Interelement relationships and age-related variation of trace element concentrations in liver of striped dolphins (Stenella coeruleoalba) from Japanese coastal waters

Concentrations of 19 trace elements (V, Cr, Mn, Fe, Co, Cu, Zn, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, Tl, Hg, and Pb) were determined in the liver of the striped dolphins (Stenella coeruleoalba) collected around Japan during 1977–1982 to examine the sex difference, age dependence, and interrelationships among trace elements. Tissue distribution of trace elements was also investigated in one adult and one fetus specimens. Generally, concentrations of Se, Sr, Ag, Cd, Cs, Ba, Hg, and Pb were higher in the tissues of adult than those of fetus, whereas the opposite trend was observed for Cr and Tl. There were no significant sex differences in the trace element levels in the liver. Significant positive correlations between age (0–26.5 years) and hepatic concentrations were found for Ag, Se, Hg, V, Fe, Pb, and Sr, suggesting their age-dependent accumulation in the liver. In contrast, hepatic concentrations of Mn and Zn decreased with age. Significant positive relationships were observed between Se, and Hg, Ag, V, Fe, and Sr in the liver.     

Asia-Pacific mussel watch: monitoring contamination of persistent organochlorine compounds in coastal waters of Asian countries

Contamination of persistent organochlorines (OCs) such as PCBs (polychlorinated biphenyls), DDT and its metabolites (DDTs), HCH (hexachlorocyclohexane) isomers (HCHs), chlordane compounds (CHLs), and HCB (hexachlorobenzene) were examined in mussels collected from coastal waters of Asian countries such as Cambodia, China, Hong Kong, India, Indonesia, Japan, Korea, Malaysia, Philippines, Far East Russia, Singapore, and Vietnam in 1994, 1997, 1998, 1999, and 2001 to elucidate the contamination status, distribution and possible pollution sources and to assess the risks on aquatic organisms and human. OCs were detected in all mussels collected from all the sampling sites investigated. Considerable residue levels of p,p(')-DDT and alpha-HCH were found in mussels and the concentrations of DDTs and HCHs found in mussels from Asian developing countries were higher than those in developed nations suggesting present usage of DDTs and HCHs along the coastal waters of Asian developing countries. On the other hand, lower concentrations of PCBs detected in mussels from Asian developing countries than those in developed countries indicate that PCBs contamination in mussels is strongly related to industrial and activities. To our knowledge, this is a first comprehensive report on monitoring OCs pollution in the Asia-Pacific region.     

Contamination of polychlorinated biphenyls (PCBs) in sediments from Kyeonggi Bay and nearby areas, Korea

To elucidate the characteristic distribution and contamination of polychlorinated biphenyls (PCBs) in sediments, 63 sediments and five benthic organisms from Kyeonggi Bay, Namyang Bay and Lake Shihwa, West coast of Korea, were analysed. Characterization of PCBs distribution in sediments was conducted by correlation between PCBs concentrations and environmental parameters, comparison of contamination level and composition of PCBs homologs between Kanechlor mixture (KC-mix) and sediments. The residues of PCBs in sediments were correlated with total organic carbon (TOC) and particulate organic carbon (POC) contents, not with mud contents and grain size distributions. Elevated concentrations of T-PCBs were found in sediments from Incheon North Harbor (INH) in Kyeonggi Bay. T-PCBs concentrations were decreased with distance increase from inner site of INH. The residues of T-PCBs in sediments from Namyang Bay were either non-detectable or near to detection limit. The contamination by PCBs in sediments from Lake Shihwa was also low. The PCBs congener profiles in INH were similar to those of KC-mix, while those in less contaminated sites showed relatively high percentage of lower chlorinated biphenyls. Sites K18 (580 ng/g or 48 ug/g-OC dry wt) and K19 (330 ng/g or 38 ug/g-OC dry wt) within INH exceeded the sediment quality criteria (SQC) (16 micrograms/g-OC as a KC-mix) derived from equilibrium partitioning (EqP) approach.     

Lunar mare volcanism in the eastern nearside region derived from Clementine UV/VIS data

Abstract— Clementine UV/VIS multi‐spectral data were used to map mare deposits in the eastern lunar nearside region (Mare Tranquillitatis, Mare Fecunditatis, Mare Serenitatis, Mare Crisium, Mare Nectaris) to understand the volcanic history of this region. An array of Clementine and Clementine‐derived data were used to classify mare basalts; these include: 750 nm albedo, UV/VIS ratio, 1 μm absorption signatures, and Clementine derived FeO and TiO₂ contents. We have successfully identified several new geological units and have determined their spectral characteristics. For example, the relatively younger low‐Ti basalts were recognized in the eastern part of Mare Tranquillitatis. The central low‐Ti basalts in Mare Serenitatis, which had been classed as mISP, were divided into 2 groups. In Mare Nectaris, 2 types of mare basalts were identified, while only 1 group was recognized in the previous study. The stratigraphy constructed from the spectral analysis indicates that the mare deposits tend to become younger in the northern maria, including Serenitatis and Crisium, and older in the southern maria, including Tranquillitatis, Fecunditatis, and Nectaris. According to the relationship between the titanium contents of the mare units and their stratigraphy, the titanium content decreases with time in the early stage but increases toward the end of volcanism in the Serenitatis and Crisium region, while it increases with time but finally decreases in the Tranquillitatis and Fecunditatis region. In connection with the distribution of mare basalts, a large amount of high‐Ti mare basalts are found in Mare Tranquillitatis, especially in the western part, while other maria are covered by low‐Ti basalts. The iron contents show a similar distribution to that of titanium.     

Palaeotemperature curve for the Late Cretaceous of the northwestern circum-Pacific

In the northwestern circum-Pacific, two main trends in Late Cretaceous temperatures can be recognized. (1) In general, a recurrent warming trend is thought to have begun in the Turonian–Campanian, reaching temperature maxima in the early Late Santonian and early Late Campanian, and temperature minima in the earliest Santonian and perhaps early Campanian. (2) During the Maastrichtian, temperatures dropped sharply, with only a slight warming in the early Late Maastrichtian. The existence of a thermal maximum at the Coniacian–Santonian transition has previously been expected, but is not confirmed by new isotopic results.