Rapid Alkalization in Lake Inawashiro, Fukushima, Japan: Implications for Future Changes in the Carbonate System of Terrestrial Waters

The global carbon cycle, one of the important biogeochemical cycles controlling the surface environment of the Earth, has been greatly affected by human activity. Anthropogenic nutrient loading from urban sewage and agricultural runoff has caused eutrophication of aquatic systems. The impact of this eutrophication and consequent photosynthetic activity on CO₂ exchange between freshwater systems and the atmosphere is unclear. In this study, we focused on how nutrient loading to lakes affects their carbonate system. Here, we report results of surveys of lakes in Japan at different stages of eutrophication. Alkalization due to photosynthetic activity and decreases in PCO₂ had occurred in eutrophic lakes (e.g., Lake Kasumigaura), whereas in an acidotrophic lake (Lake Inawashiro) that was impacted by volcanic hot springs, nutrient loading was changing the pH and carbon cycling. When the influence of volcanic activity was stronger in the past in Lake Inawashiro, precipitation of volcanic-derived iron and aluminum had removed nutrients by co-precipitation. During the last three decades, volcanic activity has weakened and the lake water has become alkalized. We inferred that this rapid alkalization did not result just from the reduction in acid inputs but was also strongly affected by increased photosynthetic activity during this period. Human activities affect many lakes in the world. These lakes may play an important part in the global carbon cycle through their influence on CO₂ exchange between freshwater and the atmosphere. Biogeochemical changes and processes in these systems have important implications for future changes in aquatic carbonate systems on land.     

Characteristics of evapotranspiration from a permafrost black spruce forest in interior Alaska

Here, the year 2011 characteristics of evapotranspiration and the energy budget of a black spruce forest underlain by permafrost in interior Alaska were explored. Energy balance was nearly closed during summer, and the mean value of the daily energy balance ratio (the ratio of turbulent energy fluxes to available energy) from June to August was 1.00, though a large energy balance deficit was observed in the spring. Such a deficit was explained partly by the energy consumed by snowmelt. Ground heat flux played an important role in the energy balance, explaining 26.5% of net radiation during summer. The mean daily evapotranspiration of this forest during summer was 1.37 mm day^?1 – considered typical for boreal forests. The annual evapotranspiration and sublimation yielded 207.3 mm year^?1, a value much smaller than the annual precipitation. Sublimation accounted for 8.8% (18.2 mm year^?1) of the annual evapotranspiration and sublimation; thus, the sublimation is not negligible in the annual water balance in boreal forests. The daytime average decoupling coefficient was very small, and the mean value was 0.05 during summer. Thus, evapotranspiration from this forest was mostly explained by the component from the dryness of the air, resulting from the aerodynamically rough surface of this forest.     

What causes the spread of model projections of ocean dynamic sea-level change in response to greenhouse gas forcing?

Sea levels of different atmosphere–ocean general circulation models (AOGCMs) respond to climate change forcing in different ways, representing a crucial uncertainty in climate change research. We isolate the role of the ocean dynamics in setting the spatial pattern of dynamic sea-level (ζ) change by forcing several AOGCMs with prescribed identical heat, momentum (wind) and freshwater flux perturbations. This method produces a ζ projection spread comparable in magnitude to the spread that results from greenhouse gas forcing, indicating that the differences in ocean model formulation are the cause, rather than diversity in surface flux change. The heat flux change drives most of the global pattern of ζ change, while the momentum and water flux changes cause locally confined features. North Atlantic heat uptake causes large temperature and salinity driven density changes, altering local ocean transport and ζ. The spread between AOGCMs here is caused largely by differences in their regional transport adjustment, which redistributes heat that was already in the ocean prior to perturbation. The geographic details of the ζ change in the North Atlantic are diverse across models, but the underlying dynamic change is similar. In contrast, the heat absorbed by the Southern Ocean does not strongly alter the vertically coherent circulation. The Arctic ζ change is dissimilar across models, owing to differences in passive heat uptake and circulation change. Only the Arctic is strongly affected by nonlinear interactions between the three air-sea flux changes, and these are model specific.

