Internal waves in the earth's core

This paper investigates possible long-period oscillations of the earth's fluid outer core. Equations describing free oscillations in a stratified, self-gravitating, rotating fluid sphere are developed using a regular perturbation on the equations of hydrodynamics. The resulting system is reduced to a finite set of ordinary differential equations by ignoring the local horizontal component of the earth's angular velocity vector, Ω, and retaining only the vertical component. The angular dependence of the eigensolutions is described by Hough functions, which are solutions to Laplace's tidal equation.
The model considered here consists of a uniform solid elastic mantle and inner core surrounding a stratified, rotating, inviscid fluid outer core. The quantity which describes the core's stratification is the Brunt—Väisälä frequency N , and for particular distributions of this parameter, analytical solutions are presented. The interaction of buoyancy, and rotation results in two types of wave motion, the amplitudes of which are confined predominantly to the outer core: (1) internal gravity waves which exist when N ² > 0, and (2) inertial oscillations which exist when N ²<4Ω². For a model with a stable density stratification similar to that proposed by Higgins & Kennedy (1971), the resulting internal gravity wave eigenperiods are all at least 8 hr, and the fundamental modes have periods of at least 13 hr. A model with an unstable density stratification admits no internal gravity waves but does admit inertial oscillations whose eigenperiods have a lower bound of 12hr.     

Hydrostatic compression of galenobismutite (PbBi<Subscript>2</Subscript>S<Subscript>4</Subscript>): elastic properties and high-pressure crystal chemistry

A single-crystal sample of galenobismutite was subjected to hydrostatic pressures in the range of 0.0001 and 9 GPa at room temperature using the diamond-anvil cell technique. A series of X-ray diffraction intensities were collected at ten distinct pressures using a CCD equipped 4-circle diffractometer. The crystal structure was refined to R1(|F₀| > 4σ) values of approximately 0.05 at all pressures. By fitting a third-order Birch-Murnaghan equation of state to the unit-cell volumes V ₀ = 700.6(2) ų, K ₀ = 43.9(7) GPa and dK/dP = 6.9(3) could be determined for the lattice compression. Both types of cations in galenobismutite have stereochemically active lone electron pairs, which distort the cation polyhedra at room pressure. The cation eccentricities decrease at higher pressure but are still pronounced at 9 GPa. Galenobismutite is isotypic with CaFe₂O₄ (CF) but moves away from the idealised CF-type structure during compression. Instead of the two octahedral cation sites and one bi-capped trigonal-prismatic site, PbBi₂S₄ attains a new high-pressure structure characterised by one octahedral site and two mono-capped trigonal-prismatic sites. Analyses of the crystal structure at high pressure confirm the preference of Bi for the octahedral site and the smaller one of the two trigonal-prismatic sites.     

Long-period (30 days1 year) electromagnetic sounding and the electrical conductivity of the lower mantle beneath Europe

The C -response connects the magnetic vertical component and the horizontal gradient of the horizontal components of electromagnetic variations and forms the basis for deriving the conductivitydepth profile of the Earth. Time-series of daily mean values at 42 observatories typically with 50 years of data are used to estimate C -responses for periods between 1 month and 1  yr. The Z : Y method is applied, which means that the vertical component is taken locally whereas the horizontal components are used globally by expansion in a series of spherical harmonics.
In combination with results from previous analyses, the method yields consistent results for European observatories in the entire period range from a few hours to 1  yr, corresponding to penetration depths between 300 and 1800  km.
1-D conductivity models derived from these results show an increase in conductivity with depth z to about 2  S  m^-1 at z =800  km, and almost constant conductivity between z =800 and z =2000  km with values of 310  S  m^-1, in good agreement with laboratory measurements of mantle material. Below 2000  km the conductivity is poorly resolved. However, the best-fitting models indicate a further increase in conductivity to values between 50 and 150  S  m^-1.     

Temporary-creep and post-creep properties of aquaculture netting materials

Creep in materials and structures may lead to increasing strains, permanent deformations, change in mechanical properties and rupture at loads significantly smaller than the breaking strength. In this paper, we present data on temporary-creep properties, recovery of strain post creep and post-creep tensile properties of a selection of Raschel knitted netting materials. Creep strain in wet netting materials subjected to a creep target load of 10–90% of average force at break for 30 min varied from 1.6% to 3.5%. The rate of creep decreased with time and decreased target load. The recovery of strain post creep was relatively fast and approximately half of the creep strain was elastic. Post-creep tensile testing showed that the length and force at break were not significantly affected by the creep load history. However, due to permanent deformations of the specimens from the creep test, the nominal breaking strain decreased and the stiffness increased with increased creep target load.     

