Accurate Isotopic and Concentration Analyses of Small Amounts of Pb Using Isotope Dilution Coupled with the Double Spike Technique

A new method has been developed for the simultaneous determination of Pb abundance and Pb isotopic composition with high precision and accuracy for small test portion masses by thermal ionisation mass spectrometry. In this method, a ²⁰⁵pb-²⁰⁴pb double spike is added to samples prior to the chemical separation of Pb, and the isotopic composition of the spike-sample mixture is determined rigorously by the double spike technique using a ²⁰⁷Pb-²⁰⁴Pb spike. The isotopic composition and concentration of Pb in the sample are then obtained by utilising the principle of isotope dilution. Using this technique, replicate determinations of Pb from NIST SRM 981 and GSJ JP-1 (peridotite; 0.07 μg g⁻¹ Pb) were performed. The measured concentration and isotopic data were identical, within uncertainty, to published data or to data that were determined independently in this study. The application of this method to U-Pb dating and the determination of the "initial" Pb isotopic composition was also tested. Lead isotopic compositions and the concentrations of Pb, Th and U were determined for a single batch of samples, through the addition of ²⁰⁵pb-²⁰⁴pb, ²³⁰Th and ²³⁵U spikes to samples prior to chemical separation. Also in these experiments, we confirmed that this routine gives accurate data for Pb, Th and U concentrations and Pb isotopic compositions.     

Regional differences in cognitive dissonance in evacuation behavior at the time of the 2011 Japan earthquake and tsunami

This paper constructs an evacuation decision-making model that takes cognitive dissonance into consideration. The purpose of this construction is to clarify the psychological mechanism for the evacuation behavior of residents during an emergency, based on Akerlof and Dickens (Akerlof and Dickens Am Econ Rev 72:307–319, 1982) "The economic consequences of cognitive dissonance". Specifically, we empirically explore people’s psychological mechanism (e.g., cognitive dissonance) for evacuation behavior when a tsunami disaster occurs. As a result, we show that the level of anxiety depends on the area where residents live and that the average anxiety of residents is mostly correlated with the level of damage of past disasters, and that it is affected also by the ages of residents. Since the level of anxiety largely affects an individual’s evacuation behavior, this result can indicate for what kinds of people intervention and assistance are required based on the level of anxiety. A high level of anxiety basically promotes evacuation. Since our results show that anxiety is increased by the experience of tsunamis, education having people virtually experience tsunamis may increase evacuation rates efficiently.