     

Distribution of fossil seawater and its role in Neogene sedimentary rock landslides in Niigata,eastern marginal region of the Japan Sea

The Neogene marine sedimentary rock area in the eastern marginal region of the Japan Sea is an area with some of the highest landslide densities in Japan. Some of the landslides in this area have been known to involve saline groundwater, which can be the cause of these landslides. In order to demonstrate the relationships between landslides and saline water, topographic, geological, groundwater, and electromagnetic surveys were performed in the eastern marginal region of the Japan Sea. Many landslides and gravitational slope deformations with linear depressions and small scarps were recognized in the study area. The resistivity profile obtained by an electromagnetic survey suggests that there is a wide zonal distribution of saline water with salt concentrations equivalent to seawater at depths of 50–100 m or more and that the groundwater shallower than 50 m has an electrical conductivity of less than 100 mS/m. The shallow resistive groundwater is inferred to be meteoric water that replaced the saline groundwater, which likely weakened the bedrock, resulting in landslides. A ridge of competent tuff overlying mudstone has many linear depressions from gravitational slope deformation and low‐resistivity water to a depth of 600 m, which suggests that the mudstone was weakened by water replacement and deformed under the tuff caprock. The saline groundwater is inferred to be fossil seawater trapped in pores during sediment deposition, which is brought near the ground surface along with rocks by tectonic movement in the hills. Thus, the saline water and its fresh water replacement are among the important basic causes of the landslides. The oil well data obtained in the eastern marginal region of the Japan Sea suggest that such saline water replacement has occurred widely and that replacement is likely one of the predispositions for the frequent landslides there.     

The peristerite gap in low-grade metamorphic rocks

Coexisting Na-plagioclases from greenschists both in the thermal aureole of the Kasugamura Granite, Japan, and in the low-P metamorphic zone of Yap Island, western Pacific were analyzed in great detail; the peristerite solvus was determined for each suite. The asymmetric solvus has steep albite-rich and gentle oligoclase-rich limbs that are similar to those for higher pressure series. The present results together with those from Vermont, New Zealand, and the Sanbagawa belt indicate that the peristerite solvus shifts toward the albite component and higher temperature with increasing pressure. With increasing pressure, albite co-existing with oligoclase (An=100 Ca/Ca+ Na=20) varies in composition from An 8–9 (in Kasugamura), through An 3 (in Yap Island and Vermont), to An 1 (in New Zealand) and An less than 0.5 (in the Sanbagawa belt). The consolute temperatures for the peristerite solvus estimated from available geothermometry are 420° C in Kasugamura, 450–550° C in Vermont and 550°–600° C in the Sanbagawa belt. The variation of plagioclase composition in progressive metamorphic zones is explained by intersection of a plagioclase-forming reaction and the peristerite immiscibility gap in an isobaric T-X _An diagram. The greenschist zone is characterized by albite, the transition zone by occurrence of peristerite pairs and the amphibolite zone by plagioclase of An 20–50.     

Space group and hydrogen sites of δ-AlOOH and implications for a hypothetical high-pressure form of Mg(OH)<Subscript>2</Subscript>

The space group and hydrogen positions of -(Al_0.84Mg_0.07Si_0.09)OOH are investigated using a single crystal synthesized using a multi-anvil apparatus under conditions of 1000 °C and 21 GPa. The space group determined by single-crystal X-ray diffraction is to Pnn2, with unit-cell parameters of a=4.6975(8) Å, b= 4.2060(6) Å, c=2.8327(4) Å, and V=55.97(1) ų. Partial occupancy of the Al site by Mg and Si suggests the possibility of a limited solid solution between -AlOOH, stishovite, and a hypothetical CaCl₂-type Mg(OH)₂ that is 16% denser than brucite. Difference-Fourier maps reveal two small but significant Fourier peaks attributable to hydrogen atoms. Atomic distances and angles around the first peak indicate a hydrogen bond with O···O distances of 2.511 Å, while those around the second peak are suggestive of a bifurcated hydrogen bond with O···O distances of 2.743 and 2.743 Å.     

