Modelling particle residence times in agricultural river basins using a sediment budget model and fallout radionuclide tracers

Contemporary patterns in river basin sediment dynamics have been widely investigated but the timescales associated with current sediment delivery processes have received much less attention. Furthermore, no studies have quantified the effect of recent land use change on the residence or travel times of sediment transported through river basins. Such information is crucial for understanding contemporary river basin function and responses to natural and anthropogenic disturbances or management interventions. To address this need, we adopt a process‐based modelling approach to quantify changes in spatial patterns and residence times of suspended sediment in response to recent agricultural land cover change. The sediment budget model SedNet was coupled with a mass balance model of particle residence times based on atmospheric and fluvial fluxes of three fallout radionuclide tracers (⁷Be, excess ²¹⁰Pb and ¹³⁷Cs). Mean annual fluxes of suspended sediment were simulated in seven river basins (38–920 km²) in south‐west England for three land cover surveys (1990, 2000 and 2007). Suspended sediment flux increased across the basins from 0.5–15 to 1.4–37 kt y^‐1 in response to increasing arable land area between consecutive surveys. The residence time model divided basins into slow (upper surface soil) and rapid (river channel and connected hillslope sediment source area) transport compartments. Estimated theoretical residence times in the slow compartment decreased from 13–48 to 5.6–14 ky with the increase in basin sediment exports. In contrast, the short residence times for the rapid compartment increased from 185–256 to 260–368 d as the modelled connected source area expanded with increasing sediment supply from more arable land. The increase in sediment residence time was considered to correspond to longer sediment travel distances linked to larger connected source areas. This novel coupled modelling approach provides unique insight into river basin responses to recent environmental change not otherwise available from conventional measurement techniques. © 2014 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Voltammetric estimation of iron(III) thermodynamic stability constants for catecholate siderophores isolated from marine bacteria and cyanobacteria

Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.     

Testing the fidelity of thermometers at ultrahigh temperatures

A highly residual granulite facies rock (sample RG07‐21) from Lunnyj Island in the Rauer Group, East Antarctica, presents an opportunity to compare different approaches to constraining peak temperature in high‐grade metamorphic rocks. Sample RG07‐21 is a coarse‐grained pelitic migmatite composed of abundant garnet and orthopyroxene along with quartz, biotite, cordierite, and plagioclase with accessory rutile, ilmenite, zircon, and monazite. The inferred sequence of mineral growth is consistent with a clockwise pressure–temperature (P–T) evolution when compared with a forward model (P–T pseudosection) for the whole‐rock chemical composition. Peak metamorphic conditions are estimated at 9 ± 0.5 kbar and 910 ± 50°C based on conventional Al‐in‐orthopyroxene thermobarometry, Zr‐in‐rutile thermometry, and calculated compositional isopleths. U–Pb ages from zircon rims and neocrystallized monazite grains yield ages of c. 514 Ma, suggesting that crystallization of both minerals occurred towards the end of the youngest pervasive metamorphic episode in the region known as the Prydz Tectonic Event. The rare earth element compositions of zircon and garnet are consistent with equilibrium growth of these minerals in the presence of melt. When comparing the thermometry methods used in this study, it is apparent that the Al‐in‐orthopyroxene thermobarometer provides the most reliable estimate of peak conditions. There is a strong textural correlation between the temperatures obtained using the Zr‐in‐rutile thermometer––maximum temperatures are recorded by a single rutile grain included within orthopyroxene, whereas other grains included in garnet, orthopyroxene, quartz, and biotite yield a range of temperatures down to 820°C. Ti‐in‐zircon thermometry returns significantly lower temperature estimates of 678–841°C. Estimates at the upper end of this range are consistent with growth of zircon from crystallizing melt at temperatures close to the elevated (H₂O undersaturated) solidus. Those estimates, significantly lower than the calculated temperature of this residual solidus, may reflect isolation of rutile from the effective equilibration volume leading to an activity of TiO₂ that is lower than the assumed value of unity.     

Turbulent heat fluxes by profile and inertial dissipation methods: analysis of the atmospheric surface layer from shipboard measurements during the SOFIA/ASTEX and SEMAPHORE experiments

Heat flux estimates obtained using the inertial dissipation method, and the profile method applied to radiosonde soundings, are assessed with emphasis on the parameterization of the roughness lengths for temperature and specific humidity. Results from the inertial dissipation method show a decrease of the temperature and humidity roughness lengths for increasing neutral wind speed, in agreement with previous studies. The sensible heat flux estimates were obtained using the temperature estimated from the speed of sound determined by a sonic anemometer. This method seems very attractive for estimating heat fluxes over the ocean. However allowance must be made in the inertial dissipation method for non-neutral stratification. The SOFIA/ASTEX and SEMAPHORE results show that, in unstable stratification, a term due to the transport terms in the turbulent kinetic energy budget, has to be included in order to determine the friction velocity with better accuracy. Using the profile method with radiosonde data, the roughness length values showed large scatter. A reliable estimate of the temperature roughness length could not be obtained. The humidity roughness length values were compatible with those found using the inertial dissipation method.     

