Gemini/GMOS spectra of globular clusters in the Virgo giant elliptical NGC 4649

NGC 4649 (M60) is one of a handful of giant Virgo ellipticals. We have obtained Gemini/GMOS (Gemini North Multi-Object Spectrograph) spectra for 38 globular clusters (GCs) associated with this galaxy. Applying the multi-index  χ²  minimization technique of Proctor and Sansom with the single stellar population models of Thomas, Maraston and Korn, we derive ages, metallicities and α-element abundance ratios. We find several young (2–3 Gyr old) supersolar metallicity GCs, while the majority are old (>10 Gyr), spanning a range of metallicities from solar to  [Z/H]=−2  . At least two of these young GCs are at large projected radii of 17–20 kpc. The galaxy itself shows no obvious signs of a recent starburst, interaction or merger. A trend of decreasing α-element ratio with increasing metallicity is found.     

Thinking globally and siting locally – renewable energy and biodiversity in a rapidly warming world

Increasing greenhouse gas emissions are projected to raise global average surface temperatures by 3?–4 °C within this century, dramatically increasing the extinction risk for terrestrial and freshwater species and severely disrupting ecosystems across the globe. Limiting the magnitude of warming and its devastating impacts on biodiversity will require deep emissions reductions that include the rapid, large-scale deployment of low-carbon renewable energy. Concerns about potential adverse impacts to species and ecosystems from the expansion of renewable energy development will play an important role in determining the pace and scale of emissions reductions and hence, the impact of climate change on global biodiversity. Efforts are underway to reduce uncertainty regarding wildlife impacts from renewable energy development, but such uncertainty cannot be eliminated. We argue the need to accept some and perhaps substantial risk of impacts to wildlife from renewable energy development in order to limit the far greater risks to biodiversity loss owing to climate change. We propose a path forward for better reconciling expedited renewable energy development with wildlife conservation in a warming world.     

Photoluminescence of zircon (ZrSiO4) doped with REE3+ (REE = Pr, Sm, Eu, Gd, Dy, Ho, Er)

The photoluminescence properties of synthetic zircon, ZrSiO₄, doped with REE³⁺ (REE = Pr, Sm, Eu, Gd, Dy, Ho, Er) were investigated using combined excitation and emission spectroscopy. All samples showed luminescence characteristics of intra-ion energy transitions, similar to other lanthanide-doped materials. However, the relative intensities were dependent on the energy of excitation and the presence of charge-transfer bands were inferred from excitation spectra. From the data, we conclude that the lanthanides in zircon occur in more than one type of coordination. Energy transfer between different lanthanides was observed in some co-doped samples and emissions that were unassigned in previous studies have been assigned to specific lanthanides based on excitation spectroscopy.     

The 2dF Galaxy Redshift Survey: galaxy luminosity functions per spectral type

We calculate the optical b _J luminosity function (LF) of the 2dF Galaxy Redshift Survey (2dFGRS) for different subsets defined by their spectral properties. These spectrally selected subsets are defined using a new parameter, η , which is a linear combination of the first two projections derived from a Principal Component Analysis. This parameter η identifies the average emission- and absorption-line strength in the galaxy rest frame spectrum, and hence is a useful indicator of the present star formation. We use a total of 75 000 galaxies in our calculations, chosen from a sample of high signal-to-noise ratio, low-redshift galaxies observed before 2001 January. We find that there is a systematic steepening of the faint-end slope ( α ) as one moves from passive  ( α =-0.54)  to active  ( α =-1.50)  star-forming galaxies, and that there is also a corresponding faintening of the rest frame characteristic magnitude   M *-5 log₁₀( h )  (from −19.6 to −19.2). We also show that the Schechter function provides a poor fit to the quiescent (Type 1) LF for very faint galaxies  [ M _{b J}-5 log₁₀( h )  fainter than −16.0], perhaps suggesting the presence of a significant dwarf population. The LFs presented here give a precise confirmation of the trends seen previously in a much smaller preliminary 2dFGRS sample, and in other surveys. We also present a new procedure for determining self-consistent k -corrections, and investigate possible fibre-aperture biases.     

