An experimental investigation of antigorite dehydration in natural silica-enriched serpentinite

Piston cylinder experiments were performed to constrain the pressure and temperature conditions for two high-pressure antigorite dehydration reactions found in silica-enriched serpentinites from Cerro del Almirez (Nevado–Filábride Complex, Betic Cordillera, southern Spain). At 630–660°C and pressures greater than 1.6 GPa, antigorite first reacts with talc to form orthopyroxene ± chlorite + fluid. We show that orthopyroxene + antigorite is restricted to high-pressure metamorphism of silica-enriched serpentinite. This uncommon assemblage is helpful in constraining metamorphic conditions in cold subduction environments, where antigorite serpentinites have no diagnostic assemblages over a large pressure and temperature range. The second dehydration reaction leads to the breakdown of antigorite to olivine + orthopyroxene + chlorite + fluid. The maximum stability of antigorite is found at 680°C at 1.9 GPa, which also corresponds to the maximum pressure limit for tremolite coexisting with olivine + orthopyroxene. The high aluminium (3.70 wt% Al₂O₃) and chromium contents (0.59 wt% Cr₂O₃) of antigorite in the investigated starting material is responsible for the expansion of the serpentinite stability to 60–70°C higher temperatures at 1.8 GPa than the antigorite stability calculated in the Al-free system. The antigorite from our study has the highest Al–Cr contents among all experimental studies and therefore likely constraints the maximum stability of antigorite in natural systems. Comparison of experimental results with olivine–orthopyroxene–chlorite–tremolite assemblages outcropping in Cerro del Almirez indicates that peak metamorphic conditions were 680–710°C and 1.6–1.9 GPa.     

A new species of the Gondwanan genus Cardiolaria Munier-Chalmas in the Sandbian of northwestern Argentina: Paleobiogeographic considerations

A new species of afghanodesmatid, Cardiolaria benicioi, is recorded from Sandbian strata of northwestern Argentina. This species confirms the strong paleobiogeographic relationships between the western Argentina basin and other peri-Gondwanan areas. The Mid-Late Ordovician distribution of bivalves fit well into the Mediterranean Province defined upon brachiopod and trilobite faunas. Similitudes between Tremadocian and Floian bivalves from the western Gondwana and the peri-Gondwanan areas indicate that such ‘Mediterranean’ paleobiogeographic patterns can be traced back well into the Early Ordovician.     

Seismic reliability of traditional and innovative concentrically braced frames

Structural engineering problems are always affected by many sources of uncertainty, such as aleatory of material properties, applied loads and earthquake intensity, therefore, seismic assessment of structures should be based on probabilistic methods. Since PBSD (Performance‐based Seismic Design) philosophy was formulated, many researches have been conducted in this field in order to develop simple and accurate procedures for evaluating structural reliability. An important contribution has been provided by Jalayer and Cornell, who have developed a closed‐form expression to evaluate the mean annual frequency of exceeding a defined limit state. In this paper, by assuming the record‐to‐record variability as the only source of uncertainty, the seismic reliability of concentrically braced frames designed according to traditional and innovative methodologies is investigated, and a comparison between their performances is presented. In particular, two design methodologies have been applied: Eurocode 8 provisions and a new design methodology based on a rigorous application of ‘capacity design’ criteria. The innovative reduced section solution strategy, based on the reduction of cross sections at bracing member ends, has also been analysed. Copyright © 2011 John Wiley & Sons, Ltd.     

U�CPb isotopic ages and Hf isotope composition of zircons in Variscan gabbros from central Spain: evidence of variable crustal contamination

Ion microprobe U?CPb analyses of zircons from three gabbroic intrusions from the Spanish Central System (SCS) (Talavera, La Solanilla and Navahermosa) yield Variscan ages (300 to 305?Ma) in agreement with recent studies. Only two zircon crystals from La Solanilla massif gave slightly discordant Paleoproterozoic ages (1,848 and 2,010?Ma). Hf isotope data show a relatively large variation with the juvenile end-members showing ?Hf_i values as high as +3.6 to +6.9 and +1.5 to +2.9 in the Navahermosa and Talavera gabbros, respectively. These positive ?Hf_i values up to +6.9 might represent the composition of the subcontinental mantle which generates these SCS gabbros. This ?Hf_i range is clearly below depleted mantle values suggesting the involvement of enriched mantle components on the origin of these Variscan gabbros, and is consistent with previous whole-rock studies. The presence of zircons with negative ?Hf_i values suggest variable, but significant, crustal contamination of the gabbros, mainly by mixing with coeval granite magmas. Inherited Paleoproterozoic zircons of La Solanilla gabbros have similar trace element composition (e.g. Th/U ratios), but more evolved Hf-isotope signatures than associated Variscan zircons. Similar inherited ages have been recorded in zircons from coeval Variscan granitoids from the Central Iberian Zone. Granitic rocks have Nd model ages (T_DM) predominantly in the range of 1.4 to 1.6?Ga, suggesting a juvenile addition during the Proterozoic. However, Hf crustal model ages of xenocrystic Proterozoic zircons in La Solanilla gabbro indicate the presence of reworked Archean protoliths (T_DM2 model ages of 3.0 to 3.2?Ga) incorporated into the hybridized mafic magma.     

