Concentration,composition and sources of PAHs in the coastal sediments of the exclusive economic zone (EEZ) of Qatar,Arabian Gulf

Surface sediments were collected from sixteen locations in order to assess levels and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Qatar exclusive economic zone (EEZ). Samples were analyzed for 16 parent PAHs, 18 alkyl homologs and for dibenzothiophenes. Total PAHs concentration (∑PAHs) ranged from 2.6 ng g⁻¹ to 1025 ng g⁻¹. The highest PAHs concentrations were in sediments in and adjacent to harbors. Alkylated PAHs predominated most of the sampling locations reaching up to 80% in offshore locations. Parent PAHs and parent high molecular weight PAHs dominated location adjacent to industrial activities and urban areas. The origin of PAHs sources to the sediments was elucidated using ternary plot, indices, and molecular ratios of specific compounds such as (Ant/Phe + Ant), (Flt/Flt + Pyr). PAHs inputs to most coastal sites consisted of mixture of petroleum and combustion derived sources. However, inputs to the offshore sediments were mainly of petroleum origin.     

Evaluating the sensitivity of wetlands to climate change with remote sensing techniques

Wetlands are valuable ecosystems that provide many valuable services, yet many of these important ecosystems are at risk because of current trends in climate change. The Prairie Pothole Region (PPR) in the upper‐midwest of the United States and south‐central Canada, characterized by glacially sculpted landscapes and abundant wetlands, is one such vulnerable region. According to regional/global climate model predictions, drought occurrence will increase in the PPR region through the 21st century and thus will probably cause the amount of water in wetlands to decline. Water surface area (WSA) of Kidder County, ND, from 1984–2011 was measured by classifying TM/ETM+(Landsat Thematic Mapper / Enhanced Thematic Mapper Plus) images through the modified normalized difference water index. We then developed a linear model based on the WSA of these wetlands and historical climate data and used this to determine the wetland sensitivity to climate change and predict future wetlands WSA in the PPR. Our model based on Palmer drought severity index (PDSI) of the current year (PDSI_{t ? 0}) and of the previous two years (PDSI_{t ? 2}) can explain 79% of the annual wetland WSA variance, suggesting a high sensitivity of wetlands to drought/climate change. We also predicted the PPR wetlands WSA in the 21st century under A1B scenario (a mid‐carbon emission scenario) using simulated PDSI based on Intergovernmental Panel on Climate Change AR4 22‐model ensemble climate. According to our prediction, the WSA of the PPR wetlands will decrease to less than half of the baseline WSA (defined as the mean wetlands WSA of the 2000s) by the mid of the 21st century, and to less than one‐third by the 2080s, and will then slightly increase in the 2090s. This considerable future wetland loss caused only by climate change provides important implication to future wetland management and climate adaptation policy. Copyright © 2012 John Wiley & Sons, Ltd.     

Rare earth element composition of Paleogene vertebrate fossils from Toadstool Geologic Park,Nebraska, USA

Fossil bones and teeth from terrestrial environments encode unique rare earth and trace element (REE and TE) signatures as a function of redox conditions, pH, concentrations of complexing ligands, and water-colloid interactions. This signature is set early in the fossilization process and serves as a paleoenvironmental and paleoclimatic proxy. These signatures can also be used to interpret temporal and spatial averaging within vertebrate accumulations, and can help relocate displaced fossil bones back into stratigraphic context. Rare earth elements in vertebrate fossils from upper Eocene and Oligocene strata of Toadstool Geologic Park, northwestern Nebraska, record mixing and evolution of Paleogene vadose or groundwaters and variations in paleoenvironments. REE signatures indicate that HREE-enriched alkaline groundwater reacted with LREE- and MREE-enriched sediments to produce 3-component mixtures. REE signatures become increasingly LREE- and MREE-enriched toward the top of the studied section as the paleoenvironment became cooler and drier, suggesting that REE signatures may be climate proxies. Time series analysis suggests that REE ratios are influenced by cycles of ca. 1050, 800, 570, 440, and 225 ka, similar to some previously determined Milankovitch astronomical and climate periodicities.     

