Measuring hydraulic permeability in a streambed using the packer test

Permeability of a streambed is an important factor regulating nutrient and oxygen availability for aquatic biota. In order to investigate the relationship, an accurate permeability should be measured. However, it is difficult to measure permeability in a coarse gravel bed using a conventional permeability test. Moreover, turbulent flow may occur in coarse bed material, and then deviations from Darcy's law do occur. Thus, permeability calculated following Darcy's law may be overestimated under turbulent flow conditions and should be corrected. The packer test can be used in highly permeable gravel beds. We developed a field method applicable to a gravel bed using the packer test and derived an equation adopting a law of turbulent flow to study the problems under any type of flow condition. The accuracy of the equation was examined using a laboratory flume with a gravel bed. The results suggested that permeability calculated from Hvorslev's equation is overestimated for turbulent flow. In contrast, our equation, developed here, could evaluate permeability accurately under any type of flow condition. Copyright © 2005 John Wiley & Sons, Ltd.     

Complex organic molecules in an early stage of protostellar evolution

We have detected the rotational lines of HCOOCH₃ toward a Class 0 low-mass protostar, NGC1333 IRAS4B, which is reported to be extremely young according to the dynamical age of the molecular outflow (a few 100 yr). This suggests that the complex organic molecules appear from the very early stage of protostellar evolution. On the other hand, the complex organic molecules are not detected in a more evolved protostar, L1527. We have also found a similar trend in a massive star forming region, NGC2264. The HCOOCH₃ emission is almost absent toward IRS1, whereas it is concentrated near MMS3, which is younger than IRS1. In addition, the HCOOCH₃ intensity peak is slightly shifted from the dust emission peak, as is seen in the Orion KL Compact Ridge, giving an important clue to solve its origin.     

Seismic behavior of bridges with pier and foundation strengthening: PsD tests and analytical study

By means of a simplified three degrees of freedom model, seismic behavior of reinforced concrete bridge piers and foundations were evaluated based on pseudo‐dynamic (PsD) tests for cases where pier strengthening and foundation strengthening are implemented. In addition, analysis based on PsD test results was conducted to investigate the influence of pier strengthening on seismic damage to the foundation. The PsD tests and the analysis show that the foundation suffers increased hysteretic response when pier strengthening is applied. The results also show that the foundation strengthening can prevent foundation damage. Copyright © 2011 John Wiley & Sons, Ltd.     

A preparation zone for volcanic explosions beneath Naka-dake crater,Aso volcano,as inferred from magnetotelluric surveys

The 1st crater of Naka-dake, Aso volcano, is one of the most active craters in Japan, and known to have a characteristic cycle of activity that consists of the formation of a crater lake, drying-up of the lake water, and finally a Strombolian-type eruption. Recent observations indicate an increase in eruptive activity including a decrease in the level of the lake water, mud eruptions, and red hot glows on the crater wall. Temporal variations in the geomagnetic field observed around the craters of Naka-dake also indicate that thermal demagnetization of the subsurface rocks has been occurring in shallow subsurface areas around the 1st crater. Volcanic explosions act to release the energy transferred from magma or volcanic fluids. Measurement of the subsurface electrical resistivity is a promising method in investigating the shallow structure of the volcanic edifices, where energy from various sources accumulates, and in investigating the behaviors of magma and volcanic fluids. We carried out audio-frequency magnetotelluric surveys around the craters of Naka-dake in 2004 and 2005 to determine the detailed electrical structure down to a depth of around 1 km. The main objective of this study is to identify the specific subsurface structure that acts to store energy as a preparation zone for volcanic eruption. Two-dimensional inversions were applied to four profiles across the craters, revealing a strongly conductive zone at several hundred meters depth beneath the 1st crater and surrounding area. In contrast, we found no such remarkable conductor at shallow depths beneath the 4th crater, which has been inactive for 70 years, finding instead a relatively resistive body. The distribution of the rotational invariant of the magnetotelluric impedance tensor is consistent with the inversion results. This unusual shallow structure probably reflects the existence of a supply path of high-temperature volcanic gases to the crater bottom. We propose that the upper part of the conductor identified beneath the 1st crater is mainly composed of hydrothermally altered zone that acts both as a cap to upwelling fluids supplied from deep-level magma and as a floor to infiltrating fluid from the crater lake. The relatively resistive body found beneath the 4th crater represents consolidated magma. These results suggest that the shallow conductor beneath the active crater is closely related to a component of the mechanism that controls volcanic activity within Naka-dake.     

