利用δ~(53)Cr定量评价Cr(Ⅵ)还原程度的实验研究

地下水污染的"原位修复"是当今国际上净化地下水最具发展前景的新技术,但对铬污染地下水"原位修复"尚未有科学有效的评价方法。定量评价地下水中Cr(Ⅵ)的被还原程度成为保护与修复铬污染地下水的关键问题。通过室内Cr(Ⅵ)的还原实验,分析Cr(Ⅵ)在还原过程中铬稳定同位素变化规律,研究其分馏机理,探索利用铬同位素定量评价地下水中Cr(Ⅵ)还原程度的可行性。研究结果表明:Cr(Ⅵ)在被还原成Cr(Ⅲ)过程中,发生明显的同位素分馏,即反应物中53Cr逐渐富集,同时生成物中52Cr逐渐富集;分馏过程可用瑞利分馏模型描述,分馏系数α为常数0.99842。表明δ53Cr能够定量评价水体中Cr(Ⅵ)的还原程度,为评价地下水铬污染修复提供了新途径。     

坡缕石粘土固定辣根过氧化酶处理硝基酚废水

以坡缕石粘土、淀粉、水玻璃为原料,研究了固定化酶载体的制备工艺,探究了固定化酶载体在辣根过氧化酶(HRP)降解硝基酚废水中的作用,并探讨了反应时间、酶浓度、H2O2及硝基酚浓度对降解效果的影响。结果表明,固定化酶载体的最佳制备工艺为:水玻璃12%,淀粉20%,煅烧温度550℃,煅烧时间2 h;固定化酶对硝基酚的去除效果明显高于原酶;固定化酶去除水中硝基酚的最佳反应条件为:反应时间1.5 h,加酶量150 U,H2O2浓度0.12%,硝基酚浓度100 mg/L;固定化酶重复使用7次后对硝基酚的去除率仍高于60%。     

Application of bacteria-plant association in biodegradation of diesel oil pollutants in soil

The bacteria and plants were associated to remove diesel oil pollutants from soil.Three efficiently degrading bacteria(named strains Q10,Q14 and Q18,respectively) were isolated.Two plants(alfalfa and Indian mustard) were selected to form the association.Biodegradation of diesel oil pollutants in soil was accelerated by bacteria-plants association.The main results are summarized as follows.The plants-bacteria association was more effective in biodegradation of diesel oil pollutants in soil than in respective experiments carried out with plants or bacteria alone.Strain Q18-Indian mustard association resulted in the maximum diesel oil reduction(69.18%).The activities of catalase and polyphenol oxidase in soil were enhanced and microbial populations in soil,especially in rhizosphere,were also stimulated in the treatment of bacteria-plant association.Overall,the soil conditions might be improved by alfalfa or Indian mustard to benefit the growth of bacteria,which resulted in degradation of diesel oil pollutants more effective by the bacteria-plant association.The bacteria-plants association may be a better approach to the removal of diesel oil pollutants from soil.     

有机溴化物的溴同位素测试技术及其生物地球化学指示意义

有机溴化物已成为继有机氯化物之后又一值得关注的全球性新兴持久性有机污染物。稳定Br同位素测试技术的快速发展,为有机溴化物生物地球化学循环研究提供了更为有效的技术支撑。在综述稳定Br同位素研究进展的基础上认为：①基于GC-MC-ICPMS技术基础上的有机单体Br同位素（CSIA-OBr）是Br同位素研究的主要趋势,难点是...     

Microscopic observation of pyrenoids in Order Ulvales (Chlorophyta) collected from Qingdao coast

Pyrenoids found in green algae Order Ulvales have taxonomical significance.Their morphology,microstructure,and the location and number in the cells have been widely used as identification criteria. As these traits can be affected by environmental conditions,it is necessary to look for other different characteristics.Here pyrenoids in several algae species collected along the Qingdao coast were studied for such purpose. The morphology and distribution of pyrenoids in the cells,as well as their change in diff...     

Finite element analysis on impact of foundation treatment in bridgehead transition section upon bridge piles

In order to decrease relative settlement, foundation treatment plays an extremely important role in bridgehead transition section, especially, the situation of building the bridge piles firstly, and th...     