Submicroscopic accessory minerals overprinting clay mineral REE patterns (celadonite–glauconite group examples)

Samples of glauconite, representing different stages of glauconitisation, as well as different formation environments, were analysed for rare earth elements (REE) and other trace elements using a combination of bulk sample and spatially-resolved in situ techniques. The results indicate that the high-sensitivity, spatially-resolved technique of laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) produces values up to two orders of magnitude lower than the bulk sample analyses. This suggests that submicroscopic rare earth element-bearing phases are distributed within the glauconite aggregates comprising the bulk samples. Analytical scanning electron microscopy (ASEM) revealed the presence of micrometre-sized grains of apatite and pore filling precipitates of an unidentified (REE, Ca)-phosphate (approximate composition Ca_0.3–0.4(Ce_0.4La_0.1–0.2Nd_0.1)PO₄) in some glauconite grains.The inherent REE concentrations of the glauconite aggregates (i.e., glauconite crystallites without accidental mechanical inclusions or authigenic, not layer silicate mineral precipitates) was found to be relatively low (e.g., typically less than 100 ppm), and this value decreased with increasing glauconitisation (smectite–mica transformation through a series of recrystallisation processes). These results suggest that the REEs substitute for Ca in the interlayer space of the layer silicate structure and, therefore, the REE content decreases as Ca is progressively removed from the interlayer (smectite–mica transition).LA-ICP-MS, when combined with electron probe microanalysis (EPMA) or ASEM, offers an opportunity to exclude submicroscopic accessory minerals from glauconite trace element analyses, and so produces reliable trace element data for the respective minerals which host those elements.These results illustrate that accessory minerals are difficult to eliminate from clay samples, and that care needs to be taken in the interpretation of clay mineral REE distributions, irrespective of the aggregation state of the studied clay (i.e., whether finely dispersed within the sedimentary rock, or forming millimetre-sized aggregates). Model calculations showed that authigenic apatite associated with the studied green marine clays tends to have higher REE content than “bioapatites”, the total REE content being above 10 000 ppm.     

Carbon dioxide flux techniques performed during GasEx-98

A comprehensive study of air–sea interactions focused on improving the quantification of CO₂ fluxes and gas transfer velocities was performed within a large open ocean CO₂ sink region in the North Atlantic. This study, GasEx-98, included shipboard measurements of direct covariance CO₂ fluxes, atmospheric CO₂ profiles, atmospheric DMS profiles, water column mass balances of CO₂, and measurements of deliberate SF₆–³He tracers, along with air–sea momentum, heat, and water vapor fluxes. The large air–sea differences in partial pressure of CO₂ caused by a springtime algal bloom provided high signals for accurate CO₂ flux measurements. Measurements were performed over a wind speed range of 1–16 m s⁻¹ during the three-week process study. This first comparison between the novel air-side and more conventional water column measurements of air–sea gas transfer show a general agreement between independent air–sea gas flux techniques. These new advances in open ocean air–sea gas flux measurements demonstrate the progress in the ability to quantify air–sea CO₂ fluxes on short time scales. This capability will help improve the understanding of processes controlling the air–sea fluxes, which in turn will improve our ability to make regional and global CO₂ flux estimates.     

A natural example of the simultaneous operation of free-face dissolution and pressure solution

The dissolution of crinoid columnals during tectonic deformation of the Appalachian Plateau was enhanced by stress-induced changes of chemical potential of calcite in solution at the surface of the crinoid columnal. Pressure solution on the outside surface occurred within areas of highest normal stress developed at grain to grain contacts whereas free-face dissolution on the inside bore (the axial canal) of the columnal occurred where parts of the crystal lattice next to the surface were subject to the highest strain, as indicated by the presence of mechanical twins. For free-face dissolution, the chemical potential of the solute is affected more by the larger strain energy associated with mechanical twinning than strain energy from elastic strain prior to mechanical twinning of the crystal lattice. These observations suggest that free-face dissolution as well as pressure solution may contribute significantly to dissolution during rock deformation by diffusive mass transfer.     