Fatty acid profiles indicate the habitat of mud snails Hydrobia ulvae within the same estuary: Mudflats vs. seagrass meadows

Mud snails Hydrobia ulvae occupy different habitats in complex estuarine ecosystems. In order to determine if fatty acid profiles displayed by mud snails can be used to identify the habitat that they occupy within the same estuary, fatty acids of H. ulvae from one mudflat and one seagrass meadow in the Ria de Aveiro (Portugal) were analyzed and compared to those displayed by microphytobenthos (MPB), the green leaves (epiphyte-free) of Zostera noltii, as well as those exhibited by the epiphytic community colonizing this seagrass. MPB and epiphytic diatom-dominated samples displayed characteristic fatty acids, such as 16:1n-7 and 20:5n-3, while 18:2n-6 and 18:3n-3 were the dominant fatty acids in the green leaves of Z. noltii. Significant differences between the fatty acid profiles of H. ulvae specimens sampled in the mudflat and the seagrass meadow could be identified, with those from the mudflat displaying higher levels of fatty acids known to be characteristic of MPB. This result points towards the well known existence of grazing activity on MPB by mud snails. The fatty acid profiles displayed by H. ulvae inhabiting the seagrass meadows show no evidence of direct bioaccumulation of the two most abundant polyunsaturated fatty acids of Z. noltii (18:2n-6 and 18:3n-3) in the mud snails, which probably indicates that either these compounds can be metabolized to produce energy, used as precursors for the synthesis of essential fatty acids, or that the snails do not consume seagrass leaves at all. Moreover, the fatty acid profiles of mud snails inhabiting the seagrass meadows revealed the existence of substantial inputs from microalgae, suggesting that the epiphytic community colonizing the leaves of Z. noltii displays an important role on the diet of these organisms. This assumption is supported by the high levels of 20:5n-3 and 22:6n-3 recorded in mud snails sampled from seagrass meadows. In conclusion, fatty acid analyses of H. ulvae can be successfully used to identify the habitat occupied by these organisms within the same estuary (e.g. mudflats and seagrass meadows) and reveal the existence of contrasting dietary regimes.     

Pliocene�CQuaternary contourites along the northern Gulf of Cadiz margin: sedimentary stacking pattern and regional distribution

This study reports novel findings on the Pliocene?CQuaternary history of the northern Gulf of Cadiz margin and the spatiotemporal evolution of the associated contourite depositional system. Four major seismic units (P1, P2, QI and QII) were identified in the Pliocene?CQuaternary sedimentary record based on multichannel seismic profiles. These are bounded by five major discontinuities which, from older to younger, are the M (Messinian), LPR (lower Pliocene revolution), BQD (base Quaternary discontinuity), MPR (mid-Pleistocene revolution) and the actual seafloor. Unit P1 represents pre-contourite hemipelagic/pelagic deposition along the northern Gulf of Cadiz margin. Unit P2 reflects a significant change in margin sedimentation when contourite deposition started after the Early Pliocene. Mounded elongated and separated drifts were generated during unit QI deposition, accompanied by a general upslope progradation of drifts and the migration of main depocentres towards the north and northwest during both the Pliocene and Quaternary. This progradation became particularly marked during QII deposition after the mid-Pleistocene (MPR). Based on the spatial distribution of the main contourite depocentres and their thickness, three structural zones have been identified: (1) an eastern zone, where NE?CSW diapiric ridges have controlled the development of two internal sedimentary basins; (2) a central zone, which shows important direct control by the Guadalquivir Bank in the south and an E?CW Miocene palaeorelief structure in the north, both of which have significantly conditioned the basin-infill geometry; and (3) a western zone, affected in the north by the Miocene palaeorelief which favours deposition in the southern part of the basin. Pliocene tectonic activity has been an important factor in controlling slope morphology and, hence, influencing Mediterranean Outflow Water pathways. Since the mid-Pleistocene (MPR), the sedimentary stacking pattern of contourite drifts has been less affected by tectonics and more directly by climatic and sea-level changes.     

Multiple provenance of detrital zircons from the Permian–Triassic boundary in the Bükk Mts., Hungary

