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881.
882.
Jiangrong Xiao Tianyou Peng Dingning Ke Ling Zan Zhenghe Peng 《Physics and Chemistry of Minerals》2007,34(4):275-285
CdS/rectorite nanocomposite was synthesized via a cation-exchange reaction followed by a sulfurization process. The obtained
samples were characterized by using X-ray diffraction (XRD), fourier transform infrared spectra (FTIR), transmission electron
microscope (TEM), UV-Vis diffuse reflectance spectra (DRS), and thermal analysis. The measured results indicate that CdS species
in the composites exist in the form of pillars and nanoparticles, the crystallized CdS particles are in the hexagonal symmetry.
The photocatalytic activities of the pillared nanocomposite were enhanced significantly comparing with the bare rectorite
and the pure CdS. Moreover, the photostabilities of the obtained nanocomposites are also better than that of the pure CdS
due to the hosts retard the photocorrosion of the CdS. 相似文献
883.
Seismic Passive Earth Pressure Behind Non-vertical Retaining Wall Using Pseudo-dynamic Analysis 总被引:3,自引:0,他引:3
Priyanka Ghosh 《Geotechnical and Geological Engineering》2007,25(6):693-703
This paper shows a detailed study on the seismic passive earth pressure behind a non-vertical cantilever retaining wall using
pseudo-dynamic analysis. A planar failure surface has been considered behind the retaining wall. The effects of soil friction
angle, wall inclination, wall friction angle, horizontal and vertical earthquake acceleration on the passive earth pressure
have been explored. Unlike the Mononobe–Okabe method, which incorporates pseudo-static analysis, the present analysis predicts
a nonlinear variation of passive earth pressure along the wall. The results have been thoroughly compared with the existing
values in the literature. 相似文献
884.
Effect of chemical fertilizers on the fractionation of Cu,Cr and Ni in contaminated soil 总被引:1,自引:0,他引:1
Jie Liu Chang-Qun Duan Yi-Nian Zhu Xue-Hong Zhang Cheng-Xian Wang 《Environmental Geology》2007,52(8):1601-1606
Effect of chemical fertilizers (urea, NH4Cl, Ca(NO3)2, KCl and KH2PO4) on the fractionation of Cu, Cr and Ni was studied by a 4-month incubation experiment. Using sequential extraction procedure,
it was found that the application of fertilizers could change the distribution of Cu, Cr and Ni in the fractions of soil.
Applying urea (CO(NH2)2) significantly decreased the concentrations of Cu, Cr and Ni in water soluble plus exchangeable (WE) fraction, but increased
those in Fe–Mn oxides bound (FM) fraction (p < 0.01). However, application of NH4Cl caused an increase in the WE fraction by 27.7% for Cu, 111.5% for Cr and 20.4% for Ni. The CO(NH2)2 raised the soil pH from 4.51 to 4.96, whereas NH4Cl lowered the pH of soil by 0.44 units. The WE fraction of the three heavy metals was significantly increased, while the
FM fraction was significantly decreased by adding KCl (p < 0.01). Moreover, the supply of KH2PO4 reduced the WE and carbonate bound (CB) fractions of Cu, Cr and Ni in the soil, however, it raised Cu and Ni in the residual
(RS) fraction and Cr in the FM fraction. In addition, the mobility index indicated that KCl and NH4Cl increased the mobility of Cu, Cr and Ni in the soil, whereas urea and KH2PO4 decreased the mobility of the three metals in the soil. These results suggest that applying chemical fertilizers does not
only provide plant nutrients, but may also change the speciation and mobility of heavy metals in the soil. 相似文献
885.
Vadim S. Kamenetsky Andrey A. Gurenko 《Contributions to Mineralogy and Petrology》2007,153(4):465-481
The origin of compositional heterogeneities among the magmas parental to mid-ocean ridge basalts (MORB) was investigated using
a single rock piece of the olivine-phyric basalt from 43°N, Mid-Atlantic Ridge (AII D11-177). The exceptional feature of this
sample is presence of very primitive olivine crystals (90–91 mol% Fo) that are significantly variable in terms of CaO (0.15–0.35 wt%).
A population of low-Ca olivine (0.15–0.25 wt% CaO) is also notably distinct from high-Ca olivine population in AII D11-177,
and primitive MORB olivine in general, in having unusual assemblage of trapped mineral and glass inclusions. Mineral inclusions
are represented by high-magnesian (Mg# 90.7–91.1 mol%) orthopyroxene and Cr-spinel, distinctly enriched in TiO2 (up to 5 wt%, c.f. <1 wt% in common MORB spinel). Glass inclusions associated with orthopyroxene and high-Ti Cr-spinel have
andesitic compositions (53–58 wt% SiO2). Compared to the pillow-rim glass and “normal” MORB inclusions, the Si-rich glass inclusions in low-Ca olivine have strongly
reduced Ca and elevated concentrations of Ti, Na, K, P, Cl, and highly incompatible trace elements. Strong variability is
recorded among glass inclusions within a single olivine phenocrysts. We argue that the observed compositional anomalies are
mineralogically controlled, and thus may arise from the interaction between hot MORB magmas and crystal cumulates in the oceanic
crust or magma chamber. 相似文献
886.