Flow and transport through clay membrane barriers

Flux equations for liquid and solute migration through clay barriers that behave as semi-permeable membranes used in waste containment and remediation applications, known as clay membrane barriers (CMBs), are discussed. The results of a simplified analysis of flow through a geosynthetic clay liner (GCL) using measured values for the chemico-osmotic efficiency coefficient (ω) of the GCL indicate a total liquid flux that counters the outward Darcy (hydraulic) flux due to chemico-osmosis associated with clay membrane behavior of the GCL. Also, the solute (contaminant) flux through the GCL is reduced relative to the solute flux that would occur in the absence of membrane behavior due to chemico-osmotic counter advection and solute restriction. Since diffusion commonly controls solute transport through GCLs and other low-permeability clay barriers, the implicit (empirical) correlation between ω and the effective salt-diffusion coefficient of the migrating contaminant is an important consideration with respect to contaminant restriction in CMBs.     

Is Ocean Acidification an Open-Ocean Syndrome? Understanding Anthropogenic Impacts on Seawater pH

Ocean acidification due to anthropogenic CO₂ emissions is a dominant driver of long-term changes in pH in the open ocean, raising concern for the future of calcifying organisms, many of which are present in coastal habitats. However, changes in pH in coastal ecosystems result from a multitude of drivers, including impacts from watershed processes, nutrient inputs, and changes in ecosystem structure and metabolism. Interaction between ocean acidification due to anthropogenic CO₂ emissions and the dynamic regional to local drivers of coastal ecosystems have resulted in complex regulation of pH in coastal waters. Changes in the watershed can, for example, lead to changes in alkalinity and CO₂ fluxes that, together with metabolic processes and oceanic dynamics, yield high-magnitude decadal changes of up to 0.5 units in coastal pH. Metabolism results in strong diel to seasonal fluctuations in pH, with characteristic ranges of 0.3 pH units, with metabolically intense habitats exceeding this range on a daily basis. The intense variability and multiple, complex controls on pH implies that the concept of ocean acidification due to anthropogenic CO₂ emissions cannot be transposed to coastal ecosystems directly. Furthermore, in coastal ecosystems, the detection of trends towards acidification is not trivial and the attribution of these changes to anthropogenic CO₂ emissions is even more problematic. Coastal ecosystems may show acidification or basification, depending on the balance between the invasion of coastal waters by anthropogenic CO₂, watershed export of alkalinity, organic matter and CO₂, and changes in the balance between primary production, respiration and calcification rates in response to changes in nutrient inputs and losses of ecosystem components. Hence, we contend that ocean acidification from anthropogenic CO₂ is largely an open-ocean syndrome and that a concept of anthropogenic impacts on marine pH, which is applicable across the entire ocean, from coastal to open-ocean environments, provides a superior framework to consider the multiple components of the anthropogenic perturbation of marine pH trajectories. The concept of anthropogenic impacts on seawater pH acknowledges that a regional focus is necessary to predict future trajectories in the pH of coastal waters and points at opportunities to manage these trajectories locally to conserve coastal organisms vulnerable to ocean acidification.     

A diatom‐based reconstruction of summer sea‐surface salinity in the Southern Okinawa Trough,East China Sea,over the last millennium

A high‐resolution diatom record from site MD05‐2908 in the Southern Okinawa Trough, East China Sea, reveals pronounced multidecadal‐ to centennial‐scale palaeoceanographic changes throughout the last millennium. Summer sea‐surface salinity (SSS) was reconstructed using a weighted averaging partial least squares diatom‐based training set. The reconstructed SSS shows slightly decreasing values during the period AD 905–1930 with considerable fluctuations superimposed on this general trend. Relatively high‐salinity conditions during the interval AD 905–1450 probably suggest a low flood frequency in north‐eastern Taiwan. Furthermore, the high SSS values are associated with a strong and stable influence of the Kuroshio Current on the Southern Okinawa Trough during the Medieval Climate Anomaly. The period AD 1450–1930 is characterized by three low‐salinity intervals (AD 1450–1500, AD 1625–1725 and AD 1770–1880) separated by periods of relatively high salinity. The low SSS intervals indicate increased freshwater discharge into the Southern Okinawa Trough during the Little Ice Age, probably as a result of higher flood frequencies in north‐eastern Taiwan. Spectral and wavelet analyses suggest that this pattern was linked to multidecadal variations in summer SSS, presumably associated with the Pacific Decadal Oscillation. Copyright © 2012 John Wiley & Sons, Ltd.