Internal differentiation of Kutsugata lava flow from Rishiri Volcano,Japan: Processes and timescales of segregation structures' formation

Internal differentiation processes in a solidifying lava flow were investigated for the Kutsugata lava flow from Rishiri Volcano in northern Japan. In a representative 6-m thick lava flow that was investigated in detail in this study, segregation products darker than the host lavas manifested mainly in the form of pipes (vesicle cylinders) and layers (vesicle sheets), occurring around 0.5–2.3 m and 2.0–4.0 m above the base, respectively. Both the cylinders and sheets are significantly richer in incompatible elements such as TiO₂ and K₂O than the host lavas, which suggest that these products essentially represent residual melt produced during solidification of the lava flow. Field observation and the geochemical features of the lavas suggest that the vesicle cylinders grew upward from near the base of the flow by continuous feeding of residual melt from the neighboring host lavas to the heads of the cylinders. On the other hand, the vesicle sheets were produced in situ in the solidifying lava flow as fracture veins caused by horizontal compression. The vesicle cylinders have a remarkably higher MgO content (up to 8 wt.%) than the host lava (< 6 wt.%), whereas the vesicle sheets display MgO depletion (as low as 3.5 wt.%). The relatively high MgO content of the vesicle cylinders cannot be explained solely by the mechanical mixing of olivine phenocrysts with the residual melt. It is suggested that the vesicle cylinders were produced by the extraction of olivine-bearing interstitial melt from an augite-plagioclase network in the host lava, whereas the vesicle sheets were formed by the migration of the residual melt from a crystal network consisting of plagioclase, augite, and olivine in the host lava into platy fractures. We infer that this selective crystal fractionation for forming the vesicle cylinders resulted from processes in which abundant vesicles rejected from the upward-migrating floor solidification front prevented olivine crystals from being incorporated into the crystal network in the host lava. The vesicle cylinders are considered to have formed in ∼ 1 day after the lava flow came to rest, while relatively large vesicle sheets (> 1 cm thick) appeared much later (after ∼ 9 days). The formation of these segregation products was essentially complete within 20 days after the lava emplacement.     

中国沿海及内陆地区长周期脉动特征分析

地脉动台阵观测作为一种低成本的剪切波速度构造探测方法,预计将在中国地震灾害预防中起到重要作用。为了研究地脉动台阵观测中长周期信号的特征以及中国长周期地脉动的特点和适用性,开展了中国从沿海到内陆地区地脉动信号的观测和分析,探查由沿海到内陆地区地脉动的变化规律以及内陆地区广域的地脉动特征,发展适合于我国内陆地区的基于地脉动的地下构造勘探方法,在中国大陆上海市、西安市、天水市及兰州市进行了长周期地脉动观测。现场试验结果表明,上海地脉动特征与日本关东平原地区的观测结果类似,可以认为在海岸地区深部结构调查的地脉动台阵观测有良好的适用性。然而,西安、兰州、天水长周期地脉动能量只有上海的千分之一,因此需要进一步研究更加灵敏的仪器性能和更加稳定的观测方法。     

Temporal variations in channel patterns and facies architecture in a gravelly fluvial system: The Paleogene Iwaki Formation on the Joban Coalfield,a forearc basin in Northeast Japan

This paper examined sequence‐stratigraphic features of a gravelly fluvial system of the Iwaki Formation, which developed in a forearc‐basin setting in Northeast Japan during the Eocene through Oligocene. On the basis of three‐dimensional architectural element analysis, we discriminated three major cycles of channel complexes, which contain ten component channel deposits in total in the fluvial succession. Component channel deposits in the uppermost part of each cycle are sandier and associated with overbank muddy deposits and coal beds as compared with those in the lower part of the cycle. Mean clast‐size also decreases upsection in the entire gravelly fluvial deposits. The fluvial succession is interpreted to have been deposited in response to an overall rise in relative sea level that was superimposed by three short‐term relative sea‐level rises on the basis of vertical stacking patterns and component lithofacies features of channel deposits, and of correlation of the fluvial succession with an age‐equivalent marine succession in an area about 50 km offshore. However, geometry and stacking patterns of the channel complexes do not exhibit any distinct temporal variation and amalgamated channel and bar deposits are dominant throughout the transgressive fluvial succession. On the other hand, an overall fining‐upward pattern of the entire Iwaki Formation fluvial deposits in association with three component fining‐upward patterns is distinct, and is interpreted to be consistent with the tenet of the standard fluvial sequence‐stratigraphic models. This indicates that the present example represents one type of variation in the standard fluvial sequence‐stratigraphic models, possibly reflecting the forearc‐basin setting, which is generally represented by higher valley slope, higher shedding of coarse‐grained sediments, and shorter longitudinal profiles to the coastal area as compared with a passive‐continental‐margin setting.     