Sven-Ulf Weber Michael Grodzicki Werner Lottermoser Günther J. Redhammer Gerold Tippelt Johann Ponahlo Georg Amthauer 《Physics and Chemistry of Minerals》2007,34(7):507-515
Natural alexandrite Al2BeO4:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by 57Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The 57Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe3+ and Fe2+, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe3+ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe3+ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe3+ on M1. 相似文献
887.
Bolivia is a country with high levels of poverty and inequality among its peoples and regions. For the nation and its urban
and rural areas, trends in the social and spatial distribution of poverty (and extreme poverty) are identified from 1976 to
2003 using UBN data with minor support where appropriate from poverty lines. The main survey between 1992 and 2001 uses composite
and selected UBN to track detailed poverty change for the country’s nine departments, its ten largest cities and a selection
of other smaller urban and rural municipalities. Because of rising background increases in population in the various surveyed
administrative units, many instances of relative reductions in poverty are accompanied by rising absolute increases. Marked
spatial variations in poverty and development in the country over the last several decades are identified as the main driver
for the country’s quickening pace of rural–urban migration. As a result, the paper concludes by assessing two different but
closely related views. One investigation tests the notion that because more poor people have been living in Bolivia’s cities
than in its rural areas since the mid to late 1990s, rapid rural–urban migration has simply shifted the locus of poverty from
the countryside to the cities in a process called, the ‘urbanisation of poverty.’ A second, more challenging, investigation
assesses the view that the flow of poor rural people to the better serviced urban areas of Bolivia has actually acted to alleviate
national poverty levels. 相似文献
888.
Manfred Baer Nicolas Deichmann Jochen Braunmiller John Clinton Stephan Husen Donat Fäh Domenico Giardini Philipp Kästli Urs Kradolfer Stefan Wiemer 《Swiss Journal of Geoscience》2007,100(3):517-528
This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during
2006. During this period, 572 earthquakes and 91 quarry blasts were detected and located in the region under consideration.
Of these earthquakes, two occurred in conjunction with the construction of the new Gotthard railway tunnel and 165 were induced
artificially by the stimulation of a proposed geothermal reservoir beneath the city of Basel. With 20 events with M
L
≥ 2.5, five of which were artificially induced, the seismic activity in the year 2006 was far below the average over the
previous 31 years. Nevertheless, six events were felt by the public, most prominently the strongest of the induced Basel events
(M
L
3.4), which caused some non-structural building damage. Noteworthy are also the two earthquakes near Cortaillod (M
L
3.2), on the shore of Lake Neuchatel, and in Val Mora (M
L
3.5), between the Engadin and Val Müstair, as well as the 42 aftershocks of the M
L
4.9 Vallorcine earthquake, between Martigny and Chamonix, of September 2005.
Editorial handling: Stefan Bucher 相似文献
889.
Limitations of real-time models for forecasting river flooding from monsoon rainfall 总被引:1,自引:0,他引:1
Very intense rainfall during the southwest and northeast monsoons causes severe river flooding in India. Some traditional
techniques used for real-time forecasting of flooding involve the relationship between effective rainfall and direct surface
runoff, which simplifies the complex interactions between rainfall and runoff processes. There are, however, serious problems
in deducing these variables in real time, so it is highly desirable to have a real-time flood forecasting model that would
directly relate the observed discharge hydrograph to the observed rainfall. The storage routing model described by Baba and
Hoshi (1997), Tanaka et al. (1997), and Baba et al. (2000), and a simplified version of this model, have been used to compute observed river discharge directly from observed hourly
rainfall. This method has been used to study rainfall–runoff data of the Ajay River Basin in eastern India. Five intense rainfall
events of this basin were studied. Our results showed that the Nash–Sutcliffe efficiency of discharge prediction for these
five events was 98.6%, 94.3%, 86.9%, 85.6%, and 67%. The hindcast for the first two events is regarded as completely satisfactory
whereas for the next two events it is deemed reasonable and for the fifth it is unsatisfactory. It seems the models will yield
accurate hindcast if the rainfall is uniform over the drainage basin. When the rainfall is not uniform the performance of
the model is unsatisfactory. In future this problem can, in principle, be corrected by using a weighted amount if rainfall
is based upon multiple rain-gauge observations over the drainage basin. This would provide some measure of the dispersion
in the rainfall. The model also seems unable to simulate flooding events with multiple peaks. 相似文献
890.
Anil Misra Lance A. Roberts Steven M. Levorson 《Geotechnical and Geological Engineering》2007,25(1):65-77
Load displacement analysis of drilled shafts can be accomplished by utilizing the “t-z” method, which models soil resistance
along the length and tip of the drilled shaft as a series of springs. For non-linear soil springs, the governing differential
equation that describes the soil-structure interaction may be discretized into a set of algebraic equations based upon finite
difference methods. This system of algebraic equations may be solved to determine the load–displacement behavior of the drilled
shaft when subjected to compression or pullout. By combining the finite difference method with Monte Carlo simulation techniques, a probabilistic load–displacement analysis can be conducted. The probabilistic analysis is advantageous
compared to standard factor of safety design because uncertainties with the shaft–soil interface and tip properties can be
independently quantified. This paper presents a reliability analysis of drilled shaft behavior by combining the finite difference
technique for analyzing non-linear load–displacement behavior with Monte Carlo simulation method. As a result we develop probabilistic relationships for drilled shaft design for both total stress (undrained)
and effective stress (drained) parameters. The results are presented in the form of factor of safety or resistance factors
suitable for serviceability design of drilled shafts. 相似文献