Mechanism of explosive eruption revealed by geophysical observations at the Sakurajima,Suwanosejima and Semeru volcanoes

A common sequence of phenomena associated with volcanic explosions is extracted based on seismic and ground deformation observations at 3 active volcanoes in Japan and Indonesia. Macroscopic inflation-related ground deformations are detected prior to individual explosions, while deflations are observed during eruptions. Precursory inflation occurs 5 min to several hours before eruption at the Sakurajima volcano, but just 1–2 min at Suwanosejima and 3–30 min at the Semeru volcano. The sequence commences with minor contraction, which is detected by extensometers 1.5 min before eruption at Sakurajima, as a dilatant first motion of the explosion earthquakes 0.2–0.3 s before surface explosions at Suwanosejima, and as downward tilt 4–5 s prior to eruption at the Semeru volcano. The sequence is detected for explosive eruptions with > 0.1 μrad tilt change at Sakurajima, 90% at Suwanosejima and 75% at Semeru volcanoes. It is inferred that the minor contraction is caused by a volume and pressure decrease due to the release of gas from a pocket at the top of the conduit as the gas pressure exceeds the strength of the confining plug. The subsequent violent expansion may be triggered by sudden outgassing of the water-saturated magma induced by the decrease in confining pressure.     

Swelling of a lava plug associated with a Vulcanian eruption at Sakurajima Volcano,Japan, as revealed by infrasound record: case study of the eruption on January 2, 2007

In order to clarify the time relation of the expansion of a gas pocket and failure of its overlying plug of lava during Vulcanian eruptions, infrasound records and video images of the Vulcanian eruption that occurred at Sakurajima volcano on January 2, 2007 were analyzed with respect to their origin times. Weak (≤3 Pa) and slowly increasing air pressure preceded the impulsive compression phase by 0.25–0.32 s, and a longer-period rarefaction phase of infrasound waves was recognized at all microphone stations. The velocity of the compression phase was assumed to be supersonic (ca. 400 m/s) up to 850 m above the crater bottom from other recent explosions. On the other hand, the propagation velocity of the preceding weak signal was regarded to be similar to the air sound velocity because the lack of impulsiveness is unlikely to be related to the main compression phase. Therefore, the estimated origin time of the main compression phase was delayed by 0.5–0.7 s from the preceding phase. The origin time of the preceding phase coincided with the onset of the isotropic expansion process of the pressurized gas pocket, which was obtained by the waveform inversion of the explosion earthquake. In contrast, the origin time of the main impulsive phase coincided with the time when the expansion rate reached its peak. This observation suggests that the volumetric increase of the gas pocket caused swelling of the surface of the crater bottom and its subsequent failure. When the expansion velocity exceeded a threshold level, the main impulsive compression phase radiated with a high velocity by the sudden releases of the pressurized gases. The volumetric change at the source was estimated to be 280–560 m³ from the preceding phase of the infrasound. This volume change indicates that the vertical displacement of the swelling ground was on the order of 1.0 m, assuming the radius of the lava plug was ca. 10 m.     

