Cobalt is obtained mainly as a byproduct of the mining and metallurgical processing of copper and nickel. The amount of minable
cobalt has a characteristic supply limit, which is dependent upon demand for copper and nickel. It is considered that cobalt
consumption will be affected by the amount mined in the near future, because world demand has been gradually increasing, while
the production from copper sulfide ores in Zaire and Zambia, major producing countries, has decreased for political, economical
and technological reasons. The world demand for cobalt has surpassed the world mine production, and cobalt sales from the
National Defense Stockpile of the United States and exports from Russia and cobalt recovered from stockpiled intermediates
contributed to the supply in 1994. It is concluded, from a statistical point of view, that this trend of shortage and high
prices for cobalt will continue in the near future. 相似文献
Seven rare-earth elements (La, Ce, Sm, Eu, Tb, Yb, Lu) and Co, Cr, Sc, Ba, Hf and Th have been determined by non-destructive neutron activation analysis on the Quaternary volcanic rocks in Hokkaido, Japan. The trace-element abundances are discussed in terms of the petrological problems, particularly the origin of calc-alkali magma. On the basis of the La/Sm ratio and the contents of K, Ba, Th and La, lateral variations in the contents of trace elements exist across the Kurile and the northern Honshū arcs. The calc-alkali rocks can be classified into three types which correspond to Kuno's three basalt-magma types. There is no essential difference in the rare-earth patterns between the basaltic rocks and the associated calc-alkali rocks in each petrographic province. This suggests that the calcalkali rocks may be derived from the basaltic magmas by fractional crystallization under certain conditions. 相似文献
Freezing was used in the jointing section of two shields (diameter 3.14 m) which ran across at right angles and at 25-m depth under the crossing of main roads for the construction of a 2.4-m diameter sewer tunnel. The object of freezing was to create a frozen barrier to prevent the inflow of water and fine sand into the area to be excavated.
Thirty-five freeze pipes (length about 7 m) were placed from one shield conically in the direction of the flank of another shield with freeze pipes attached to its inside wall. The cooling unit was placed on unoccupied land at about 60 m distant from the jointing section and the freeze pipes were connected with the cooling unit by supply and return pipelines.
The cooling unit had a cooling capacity of 79,000 kcal/h at an evaporation temperature of −27°C and a condensation temperature of +40°C. Freezing was continued for 180 days and the CaCl2 brine temperature was −25 to −30°C. These works were accomplished without the sinking of shaft and the use of injection, in complete safety with no traffic restriction on the road surface. 相似文献
Near-liquidus phase relations in one-atmosphere dry and water-saturated high pressure conditions were experimentally determined on products of three historic andesitic eruptions. Run conditions ranged from 900 to 1100°C, at pressures up to 1500 bars with fO2 controlled close to the nickel-nickel oxide (NNO) buffer. In order to represent the compositions of the true liquid parts of the erupting magmas, groundmass portions were mechanically separated from the porphyritic andesites. Such groundmass materials should lie exactly on the liquidus field boundary between the phases precipitating from the magma just prior to eruption under the prevailing P-T condition.All the samples showed a crossing of the plagioclase and orthopyroxene liquidi in the pressure-temperature range from 1 to 800 bar and 950–1090°C. The crossing condition approximates the magmatic condition immediately prior to eruption. In the case of the 1970 eruption of Akita-komagatake, the crossing point is at 150 bar and 1090°C, matching closely the observed explosive gas pressure and the temperature. In both cases of the 1783 eruption of Asama and the 1914–1915 eruption of Sakurajima volcanoes, the crossing point shift from higher water pressure and lower temperature for the earlier erupting magmas to lower pressure and higher temperature for the later magmas. This regularity may be explained by a vertical gradient of the temperature and water content within the magma column prior to eruption. 相似文献