3He, 20,21,22Ne, 14C, 10Be, 26Al,and 36Cl in magnetic fractions of cosmic dust from Greenland and Antarctica

Abstract— We report on studies of the concentrations of cosmogenic nuclides in the magnetic fraction of cosmic dust particles recovered from the South Pole Water Well (SPWW) and from Greenland. Our results confirm that cosmic dust material from these locations contains measurable amounts of cosmogenic nuclides. The Antarctic particles (and possibly those from Greenland as well) also contain minor amounts of solar Ne. Concentrations of cosmogenic nuclides are consistent with irradiation of this material as small objects in space, with exposure ages similar to the expected Poynting‐Robertson (P‐R) lifetimes of 50–200 kyr for particles 25–100 μm in size.     

A macro-scale flood risk model for Jamaica with impact of climate variability

Floods account for more than half of the global hydrometeorological risks. Severe floods cause significant economic shocks and loss of lives, particularly for developing countries such as Jamaica. There is need for more information on the present and projected flood risks to justify macro-scale planning for climate change adaptation and facilitate the decision-making processes. In this study, a catalogue of 198 flood events occurring between 1678 and 2010 is compiled for Jamaica and used to examine the climatology, occurrence, trends, causes and duration of the island’s severe events. The annual flood risk is estimated to be a loss of life rate of 4 persons and estimated annual damage of USD96.3 million per annum in 2010 values and approximately 0.84 % of GDP per annum. Macro-scale models for flood risks (deaths and damages) are also developed using data from the flood catalogue and maximum precipitation at the town and parish level. The models examine the relationship between flood risks (death and damages) and extreme rainfall depths and intensities. Future climate risks of loss of lives and damages are predicted to increase 11 and 9 %, respectively, to 4.4 persons and USD105.2 million per annum.     

利用卫星长波长地球物理位场对东亚地区深部结构的研究

有研究表明从中国北部经黄海、朝鲜半岛、日本海至日本本州岛存在一个大型断裂带,被称为“北纬40°断裂带”.为了验证该断裂带的存在性,本文通过GRACE和CHAMP卫星的位场数据中的大尺度区域重力和磁力异常来研究该区的大型构造特征.区域性研究范围为24°N~56°N,90°E~150°E,详细研究范围为32°N~42°N,122°E~132°E.2008年Taylor等利用CHAMP卫星2005年6月至12月收集的轨道数据,从测量数据中消除地核和外部产生磁场效应,经化磁极之后得到磁异常图,从中来追踪构造特征,并根据地质和地球物理资料建立了数学模型来进行解释.本文在此基础上,增加了GRACE卫星2003年10月份测量的重力异常场数据.实测差分位场数据利用高斯-勒让德求积法转换为垂向重力异常值,通过减去最新地球重力场模型（EGM96）的场值来去除波长超过1100 km的长波长异常,所得的重力异常数据和磁场数据进行比较.为了能从中得到研究区的共同构造特征,建立一个球面棱柱模型进行正演模拟、并进行重、磁异常场的波数相关性分析.研究发现在重、磁异常中均发现一个呈负相关的纬向构造特征,东亚地区“北纬40°断裂带”横穿了整个朝鲜半岛.     

Improved magnetic anomalies of the Antarctic lithosphere from satellite and near-surface data

The Antarctic magnetic anomaly map compiled marine and airborne surveys collected south of 60°S through 1999 and used Magsat data to help fill in the regional gaps between the surveys. Ørsted and CHAMP satellite magnetic observations with greatly improved measurement accuracies and temporal and spatial coverage of the Antarctic, have now supplanted the Magsat data. We combined the new satellite observations with the near-surface survey data for an improved magnetic anomaly map of the Antarctic lithosphere. Specifically, we separated the crustal from the core and external field components in the satellite data using crustal thickness variations estimated from the terrain and the satellite-derived free-air gravity observations. Regional gaps in the near-surface surveys were then filled with predictions from crustal magnetization models that jointly satisfied the near-surface and satellite crustal anomalies. Comparisons in some of the regional gaps that also considered newly acquired aeromagnetic data demonstrated the enhanced anomaly estimation capabilities of the predictions over those from conventional minimum curvature and spherical harmonic geomagnetic field models. We also noted that the growing number of regional and world magnetic survey compilations involve coverage gaps where these procedures can contribute effective near-surface crustal anomaly estimates.     

Non-linear Responses of a Coastal Aquatic Ecosystem to Large Decreases in Nutrient and Organic Loadings

Between 1991 and 2000, Boston Harbor, a bay–estuary in the northeast USA, experienced a decrease in loadings of total nitrogen (TN), total phosphorus (TP), and particulate organic carbon (PC) of between ∼80% and ∼90%. The average concentrations of TN and TP in the harbor water column were decreased in linear proportion to the loadings. The changes to the chlorophyll-a (chl-a), PC, and bottom water DO concentrations were curvilinear relative to the loadings, with larger changes at low than high loadings. For TN and TP, the starts of the decreases in concentrations coincided with the starts of the decreases in loadings. For the three variables that showed curvilinear responses, the starts of the changes lagged by 2 to 3 years the starts of the decreases in TN loadings. Total suspended solid concentrations and water clarity in the harbor were unchanged. The study shows that for systems such as Boston Harbor, decreases in nutrient loadings will have quite different effects depending on the base loadings to the system.