Laboratory tests of vortex-induced vibrations of a long flexible riser pipe subjected to uniform flow

Laboratory tests have been conducted on vortex-induced vibration (VIV) of a long flexible riser towed horizontally in a wave basin. The riser model has an external diameter of 16 mm and a total length of 28.0 m giving an aspect ratio of about 1750. Reynolds numbers ranged from about 3000 to 10,000. Fiber optic grating strain gages are adopted to measure the dynamic response in both cross-flow and in-line directions. The cross-flow vibrations were observed to vibrate at modes up to 6 and the in-line reached up to 12. The fundamental response frequencies can be predicted by a Strouhal number of about 0.18. Multi-mode responses and the asymmetry of the bare pipe response in uniform flow were observed and analyzed. The experimental results confirmed that the riser pipe vibrated multi-modally despite it being subject to a uniform current profile and all of the excited modes vibrated at the Strouhal frequency. The asymmetrical distribution of displacement mainly resulted from the modal composition. Higher harmonics of the VIV response such as the third, fourth and fifth harmonics frequencies were found to be steady over the entire duration of the test even if they varied along the length of the riser pipe.     

依兰盆地达连河组油页岩沉积特征及分布规律

依兰盆地为伸展作用下形成的半地堑式断陷盆地,油页岩发育于古近系达连河组中。油页岩与煤层伴生,分布在煤层顶部,是最主要的含矿层位。它形成于湖泊体系与沼泽体系,主要发育在水进体系域与高水位体系域中。其中,高水位体系域即上煤层顶板存在油页岩密集段,使得盆地油页岩资源潜力大幅度提高。达连河矿区是油页岩富集成矿的中心区带,东西向断裂控制着达连河组油页岩矿层的埋深以及展布成矿过程。     

依兰盆地达连河组油页岩成矿模式及类型

提要：达连河油页岩含矿区位于黑龙江省依兰地区,该区是一个半地堑式断陷盆地。古近系达连河组为一个完整的三级层序,油页岩形成于水进体系域和高水位体系域发育时期。本文认为达连河组油页岩存在两种成矿模式,即湖泊-沼泽相油页岩成矿模式、浅湖相-半深湖相油页岩成矿模式;不同成矿类型油页岩分布于层序的不同体系域,古地貌型、沉积密集段型油页岩成矿常分布于水进体系域,沉积密集段型、气候型油页岩成矿位于高水位体系域。     

华夏陆块闽西南坳陷二叠系含有机质页岩组成及赋气孔隙特征

华夏陆块从早古生代以来,经历了多期推覆与伸展构造的叠加。文中对华夏陆块闽西南仙亭、曲斗等地区/矿区附近及井下所采集的含有机质页岩样品进行实验测试,分析了有机质参数、矿物组成及赋气孔隙参数,将对中国华夏陆块闽西南二叠系页岩的储层特征研究及页岩气勘探前景预测提供理论依据。研究结果表明：(1)采用TOC残余碳分析实验、荧光显微镜及显微镜光度计实验等,认为闽西南二叠系页岩含碳量中等,为0.15%~2.71%;有机质成熟度高,为3.51%~4.33%。(2)储层矿物组成方面,利用X射线衍射实验进行全岩分析,结果显示黏土矿物占38.2%~49.6%,含量较高,主要为伊利石,含少量的绿泥石、蒙皂石;常见非黏土矿物主要为石英,均占45%以上;钾长石和斜长石含量较少,占1%~2.3%。(3)储层孔渗性方面：有效孔隙度为0.3%~11.4%,渗透率为(0.006 5~0.987)×10-3μm2;利用低温液氮吸附实验等对纳米级孔隙进行分析,认为部分小孔(2~50 nm)的孔容、比表面积较大,其次为微孔(小于2 nm)和大孔(大于50 nm)。此外,累计比表面积和累计孔容呈现出较好的正相关性,纳米孔隙累计比表面积、累计孔容与孔径之间的关系表明,闽西南二叠系页岩气主要赋存于微孔和小于10 nm的小孔中。依照页岩储层评价标准,闽西南二叠系海陆交互相页岩在有机质丰富、有机质成熟度、页岩厚度、矿物组成、孔隙结构等方面符合页岩气开发最低标准,具有勘探开发前景。