Detailed zircon analyses were carried out on samples from the Bálvány North section, which contains the Permian–Triassic boundary. A fine-grained sandstone bed within the “boundary shale” contains a significant amount of zircon crystals. Pupin morphological, scanning electron microscopy [secondary electron, back-scattered electron, cathodoluminescence (CL)] and laser ablation inductively coupled mass spectrometry (LA-ICP-MS) investigations were done in selected single grains to combine morphological information with radiometric ages, and infer the provenance of zircons. Three populations are distinguished on the basis of Pupin morphology. Their centres of gravity are S17, S2 and P1. The LA-ICP-MS radiometric ages reveal three main age groups and a smaller one, apart from a few scattered old ages. The largest group, comprising ca. 50% of the measured grains, has an age of 470–440 Ma. The two other main groups, which together represent ca. 25% of the measured grains, are around 280 and 600 Ma. The 280 Ma group contains slightly more grains than the 600 Ma group. A small group has an age of 370–340 Ma. In addition, there are some older grains with ages of 850, 969, 1,050 and 2,150 Ma. Based on the zircon morphology no clear separation of the different age groups could be made. Both the 280 Ma and the 470–440 Ma age groups tend to show zircon crystals derived from three types of sources: crustal granites, calc-alkaline granitoids and alkali granites and/or their volcanic equivalents. Zircons in the 450 Ma group have a magmatic rim around their altered, relict core, as revealed by CL images. Post-magmatic processes also affected the rim. The age of the core is possibly reset during the formation of the magmatic rim. This suggestion is supported by the LA-ICP-MS data, because no difference was seen between the core and the rim. The different roundness of the zircons, the well-sorted crystals and the at least five different source rocks indicate previous concentration of the grains, before their transportation into the “boundary shale”. Austroalpine and Southern Alpine rocks could be the sources of the zircon crystals, which fit well into the paleogeographical model of the area, which suggests that the Bükk Mts. was located in the foreground of the Alpine units.     

Climate and human impact on a meromictic lake during the last 6,000 years (Montcortès Lake,Central Pyrenees,Spain)

Sedimentological, mineralogical and compositional analyses performed on short gravity cores and long Kullenberg cores from meromictic Montcortès Lake (Pre-Pyrenean Range, NE Spain) reveal large depositional changes during the last 6,000 cal years. The limnological characteristics of this karstic lake, including its meromictic nature, relatively high surface area/depth ratio (surface area ~0.1 km²; z _max = 30 m), and steep margins, facilitated deposition and preservation of finely laminated facies, punctuated by clastic layers corresponding to turbidite events. The robust age model is based on 17 AMS ¹⁴C dates. Slope instability caused large gravitational deposits during the middle Holocene, prior to 6 ka BP, and in the late Holocene, prior to 1,600 and 1,000 cal yr BP). Relatively shallower lake conditions prevailed during the middle Holocene (6,000–3,500 cal years BP). Afterwards, deeper environments dominated, with deposition of varves containing preserved calcite laminae. Increased carbonate production and lower clastic input occurred during the Iberian-Roman Period, the Little Ice Age, and the twentieth century. Although modulated by climate variability, changes in sediment delivery to the lake reflect modifications of agricultural practices and population pressure in the watershed. Two episodes of higher clastic input to the lake have been identified: 1) 690–1460 AD, coinciding with an increase in farming activity in the area and the Medieval Climate Anomaly, and 2) 1770–1950 AD, including the last phase of the Little Ice Age and the maximum human occupation in late nineteenth and early twentieth centuries.     

Armorican provenance for the mélange deposits below the Lizard ophiolite (Cornwall,UK): evidence for Devonian obduction of Cadomian and Lower Palaeozoic crust onto the southern margin of Avalonia

Devonian sedimentary rocks of the Meneage Formation within the footwall of the Lizard ophiolite complex in SW England are thought to have been derived from erosion of the over-riding Armorican microplate during collision with Avalonia and the closure of the Rheic Ocean. We further test this hypothesis by comparison of their detrital zircon suites with those of autochthonous Armorican strata. Five samples analysed from SW England (Avalonia) and NW France (Armorica) have a bimodal U–Pb zircon age distribution dominated by late Neoproterozoic to middle Cambrian (c. 710–518 Ma) and Palaeoproterozoic (c. 1,800–2,200 Ma) groupings. Both can be linked with lithologies exposed within the Cadomian belt as well as the West African craton, which is characterized by major tectonothermal events at 2.0–2.4 Ga. The detrital zircon signature of Avalonia is distinct from that of Armorica in that there is a much larger proportion of Mesoproterozoic detritus. The common provenance of the samples is therefore consistent with: (a) derivation of the Meneage Formation mélange deposits from the Armorican plate during Rheic Ocean closure and obduction of the Lizard Complex and (b) previous correlation of quartzite blocks within the Meneage Formation with the Ordovician Grès Armoricain Formation of NW France.     

Effect of Void Ratio on <Emphasis Type="Italic">K</Emphasis><Subscript>0</Subscript> of a Sand by Means of Triaxial Stress-Path Testing

This paper presents an experimental technique using a computer controlled triaxial test to evaluate K ₀, not requiring the use of any radial measurement transducers. It uses commercial software that applies a ramp of radial stress with back volume measurement and control. The method is applicable only to saturated specimens in drained conditions. The equipment used is briefly described, as well as the testing procedures. Results of laboratory tests on Toyoura sand specimens, with four different initial void ratios, are presented. For the preparation of all specimens tested, a dry funnel deposition method with undercompaction was used. It was concluded that, for the initial void ratios tested and for the stress level induced, stress-strain behavior fell in a narrow range the \(K_{0}^{NC}\) values were slightly higher for looser specimens, although lower than predicted by Jaky’s equation.