Middle Eocene low-paleolatitude radiolarian evidence for the Cabog Formation,Central East Luzon,Philippine Mobile Belt

The Cabog Formation, newly established herein and exposed in central East Luzon, Philippine Mobile Belt, is defined in age by the occurrence of radiolarians. The radiolarian assemblage is correlative with the middle Eocene and suggests a low paleolatitude affinity. The correlation, sedimentary environment, and the tectonic significance are discussed. The Cabog Formation is correlative with the distal part of the middle–late Eocene Caraballo Formation, which is exposed in the northeastern side of the Philippine Fault Zone. The sandstone composition and radiolarian age suggest that the Cabog Formation represents the first depositional stage in the early arc setting. The northward migration of the formation is also estimated in relation with the Philippine Sea Plate motion along the Older Philippine Fault from the equatorial area.     

Geochemical characteristics of Tertiary Sagara oil from an active forearc basin, Shizuoka, Japan

Abstract   The Sagara oil field is located in the Neogene Kakegawa Basin, close to the Izu collision zone at the junction between the main Japanese Islands and the Izu–Bonin Arc. The Sagara oil field is one of the few oil fields situated in a forearc basin on the Pacific side of Japan and is present in a sedimentary basin with poor oil-generating potential. Several crude oils from Sagara oil field were investigated to infer their origin. Organic geochemical characteristics of Sagara oils showed the influences of light biodegradation, migration-contamination, and migration-fractionation. The maturity levels of Sagara oils evaluated based on abundant alkylnaphthalenes corresponded to 0.9–1.2% vitrinite reflectance. Sagara oils were characterized by significant amounts of higher plant biomarkers, a high pristane/phytane ratio and an absence of organic sulphur compounds, suggesting a siliciclastic source rock deposited under nearshore to fluvial–deltaic environments. Numerous faults and fractures in the active forearc basin provided excellent conduits and facilitated upward migration of light hydrocarbons generated at greater depth in the Kakegawa Basin.     

Effects of frozen soil and snow cover on cold‐season soil water dynamics in Tokachi,Japan

Despite the potential impact of winter soil water movements in cold regions, relatively few field studies have investigated cold‐season hydrological processes that occur before spring‐onset of snowmelt infiltration. The contribution of soil water fluxes in winter to the annual water balance was evaluated over 5 years of field observations at an agricultural field in Tokachi, Hokkaido, Japan. In two of the winters, soil frost reached a maximum depth of 0·2 m (‘frozen’ winters), whereas soil frost was mostly absent during the remaining three winters (‘unfrozen’ winters). Significant infiltration of winter snowmelt water, to a depth exceeding 1·0 m, occurred during both frozen and unfrozen winters. Such infiltration ranged between 126 and 255 mm, representing 28–51% of total annual soil water fluxes. During frozen winters, a substantial quantity of water (ca 40 mm) was drawn from deeper layers into the 0–0·2 m topsoil layer when this froze. Under such conditions, the progression and regression of the freezing front, regulated by the thickness of snow cover, controlled the quantity of soil water flux below the frozen layer. During unfrozen winters, 13–62 mm of water infiltrated to a depth of 0·2 m, before the spring snowmelt. These results indicate the importance of correctly evaluating winter soil water movement in cold regions. Copyright © 2010 John Wiley & Sons, Ltd.     

A method for remote detection of oil spills using laser-excited Raman backscattering and backscattered fluorescence

A laser method for the remote detection of oil present as a pollutant in the sea water using Raman backscattering and backscattered fluorescence is discussed. The scattering spectra of oils obtained by using a laser Raman spectrometer that employs a CW Ar laser are described. The backscattering spectra of oils obtained by a laser radar technique in the laboratory and the field are also described. Furthermore, theoretical performance of a laser radar with a CW laser or a pulsed laser for the detection of Raman backscattering of kerosene is discussed.