Impact-induced phyllosilicate formation from olivine and water

Shock-recovery experiments on mixtures of olivine and water with gas (air) were performed in a previous study to demonstrate water-mineral interactions during impact events (Furukawa et al., 2007). The products of these former experiments were investigated in the present study using transmission electron microscopy, scanning electron microscopy, and X-ray powder diffraction with the aim of finding evidence of aqueous alteration. Serpentine formed on the surface of shocked olivine with well-developed mosaicism. The yield of serpentine depended on the water/olivine ratio in the starting material, indicating progressive serpentinization under water-rich conditions. Comminution and mosaicism were developed in shocked olivine grains. The temperature and pressure changes of the samples during the experiments were estimated by constructing Hugoniots for mixtures of olivine and water, combined with the results of an additional fracturing experiment on a shocked container. Pressures and temperatures reached 4.6-7.2 GPa and at least 230-390 °C, respectively, for 0.7 μs during in-shock compression. Post-shock temperatures reached a maximum of ∼1300 °C, when the shock wave reached the gas in the sample cavity. The serpentine formed after the post-shock temperature maximum, most likely when temperatures dropped to between 200 and 400 °C. This is the first experiment to demonstrate the formation of phyllosilicates using heat supplied by an impact. The present results and estimations suggest that phyllosilicates could form as a result of impacts into oceans as well as by impacts on terrestrial and Martian crustal rocks, and on some asteroidal surfaces, where liquid or solid H₂O is available. A significant amount of phyllosilicates would have formed during the late heavy bombardment of meteorites on the Hadean Earth, and such phyllosilicates might have affected the prebiotic carbon cycle.     

Eruptive history of the Barombi Mbo Maar, Cameroon Volcanic Line, Central Africa: Constraints from volcanic facies analysis

his study presents the first and detail field investigations of exposed deposits at proximal sections of the Barombi Mbo Maar (BMM), NE Mt Cameroon, with the aim of documenting its past activity, providing insight on the stratigraphic distribution, depositional process, and evolution of the eruptive sequences during its formation. Field evidence reveals that the BMM deposit is about 126m thick, of which about 20m is buried lowermost under the lake level and covered by vegetation. Based on variation in pyroclastic facies within the deposit, it can be divided into three main stratigraphic units: U₁, U₂ and U₃. Interpretation of these features indicates that U₁ consists of alternating lapilli-ash-lapilli beds series, in which fallout derived individual lapilli-rich beds are demarcated by surges deposits made up of thin, fine-grained and consolidated ash-beds that are well-defined, well-sorted and laterally continuous in outcrop scale. U₂, a pyroclastic fall-derived unit, shows crudely lenticular stratified scoriaceous layers, in which many fluidal and spindle bombs-rich lapilli-beds are separated by very thin, coarse-vesiculatedash-beds, overlain by a mantle xenolith- and accidental lithic-rich explosive breccia, and massive lapilli tuff and lapillistone. U3 displays a series of surges and pyroclastic fall layers. Emplacement processes were largely controlled by fallout deposition and turbulent diluted pyroclastic density currents under “dry” and “wet” conditions. The eruptive activity evolved in a series of initial phreatic eruptions, which gradually became phreatomagmatic, followed by a phreato-Strombolian and a violent phreatomagmatic fragmentation. A relatively long-time break, demonstrated by a paleosol between U₂ and U₃, would have permitted the feeding of the root zone or the prominent crater by the water that sustained the next eruptive episode, dominated by subsequent phreatomagmatic eruptions. These preliminary results require complementary studies, such as geochemistry, for a better understanding of the changes in the eruptive styles, and to develop more constraints on the maar’s polygenetic origin.     

沙虫干呈味及功能性成分研究

对沙虫干抽提物成分的组成进行的研究结果表明 :游离氨基酸含量 w为 10 .3% ,占抽提物含氮物质的 77.9%。抽提物组成中 ,呈甘味的 Gly(3.2 % )、Ala(2 .5% )和呈鲜味的 IMP(0 .2 7% )、Glu(0 .2 5% )、琥珀酸 (0 .35% )等成分同沙虫干独特的风味有关 ,Na 、Cl-等无机离子也同其呈味相关。此外 ,牛磺酸含量 w高达 3.2 % ,是富含牛磺酸的一种海洋生物 ;精氨酸的含量 w亦较高 ,为 1.2 %。     

The effect of iron on montmorillonite stability. (I) Background and thermodynamic considerations

