaches a maximum at the coast eastward of the epicenter and decreases with the relationship 8.6e ^–0.017x (m) with distancex (km) measured from the coast nearest to the epicenter. A small increase of levels was observed at coasts to the south of the tsunami source having distance larger than 200 km. With the aid of tide gauge records we revealed an excitation of edge wave which brought about the small increase of levels at the southern coast. In comparison with the decrease with distance obtained on the coasts of the main islands of Japan, some noticeable peaks were observed at several small islands. It is suggested that the reason why a short period component is predominant for the initial wave motion of tsunami is that the source region has depth of 3, 000 meters. The feature of wave period is discussed in comparison with that of the 1964 Niigata Tsunami.     

Vertical Distributions of Larvae of the Clam <Emphasis Type="Italic">Ruditapes philippinarum</Emphasis> and the Striped Horse Mussel <Emphasis Type="Italic">Musculista senhousia</Emphasis> in Eastern Ariake Bay,Southern Japan

We have examined the vertical distributions of planktonic bivalve larvae, particularly the clam Ruditapes philippinarum and the mussel Musculista senhousia which are common and abundant on tidal flats of eastern Ariake Bay, southern Japan. Submersible pumping gear was used to take samples at 2 stations every 2 hours during the spring tide over a whole tidal cycle and/or through daytime and nighttime. Water samples were pumped up from 3 to 5 depths from the surface to sea bottom. Regardless of tidal cycles, D-shaped larvae were concentrated near the surface, while umbo larvae were found at the surface to intermediate depths. On average, these larval densities were significantly higher at the station close to the shore than the offshore station, with no significant difference between daytime and nighttime and between flood and ebb tides at each station. The velocity and direction of water movement at both stations revealed remarkable difference between the surface and bottom waters. The larvae at the surface may quickly disperse and be transported elsewhere, while those in water close to the sea bottom may tend to be retained.     

Open Ocean Originated Phosphorus and Nitrogen in the Seto Inland Sea,Japan

The ratios of phosphorus and nitrogen originating from land and the open ocean in the Seto Inland Sea, which is the largest semi-enclosed coastal sea in Japan, have been estimated from data on total phosphorus and nitrogen loads and observed concentrations of total phosphorus and nitrogen. The ratios of land-origin and open-ocean-origin total phosphorus and nitrogen in the Seto Inland Sea are 0.28:0.72 and 0.19:0.81, respectively.     

Spin-up and spin-down processes of the large cold water mass of the Kuroshio south of Japan

Time variation of the cold water mass of the Kuroshio south of Japan, which was formed in August 1975 and disappeared in August 1980, is studied. Its lifecycle includes several repetitions of spin-down and spin-up processes. The spin-down (or the spin-up) process is accompanied by warming (cooling) of the cold water mass and descending (ascending) motion of the inner water. Expansion of the cold water area is also associated with the spin-up period while shrinking occurs in the spin-down period. The rate of spin-down of the cold water mass is approximately equal to that of the Gulf Stream rings. The spin-up process is not observed in the Gulf Stream rings and the longer lifetime of the cold water mass off Japan, in comparison with the Gulf Stream rings, is due to the existence of the spin-up periods. The spin-up process tends to occur in late spring to summer, and it seems to be related to the seasonal variation in intensity of the Kuroshio.     

Comparison of surface velocities determined from altimeter and drifting buoy data

Surface velocities determined from trajectory of a drifting buoy from March through November 1987 are compared with surface geostrophic velocities determined from sea surface dynamic topography (SSDT) obtained from altimetry data with the aid of long-term hydrographic observation data. In general, these velocities show similar temporal variations in both zonal and meridional components, except in a period when obvious error is found in the altimetric SSDT field. When the buoy was trapped by several mid-ocean meso-scale eddies, the comparison is especially good. Systematic discrepancy is found, however, when the buoy was in the Kuroshio region, because of using both temporally and spatially smoothed mean SSDT estimated from hydrographic data; instead, surface geostrophic velocities determined from the altimetric SSDT referred to the improved geoid model result in better comparison.     

Dredge petrology of the boninite‐ and adakite‐bearing Hahajima Seamount of the Ogasawara (Bonin) forearc: An ophiolite or a serpentinite seamount?§

Abstract During the Hakuho‐Maru KH03‐3 cruise and the Tansei‐Maru KT04‐28 cruise, more than 1000 rock samples were dredged from several localities over the Hahajima Seamount, a northwest–southeast elongated, rectangular massif, 60 km × 30 km in size, with a flat top approximately 1100 m deep. The rocks included almost every lithology commonly observed among the on‐land ophiolite outcrops. Volcanic rocks included mid‐oceanic ridge basalt (MORB)‐like tholeiitic basalt and dolerite, calc‐alkaline basalt and andesite, boninite, high‐Mg adakitic andesite, dacite, and minor rhyolite. Gabbroic rocks included troctolite, olivine gabbro, olivine gabbronorite (with inverted pigeonite), gabbro, gabbronorite, norite, and hornblende gabbro, and showed both MORB‐type and island arc‐type mineralogies. Ultramafic rocks were mainly depleted mantle harzburgite (spinel Cr? 50–80) and its serpentinized varieties, with some cumulate dunite, wehrlite and pyroxenites. This rock assemblage suggests a supra‐subduction zone origin for the Hahajima Seamount. Compilation of the available dredge data indicated that the ultramafic rocks occur in the two northeast–southwest‐oriented belts on the seamount, where serpentinite breccia and gabbro breccia have also developed, but the other areas are free from ultramafic rocks. Although many conical serpentinite seamounts 10 km in size are aligned along the Izu–Ogasawara (Bonin)–Mariana forearc, the Hahajima Seamount may be better interpreted as a fault‐bounded, uplifted massif composed of ophiolitic thrust sheets, resembling the Izki block of the Oman ophiolite in its shape and size. The ubiquitous roundness of the dredged rocks and their thin Mn coating (<2 mm) suggest that the Hahajima Seamount was uplifted above sealevel and wave‐eroded, like the present Macquarie Is., a rare example of ophiolite exposure in an oceanic setting. The Ogasawara Plateau on the Pacific Plate is adjacent to the east of the Hahajima Seamount, and collision and subduction of the plateau may have caused uplift of the forearc ophiolite body.     

Applied focused ion beam techniques for sample preparation of astromaterials for integrated nanoanalysis

Abstract— Sample preparation is always a critical step in the study of micrometer‐sized astromaterials available for study in the laboratory, whether their subsequent analysis is by electron microscopy or secondary ion mass spectrometry. A focused beam of gallium ions has been used to prepare electron transparent sections from an interplanetary dust particle (IDP), as part of an integrated analysis protocol to maximize the mineralogical, elemental, isotopic, and spectroscopic information extracted from one individual particle. In addition, focused ion beam (FIB) techniques have been employed to extract cometary residue preserved on the rims and walls of microcraters in 1100 series aluminum foils that were wrapped around the sample tray assembly on the Stardust cometary sample collector. Non‐ideal surface geometries and inconveniently located regions of interest required creative solutions. These include support pillar construction and relocation of a significant portion of sample to access a region of interest. Serial sectioning, in a manner similar to ultramicrotomy, is a significant development and further demonstrates the unique capabilities of focused ion beam microscopy for sample preparation of astromaterials.