The photoelectron spectra of some Tl-Sb sulphosalts

The results of X-ray induced photoelectron spectroscopy (XPS) experiments on several phases of the ternary system Tl-Sb-S are reported. The binding energies of the inner S, Sb and Tl electrons increase with increasing quantities of Sb and decreasing amounts of Tl in these compounds. This is explained by the influences of the proportions of the bonded metals on the effective electron affinity of S. The higher proportions of the more electronegative element bonded to S cause the increase of its effective electron affinity. The results for Tl₂S (carlinite), Tl₃SbS₃, TlSbS₂ (weissbergite), TlAsS₂ (lorandite) and Sb₂S₃ (antimonite) can be interpreted in this way. The results for Tl₄S₃ suggest a predominantly covalent character of bonding for both Tl(III) and Tl(I), which are present in this sulfide. From comparison with Tl₃SbS₄ it could be supposed that Tl(III)-S bond has a more covalent character than Sb(V)-S bond. The results for Tl₃SbS₄ are in agreement with crystal structure data and the results of Moessbauer spectroscopy. For AsS (realgar) the binding energies of the inner electrons of As and S significantly increase, showing that the electrons in molecular orbitals are less strongly bonded to individual atoms, as compared to pure elements. The results for the amorphous TlSb₅S₈ (corresponding in composition to parapierrotite) suggest that in amorphous compound the Tl-S bonding is stronger and the coordination of Tl more regular than in a crystalline one.     

Total ozone response to major geomagnetic storms and changes in meteorological situations

Summary The total ozone response to strong major geomagnetic storms (A_p≥60) in winter along the 50° N latitudinal circle is studied. The results add to the recent results of Laštovička et al. (1992) obtained for European middle latitudes (∼50°N) and to the results of Mlch (1994). A significant response of total ozone is only observed in winter under high solar activity/E-phase of QBO conditions (E-max) and seems to be caused by geomagnetic storm-induced changes of atmospheric dynamics. There are two sectors along latitude 50°N, which are sensitive to forcing by geomagnetic storms both in total ozone and the troposphere — north-eastern Atlantic-European and eastern Siberia-Aleutian sectors. The total ozone response under E-max conditions manifests itself mainly as a large decrease in the longitudinal variation of ozone after the storm, which means an increase of ozone in Europe. The observed effects in total ozone consist in redistribution, not production or loss of ozone.     

Influence of the IMF sector boundaries on cosmic rays and tropospheric vorticity

Summary The effect of the IMF sector boundary crossing (IMF SBC) in the vorticity area index (VAI) — the well-known dip in the VAI after IMF SBC — is found to be independent of the IMF SBC effect in the cosmic ray flux. This finding refutes a recent suggestion by Lundstedt [1] that the IMF SBC effect in VAI is caused by a decrease in cosmic ray flux, but supports the concept of the IMF SBC effects in the ionosphere and atmosphere developed by Latovika [2–4]. Cosmic rays seem to affect the troposphere in another way.

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¶rt;mu nu mau nam aum n ( ) a u¶rt; na¶rt;u aumu () — um uu n — a¶rt; auu m ma nm uu . mm mam nam ¶rt;a n¶rt;u ¶rt;m¶rt;a [1], m m a nuu nma uu , n¶rt;¶rt;uam nu m u u am, aum amu [2–4]. am m uu u m um a mn ¶rt;u a.

     

Electrical conductivity of some rocks from the Indian subcontinent

Summary Results on electrical conductivity, chemical analysis and age of the rock samples from the Indian Subcontinent are presented. The old Precambrian Indian rocks tend to be less conductive than characteristic rocks of crustal and upper mantle structures.

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nuam mam uu mnm¶rt;mu, uu aaua u n¶rt;u u uu n¶rt; u ¶rt;uu. ma nauu n¶rt; u ¶rt;uu naam mn¶rt;m aamumuu n¶rt; u amuu.