Strike-slip fault patterns on Europa: Obliquity or polar wander?

Variations in diurnal tidal stress due to Europa’s eccentric orbit have been considered as the driver of strike-slip motion along pre-existing faults, but obliquity and physical libration have not been taken into account. The first objective of this work is to examine the effects of obliquity on the predicted global pattern of fault slip directions based on a tidal-tectonic formation model. Our second objective is to test the hypothesis that incorporating obliquity can reconcile theory and observations without requiring polar wander, which was previously invoked to explain the mismatch found between the slip directions of 192 faults on Europa and the global pattern predicted using the eccentricity-only model. We compute predictions for individual, observed faults at their current latitude, longitude, and azimuth with four different tidal models: eccentricity only, eccentricity plus obliquity, eccentricity plus physical libration, and a combination of all three effects. We then determine whether longitude migration, presumably due to non-synchronous rotation, is indicated in observed faults by repeating the comparisons with and without obliquity, this time also allowing longitude translation. We find that a tidal model including an obliquity of 1.2°, along with longitude migration, can predict the slip directions of all observed features in the survey. However, all but four faults can be fit with only 1° of obliquity so the value we find may represent the maximum departure from a lower time-averaged obliquity value. Adding physical libration to the obliquity model improves the accuracy of predictions at the current locations of the faults, but fails to predict the slip directions of six faults and requires additional degrees of freedom. The obliquity model with longitude migration is therefore our preferred model. Although the polar wander interpretation cannot be ruled out from these results alone, the obliquity model accounts for all observations with a value consistent with theoretical expectations and cycloid modeling.     

High‐frequency water quality monitoring in an urban catchment: hydrochemical dynamics,primary production and implications for the Water Framework Directive

This paper describes the hydrochemistry of a lowland, urbanised river‐system, The Cut in England, using in situ sub‐daily sampling. The Cut receives effluent discharges from four major sewage treatment works serving around 190 000 people. These discharges consist largely of treated water, originally abstracted from the River Thames and returned via the water supply network, substantially increasing the natural flow. The hourly water quality data were supplemented by weekly manual sampling with laboratory analysis to check the hourly data and measure further determinands. Mean phosphorus and nitrate concentrations were very high, breaching standards set by EU legislation. Although 56% of the catchment area is agricultural, the hydrochemical dynamics were significantly impacted by effluent discharges which accounted for approximately 50% of the annual P catchment input loads and, on average, 59% of river flow at the monitoring point. Diurnal dissolved oxygen data demonstrated high in‐stream productivity. From a comparison of high frequency and conventional monitoring data, it is inferred that much of the primary production was dominated by benthic algae, largely diatoms. Despite the high productivity and nutrient concentrations, the river water did not become anoxic, and major phytoplankton blooms were not observed. The strong diurnal and annual variation observed showed that assessments of water quality made under the Water Framework Directive (WFD) are sensitive to the time and season of sampling. It is recommended that specific sampling time windows be specified for each determinand, and that WFD targets should be applied in combination to help identify periods of greatest ecological risk. © 2015 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.     

Association Between <Emphasis Type="BoldItalic">Fusarium</Emphasis> spp. on <Emphasis Type="BoldItalic">Spartina alterniflora</Emphasis> and Dieback Sites in Connecticut and Massachusetts