Simultaneous Analysis of Natural Free Estrogens and Their Conjugates in Wastewater by GC‐MS

A solid‐phase extraction (SPE)‐gas chromatography (GC)‐mass spectrometry (MS) analytical method was developed for the simultaneous analysis of natural free estrogens and their conjugates in wastewater samples. Natural free estrogens and their conjugates in wastewater were successfully separated by the oasis hydrophilic‐lipophilic balance solid phase extraction (Oasis HLB SPE) method, and the conjugates were initially enzyme hydrolyzed by β‐glucuronidase or arylsulfatase from Helix pomatia prior to derivatization. N‐methyl‐N‐(tert‐butyldimethylsilyl)trifluoroacetamide (MTBSTFA) plus 1% tert‐butyldimetheylchlorosilane (TBDMCS) was chosen as the derivatization reagent, and the most appropriate conditions of derivatization were determined to be at 95°C for 90 min. The recovery ratios of nine target chemicals were determined by spiking them in 1 L of ultra‐purified water or the influent of a wastewater treatment plant (WWTP). The recovery ratios of six out of nine for the analytes ranged from 73.3–114.9% with relative standard deviations (RSD) from 1.6–19.9%. The established method was successfully applied to environmental wastewater samples which were collected from one municipal wastewater treatment plant (WWTP) in Osaka, Japan, for the determination of natural free estrogens and their conjugates. In the influent sample, E1, E2, E1‐3S, E3‐3S, and E1‐3G were detected at concentrations of 16.6, 9.6, 8.2, 21.9, and 3.2 ng L^–1, respectively. However, only E1 was detected at a high concentration of 44 ng L^–1 in the effluent sample, suggesting that it is the dominant natural free estrogen in the effluent.     

Holocene estuarine sediments as a source of arsenic in Pleistocene groundwater in suburbs of Hanoi,Vietnam

Groundwater pollution by arsenic is a major health threat in suburban areas of Hanoi, Vietnam. The present study evaluates the effect of the sedimentary environments of the Pleistocene and Holocene deposits, and the recharge systems, on the groundwater arsenic pollution in Hanoi suburbs distant from the Red River. At two study sites (Linh Dam and Tai Mo communes), undisturbed soil cores identified a Pleistocene confined aquifer (PCA) and Holocene unconfined aquifer (HUA) as major aquifers, and Holocene estuarine and deltaic sediments as an aquitard layer between the two aquifers. The Holocene estuarine sediments (approximately 25–40 m depth, 9.6–4.8 cal ka BP) contained notably high concentrations of arsenic and organic matter, both likely to have been accumulated by mangroves during the Holocene sea-level highstand. The pore waters in these particular sediments exhibited elevated levels of arsenic and dissolved organic carbon. Arsenic in groundwater was higher in the PCA (25–94 μg/L) than in the HUA (5.2–42 μg/L), in both the monitoring wells and neighboring household tubewells. Elevated arsenic concentration in the PCA groundwater was likely due to vertical infiltration through the arsenic-rich and organic-matter-rich overlying Holocene estuarine sediments, caused by massive groundwater abstraction from the PCA. Countermeasures to prevent arsenic pollution of the PCA groundwater may include seeking alternative water resources, reducing water consumption, and/or appropriate choice of aquifers for groundwater supply.     

Earthquake sequences on a frictional fault model with non-uniform strengths and relaxation times

Summary. The space and time characteristics of earthquake sequences, including a main shock, aftershocks and the recurrence of major shocks in a long time range, are investigated on a frictional fault model with non-uniform strengths and relaxation times, which is subjected to a time-dependent shear stress. Aftershocks with low stress drop take place successively in spaced regions so as to fill the gaps which have not yet been ruptured since the main shock, while those with high stress drop occur in and around the regions left unruptured during the main faulting. The frequency decay of aftershocks with time follows a hyperbolic law with the rates p consistent with observations. There are good linear relations in logarithmic scales for source area versus frequency and seismic moment versus frequency of the generated aftershocks. The b -value obtained in the present experiments appears slightly larger than that for observations. It was found that more heterogeneous distribution of the fault strength give smaller p and larger b -values. The recurrence of major shocks, particularly of very large shocks with high stress drop, is often preceded by a completely silent period of activity or very low activity with a small number of foreshocks. The major shocks take place successively in adjacent unruptured regions and sometimes show slow-speed migrations. These results provide explanations to various observations of earthquake sequences.