The tsunami caused by the Great East Japan Earthquake on 11 March 2011 greatly influenced the coastal benthic environment on the northern Pacific coast of Japan. We used the direct count method to investigate changes in the abundance and distribution of Alexandrium (Alexandrium tamarense and Alexandrium catenella) cysts before and after the tsunami in Sendai Bay. Densities of Alexandrium cysts in sediments collected in summer 2011 ranged from 0 to 8,190 cysts cm?3. In the western part of the bay, the density increased greatly after the tsunami, the highest density being approximately 10 times the density recorded in 2005. Molecular identification of single cysts with multiplex polymerase chain reaction (PCR) showed that Alexandriumtamarense dominated the cyst population in the southwestern part of the bay in 2011. Furthermore, accumulation of cysts on the surface sediment after disturbance of the sediment was confirmed by a laboratory experiment. The main factor causing the drastic changes in abundance and distribution of Alexandrium cysts after the earthquake was considered to be vertical and horizontal redistribution of the cysts in sediments after the tsunami. 相似文献
The conditions under which rear-arc magmas are generated were estimated using primary basalts from the Sannome-gata volcano, located in the rear of the NE Japan arc. Scoriae from the volcano occur with abundant crustal and mantle xenoliths, suggesting that the magma ascended rapidly from the upper mantle. The scoriae show significant variations in their whole-rock compositions (7.9–11.1 wt% MgO). High-MgO scoriae (MgO > ~9.5 wt%) have mostly homogeneous 87Sr/86Sr ratios (0.70318–0.70320), whereas low-MgO scoriae (MgO < ~9 wt%) have higher 87Sr/86Sr ratios (>0.70327); ratios tend to increase with decreasing MgO content. The high-MgO scoriae are aphyric, containing ~5 vol% olivine microphenocrysts with Mg# [100 × Mg/(Mg + Fe2+)] of up to 90. In contrast, the low-MgO scoriae have crustal xenocrysts of plagioclase, alkali feldspar, and quartz, and the mineralogic modes correlate negatively with whole-rock MgO content. On the basis of these observations, it is inferred that the high-MgO scoriae represent primary or near-primary melts, while the low-MgO scoriae underwent considerable interaction with the crust. Using thermodynamic analysis of the observed petrological features of the high-MgO scoriae, the eruption temperature of the magmas was constrained to 1,160–1,220 °C. Given that the source mantle was depleted MORB-source mantle, the primary magma was plausibly generated by ~7 % melting of a garnet-bearing spinel peridotite; taking this into consideration, and considering the constraints of multi-component thermodynamics, we estimated that the primary Sannome-gata magma was generated in the source mantle with 0.5–0.6 wt% H2O at 1,220–1,230 °C and at ~1.8 GPa, and that the H2O content of the primary magma was 6–7 wt%. The rear-arc Sannome-gata magma was generated by a lower degree of melting of the mantle at greater depths and lower temperatures than the frontal-arc magma from the Iwate volcano, which was also estimated to be generated by ~15 % melting of the source mantle with 0.6–0.7 wt% H2O at ~1,250 °C and at ~1.3 GPa. 相似文献
The growth rate of ringwoodite reaction rims between MgSiO3 perovskite and periclase was investigated at 22.5 GPa and 1,800 °C for 1–24 h using the Kawai-type high-pressure apparatus. The reaction was likely to proceed by a diffusion-controlled mechanism in which the dominant diffusion mechanism was grain-boundary diffusion. The reaction constant (the width of the ringwoodite reaction rim squared divided by time) determined from these experiments was between 1.3 × 10?15 and 5.6 × 10?15 m2/s. A Pt inert marker experiment indicated that the MgO component migrated faster than the SiO2 component in ringwoodite. Thus, either Mg or O having the slower diffusion rate controlled the reaction. Because previous diffusion studies have shown that diffusion rates of O are slower than those of Mg, O would be a rate-controlling element for ringwoodite formation from MgSiO3 perovskite and periclase. The growth rate appeared to be too fast to explain the observed topographic rise (~10 km) inside mantle plumes at the 660-km discontinuity. 相似文献