Sudden vegetation dieback (SVD) is defined as the loss and lack of recovery of smooth cordgrass (Spartina alterniflora) in salt marshes. A new species of a moderately pathogenic fungus called Fusarium palustre is consistently found in SVD sites, but greenhouse tests revealed that it is not capable of causing mortality of healthy plants. Similarly, root-knot nematodes (Meloidogyne spartinae) are also found in SVD sites, but their incidence in marshes affected by SVD is not known. To understand more about the ecology of F. palustre and M. spartinae, salt marshes along Connecticut’s Long Island Sound and Massachusetts’ Cape Cod that exhibited SVD and those that did not, were visited during the summers of 2007, 2008, and 2009. Belowground and aboveground tissues of smooth cordgrass plants from 18 marshes were removed, washed, and assayed for Fusarium spp. to determine if patterns between the incidence of the different species of Fusarium, their virulence on S. alterniflora, root-knot nematodes (M. spartinae), and the health of the marsh could be revealed. There were significantly more colonies of Fusarium growing from plants in SVD sites (6.1%) than in healthy marshes where no SVD was present (<1.0%). The incidence of Fusarium spp. from plants at the perimeter of the SVD site was not statistically different from asymptomatic plants 10–20 m from the SVD edge. The majority of isolates could be assigned to one of two species, F. palustre or another slightly pathogenic group called Fusarium cf. incarnatum (88% in 2007, 62% in 2008, and 96% in 2009). The ratio of F. palustre to F. cf. incarnatum was 6.7, 2.7, or 2.1 for 2007, 2008, or 2009, respectively. Greenhouse tests on healthy S. alterniflora revealed that isolates of F. palustre were more virulent than F. cf. incarnatum, regardless of whether they were recovered from plants in healthy marshes or in SVD sites. Root-knot nematodes were found sporadically and could not be associated with SVD. Factorial greenhouse experiments did not demonstrate any interaction between F. palustre and M. spartinae providing no experimental evidence that combining Fusarium and root-knot nematodes could cause mortality. The presence of Fusarium on S. alterniflora in healthy marshes also suggests an endophytic relationship that may subsequently function in the breakdown of tissue when plants are compromised.     

Volatile loss from melt inclusions in pyroclasts of differing sizes

We have investigated the loss of H₂O from olivine-hosted melt inclusions (MIs) by designing an experiment using tephra samples that cooled at different rates owing to their different sizes: ash, lapilli, and bomb samples that were deposited on the same day (10/17/74) of the sub-Plinian eruption of Volcán de Fuego in Guatemala. Ion microprobe, laser ablation-ICPMS, and electron probe analyses show that MIs from ash and lapilli record the highest H₂O contents, up to 4.4 wt%. On the other hand, MIs from bombs indicate up to 30 % lower H₂O contents (loss of ~1 wt% H₂O) and 10 % post-entrapment crystallization of olivine. This evidence is consistent with the longer cooling time available for a bomb-sized clast, up to 10 min for a 3–4-cm radius bomb, assuming conductive cooling and the fastest H diffusivities measured in olivine (D~10^?9 to 10^?10 m²/s). On the other hand, several lines of evidence point to some water loss prior to eruption, during magma ascent and degassing in the conduit. Thus, results point to both slower post-eruptive cooling and slower magma ascent affecting MIs from bombs, leading to H₂O loss over the timescale of minutes to hours. The important implication of this study is that a significant portion of the published data on H₂O concentrations in olivine-hosted MIs may reflect unrecognized H₂O loss via diffusion. This work highlights the importance of reporting clast and MI sizes in order to assess diffusive effects and the potential benefit of using water loss as a chronometer of magma ascent.     

http://www.sciencedirect.com/science/article/pii/S1674987113000595

Magmatic oxide deposits in the～260 Ma Emeishan Large Igneous Province(ELIP),SW China and northern Vietnam,are important sources of Fe,Ti and V.Some giant magmatic Fe-Ti-V oxide deposits, such as the Panzhihua,Hongge,and Baima deposits,are well described in the literature and are hosted in layered mafic-ultramafic intrusions in the Panxi region,the central ELIP.The same type of ELIP- related deposits also occur far to the south and include the Anyi deposit,about 130 km south of Panzhihua,and the Mianhuadi deposit in the Red River fault zone.The Anyi deposit is relatively small but is similarly hosted in a layered mafic intrusion.The Mianhuadi deposit has a zircon U-Pb age of～260 Ma and is thus contemporaneous with the ELIP.This deposit was variably metamorphosed during the Indosinian orogeny and Red River faulting.Compositionally,magnetite of the Mianhuadi deposit contains smaller amounts of Ti and V than that of the other deposits,possibly attributable to the later metamorphism.The distribution of the oxide ore deposits is not related to the domal structure of the ELIP.One major feature of all the oxide deposits in the ELIP is the spatial association of oxide-bearing gabbroic intrusions,syenitic plutons and high-Ti flood basalts.Thus,we propose that magmas from a mantle plume were emplaced into a shallow magma chamber where they were evolved into a field of liquid immiscibility to form two silicate liquids,one with an extremely Fe-Ti-rich gabbroic composition and the other syenitic.An immiscible Fe-Ti-(P) oxide melt may then separate from the mafic magmas to form oxide deposits.The parental magmas from which these deposits formed were likely Fe-Ti-rich picritic in composition and were derived from enriched asthenospheric mantle at a greater depth than the magmas that produced sulfide-bearing intrusions of the ELIP.     