It is envisaged that high-level nuclear waste (HLW) will be disposed of in underground repositories. Many proposed repository designs include steel waste canisters and bentonite backfill. Natural analogues and experimental data indicate that the montmorillonite component of the backfill could react with steel corrosion products to produce non-swelling Fe-rich phyllosilicates such as chamosite, berthierine, or Fe-rich smectite. In K-bearing systems, the alteration of montmorillonite to illite/glauconite could also be envisaged. If montmorillonite were altered to non-swelling minerals, the swelling capacity and self-healing properties of the bentonite backfill could be reduced, thereby diminishing backfill performance. The main aim of this paper was to investigate Fe-rich phyllosilicate mineral stability at the canister-backfill interface using thermodynamic modelling. Estimates of thermodynamic properties were made for Fe-rich clay minerals in order to construct approximate phase-relations for end-member/simplified mineral compositions in logarithmic activity space. Logarithmic activity diagrams (for the system Al₂O₃-FeO-Fe₂O₃-MgO-Na₂O-SiO₂-H₂O) suggest that if pore waters are supersaturated with respect to magnetite in HLW repositories, Fe(II)-rich saponite is the most likely montmorillonite alteration product (if f_O2(g) values are significantly lower than magnetite-hematite equilibrium). Therefore, the alteration of montmorillonite may not be detrimental to nuclear waste repositories that include Fe, as long as the swelling behaviour of the Fe-rich smectite produced is maintained. If f_O2(g) exceeds magnetite-hematite equilibrium, and solutions are saturated with respect to magnetite in HLW repositories, berthierine is likely to be more stable than smectite minerals. The alteration of montmorillonite to berthierine could be detrimental to the performance of HLW repositories.     

Impacts of Indian Ocean SST biases on the Indian Monsoon: as simulated in a global coupled model

In this study, the impact of the ocean–atmosphere coupling on the atmospheric mean state over the Indian Ocean and the Indian Summer Monsoon (ISM) is examined in the framework of the SINTEX-F2 coupled model through forced and coupled control simulations and several sensitivity coupled experiments. During boreal winter and spring, most of the Indian Ocean biases are common in forced and coupled simulations, suggesting that the errors originate from the atmospheric model, especially a dry islands bias in the Maritime Continent. During boreal summer, the air-sea coupling decreases the ISM rainfall over South India and the monsoon strength to realistic amplitude, but at the expense of important degradations of the rainfall and Sea Surface Temperature (SST) mean states in the Indian Ocean. Strong SST biases of opposite sign are observed over the western (WIO) and eastern (EIO) tropical Indian Ocean. Rainfall amounts over the ocean (land) are systematically higher (lower) in the northern hemisphere and the south equatorial Indian Ocean rainfall band is missing in the control coupled simulation. During boreal fall, positive dipole-like errors emerge in the mean state of the coupled model, with warm and wet (cold and dry) biases in the WIO (EIO), suggesting again a significant impact of the SST errors. The exact contributions and the distinct roles of these SST errors in the seasonal mean atmospheric state of the coupled model have been further assessed with two sensitivity coupled experiments, in which the SST biases are replaced by observed climatology either in the WIO (warm bias) or EIO (cold bias). The correction of the WIO warm bias leads to a global decrease of rainfall in the monsoon region, which confirms that the WIO is an important source of moisture for the ISM. On the other hand, the correction of the EIO cold bias leads to a global improvement of precipitation and circulation mean state during summer and fall. Nevertheless, all these improvements due to SST corrections seem drastically limited by the atmosphere intrinsic biases, including prominently the unimodal oceanic position of the ITCZ (Inter Tropical Convergence Zone) during summer and the enhanced westward wind stress along the equator during fall.     

ANALYSIS OF Cu, Cd, Co AND Ni IN SURFACE WATER OF THE KUROSHIO AREA IN THE EAST CHINA SEA

Study of 1986 and 1987 heavy metal distribution in surface water of the Kuroshio area in the East China Sea showed regional and slight seasonal variations in distribution and concentration . Heavy metal levels in Taiwan Strait, the sea area north of Taiwan and the continental shelf are higher than those in the main axis of the Kuroshio . Dissolved Cu in summer and winter decreases with the increase of salinity , but dissolved Cd has no obvious change with salinity .     

Motion of iron sulfide inclusions inside a shock‐melted chondrule

Abstract— We calculated the trajectories of molten spheres of iron sulfide inclusions inside a melted chondrule during the nebular shock wave heating. Our calculations included the effects of high‐velocity internal flow in the melted chondrule and apparent gravitational force caused by the drag force of nebular gas flow. The calculated results show that large iron sulfide inclusions, which have radii 0.23 times larger than those of the parent chondrules, must reach the surface of the melted chondrule within a short period of time (<<1 s). This effect will provide us with very important information about chondrule formation by nebular shock wave heating.