Petrogenesis of ca 1.50 Ga granitic gneiss of the Coompana Block: filling the ‘magmatic gap’ of Mesoproterozoic Australia

The Coompana Block is an essentially unknown basement province that separates the Gawler Craton of South Australia from the Yilgarn Craton of Western Australia. Previously unstudied granitic gneiss intersected by deep drilling in the Coompana Block represents an important period of within-plate magmatism during a time of relative magmatic quiescence in the Australian Proterozoic. Granitic gneiss intersected at ～1500 m depth in Mallabie 1 diamond drillhole is metaluminous and dominantly granodioritic in composition. The granodiorites have distinctive A-type chemistry characterised by high contents of Zr, Nb, Y, Ga, LREE with low Mg#, Sr, CaO and HREE. U – Pb LA-ICPMS dating of magmatic zircons provides an age of 1505 ± 7 Ma, interpreted as the crystallisation age of the granite protolith. ? _Nd values are high with respect to exposed crust of the Musgrave Province and Gawler Craton, and range from +1.2 to +3.3 at 1.5 Ga. The granitic gneiss is interpreted to be a fractionated melt of a mantle-derived parental melt. The tectonic environment into which the precursor granite was emplaced is not clear. One possibility is emplacement within an extensional environment. Regardless, the granitic gneiss intersected in Mallabie 1 represents magmatic activity during the ‘Australian Mesoproterozoic magmatic gap’ of ca 1.50 – 1.35 Ga, and is a possible source for ca 1.50 detrital zircons found in sedimentary rocks of Tasmania and Antarctica, and metasedimentary rocks of the eastern Musgrave Province.     

Some useful approximations to generalized ray theory for regional distance seismograms

Summary . Seismograms recorded at regional distances (2°–12°) are quite complicated due to the waveguide nature of the crust. Generalized ray theory can be used to model the body waves in this distance range but a very large number of rays is required. Here I present a series of approximations to streamline generalized ray theory for the waveguide problem. If a layer over a half-space is used for the structure, then the de Hoop contour for a given ray is most strongly dependent on the fastest velocity of any leg of the ray. This results in analytic approximations to locate the contour. Each ray has two body wave arrivals (a headwave and a reflected arrival) so the displacement response of the ray need only be evaluated at a few points in time about the two arrival times and interpolated in between. A change in structure (increasing crustal thickness or Pn velocity) most strongly affects the relative timing of the headwave and the reflected arrival, so it is possible to 'stretch' or 'squeeze' the waveform of a representative model to simulate a whole suite of models.
Also discussed is the applicability of a single layer over a half-space structure for modelling the observed regional distance waveforms for shallow earthquakes. At periods greater than a few seconds crustal layering can be replaced by a single layer having the appropriate average velocities. Lateral variations in crustal thickness with scale lengths of less than about 100 km can also be modelled with a simple horizontal layer of appropriate average thickness.     

Contrasting Carbon Dioxide Inputs and Exchange in Three Adjacent New England Estuaries

Four surveys of the adjacent Cocheco, Bellamy, and Oyster estuaries reveal spatial heterogeneity with respect both to river-born carbon dioxide (CO₂) fluxes and CO₂ exchange with the atmosphere (−17 to 51 mmol m⁻² day⁻¹), a finding partially explained by CO₂ inputs from contributing watersheds. Nonuniform nutrient and organic carbon loading from upstream rivers and within the estuaries is considered as a mechanism resulting in the variability between estuaries. Conditions during the surveys included spring river runoff and phytoplankton blooms, drought with baseline river flow, and a historic flood which led to a large CO₂ release to the atmosphere. This study highlights the variability of CO₂ transport and release found between proximate estuaries over a wide range of flow conditions.