     

Deep structure of the bohemian massif from phase velocities of Rayleigh and Love waves

Summary Phase velocities of Rayleigh and Love waves have been measured between the broadband seismic stations KHC (Kaperské Hory, South Bohemia) and KSP (Ksi, Lower Silesia), a profile that nearly coincides with the Interactional DSS Profile VII. The data for both wave types were separately inverted into models of shear-wave velocity versus depth. Novotný's model KHKS 82[1] for the DSS Profile VII was used as a start model. While the crustal section of Novotný's model is compatible with both of our data sets, our Rayleigh-wave data require smaller shear-wave velocities, on the average by 0.24 km/s, in the top 180 km of the mantle. The average difference between Novotný's model and our Love-wave model in that depth range is only 0.06 km/s. If our identification of the observed Love waves as the fundamental mode is correct, this result indicates the presence of polarization anisotropy in the uppermost mantle.

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u a mu u a ¶rt; unu uuu mauu (an , a u) u S (, ua uu). u - S nuuum mmmm ¶rt;a¶rt; nu VII . a ¶rt; u mun m¶rt; umua ¶rt;u auumu mu nn mu. am mam¶rt;u a unaa ¶rt; S 82 m[1] ¶rt; nu VII . a am ¶rt;u m aua uu aau au ¶rt;a, ¶rt;a au ¶rt;a ¶rt; mm uu m nn — ¶rt; a 0,24 / 180 uma amuu. ¶rt;a aua ¶rt; ¶rt; m u a ¶rt; ¶rt; a m ¶rt;uanau n¶rt;mam 0,06 /. u aa u¶rt;muuau a¶rt;a a a ¶rt;ama ¶rt;a m nau, m mm mam u¶rt;ummm numuu nuau aumnuu amuu.

     

Difference between the even and odd 11-year cycles of geomagnetic activity

Summary With the aid of 36 monthly and a double 12-month running average, graphs of the smoothed run of geomagnetic activity were constructed from the monthly values of the geomagnetic activity index aa for the period 1868–1978 and they were then used to determine the run of the geomagnetic activity, expressed during a uniform period and devoid of the secular variation of geomagnetic activity, for the individual 11-year cycles Nos 12–20 and the average runs for even and odd cycles, as well as for the whole period of the 9 cycles. The analysis and comparison of the graphs substantiates and renders more accurate the tendency, observed earlier, towards a regular alternation of geomagnetic activity cycles with double and single maxima. Wheareas a saddle-like shape with a maximum in the neighbourhood of the first and third quarter of the cycle is characteristic of the shape of the even cycle, the second maximum being, as a rule, the main one, the odd cycle is characterized by a peak-like shape with the main maximum in the vicinity of the cycle's centre.     

Earthquakes in the Czech Republic and Surrounding Regions in 1995–1999

In the time span from January 1995 to December 1999 the Czech National Seismological Network (CNSN), consisting of ten permanent digital broadband stations, several local networks and two data centers, detected and recorded 9530 regional natural seismic events, 27 greater than magnitude 2. Most of these events were located by the Czech Seismological Service (CSS), and the most prominent of them were analyzed in detail. A large number of quarry blasts were recorded as well but were not included in the analysis. We provide basic information on the configuration of the CNSN and on the way of routine data processing employed by the CSS in this paper. The over-all regional seismicity monitored by the CNSN in 1995–1999 is briefly reviewed. The main results of observations and evaluation of the local (NW-Bohemia/Vogtland, South Bohemia, Sudeten) and induced (Kladno, Píbram, Upper Silesia, Lubin/Poland) seismic activity within this period are presented in a condensed form. Finally, a summary on macroseismic observations on the territory of the Czech Republic in 1995–1999 is also presented.     

Numerical Modeling of the Ston-Slano (Croatia) Aftershock Sequence

The rate of aftershock occurrence after the M6 Ston-Slano (Croatia) earthquake is modeled as the Epidemic Type Aftershock Sequence (ETAS). Increase of the modeled cumulative number of aftershocks with time was fitted to observations by the least-squares criterion using the combined grid-search and Monte-Carlo approach. This enabled not only the estimation of the most probable ETAS parameters, but also the determination of their confidence limits, as well as the estimation of the bias between them. It has been found that the bias is significant for some of the parameter pairs, regardless of the threshold magnitude assumed. Residual analyses revealed that all strong aftershocks (M _L 4.5) occurred during the periods of normal to high aftershock activity. There were two periods of quiescence in the sequence, both of which were followed by a strong aftershock.