Book reviews

APPLIED GEOGRAPHY: Issues, Questions and Concerns (Geo Journal Library Vol. 15) edited by M. S. Kenzer. 16 × 24 cm, x and 210 pages. Kluwer: Dordrecht 1989 (ISBN 0 7923 04381).

WINE AND THE VINE: An Historical Geography of Viticulture and the Wine Trade by T. Unwin. 16 × 24 cm, xvi and 409 pages. Routledge: London 1991 (ISBN 0 415 13120 6) $A155.00 (hard); distributed by The Law Book Co.

WATERFRONT SYDNEY 1860–1920 by G. Aplin and J. Storey. 26 × 18 cm. 144 pages. Allen & Unwin: Sydney 1991 (first published 1984) (ISBN 1 86373 098 2) $A24.95 (soft).

Australian Geographer 23 (2), November 1992

INDUSTRIAL LOCATION: Principles and Policies (Second Edition) by K. Chapman and D. F. Walker. 15 × 23 cm, xiii and 322 pages. Basil Black‐well: Oxford 1991 (ISBN 0 631 16789 7) $A39.95 (soft).

INTERNATIONALISATION OF AUSTRALIA'S SERVICE INDUSTRIES by J. V. Langdale. 17 × 25 cm, iv and 373 pages. Australian Government Publishing Service, for Department of Industry, Technology and Commerce: Canberra 1991 (ISBN 0 644 13841 6).

TOURISM AND GOLD IN KAKADU: The Impact of Current and Potential Natural Resource Use on the Northern Territory Economy by B. Knapman, O. Stanley and J. Lea. 21 × 29 cm, vi and 49 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1179 4).

ABORIGINAL AUSTRALIA AND THE ‘NEW FEDERALISM’ INITIATIVE (Discussion Paper No. 2) by G. J. Crough. 14 × 21 cm, 42 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1325 8).

AUSTRALIAN NATIONHOOD AND OUTBACK INDIGENOUS PEOPLES (Discussion Paper No. 1) by P. Jull. 14 × 21 cm, 38 pages. North Australia Research Unit, Australian National University: Darwin 1991 (ISBN 0 7315 1309 6).

MIGRATION AND DEVELOPMENT IN THE SOUTH PACIFIC (Pacific Research Monograph No. 24) edited by J. Connell. 17 × 25 cm, xii and 199 pages. National Centre for Development Studies, Australian National University: Canberra 1990 (ISBN 0 07315 0668 5) $A25.00 (soft).

POPIULESIN BLONG HONIARA: Olketa Popiulesin Map Blong 1986 Sensis. HONIARA: 1986 Census Atlas (Statistics Office Occasional Paper No. 4 / Board of Development Studies Monograph No. 1) by A.C. Walsh. 21 × 29 cm, vii and 95 pages. Department of Statistics: Honiara and Board of Development Studies, Massey University: Palmerston North 1990 (ISSN 0114 8834) $NZ34.00 in New Zealand, $NZ38.00 elsewhere (soft).

DOI MOI: Vietnam's Renovation Policy and Performance (Political and Social Change Monograph No. 14) edited by D. K. Forbes, T. H. Hull, D. G. Marr and B. Brogan. 15 × 22 cm, xiv and 263 pages. Department of Political and Social Change, Australian National University: Canberra 1991 (ISBN 0 7315 1303 7).