Superzoned garnets in the coesite-bearing Brossasco-Isasca Unit, Dora-Maira massif, Western Alps, and the origin of the whiteschists

Rare centimeter-sized superzoned garnets (SZGs) were discovered in two coesite-bearing whiteschists of the Brossasco-Isasca Unit (BIU), southern Dora-Maira massif (DMM), Western Alps. The superzoned garnet consists of a reddish-brown almandine core crowded with inclusions of staurolite, chloritoid, kyanite, chlorite and paragonite, and of a pinkish pyrope rim with sporadic inclusions of kyanite, and magnesian chlorite. The core–rim contact is relatively sharp and marks the termination of the inclusion-rich portion. The core composition of the superzoned garnet is almost identical to, or slightly richer in Mg, than that of the rim of porphyroblastic garnet in metapelites from the same unit. In the rim of the superzoned garnet, Mg–Fe ratio increases abruptly towards the outermost rim, whose composition is identical to that of the common pyrope in the whiteschist. At the core–rim boundary, there is no chemical gap. Chloritoid and staurolite are common inclusions in the core of the superzoned garnet in the whiteschist and in the porphyroblastic garnet in the metapelite. The staurolite composition (Si=2.00 and total R²⁺<2.0 for O=23 basis) and its reverse Fe–Mg distribution with respect to garnet suggest a HP origin. The Fe–Mg distribution between chloritoid and garnet is reverse in the superzoned garnet, but normal in the garnet of metapelite. Because normal Fe–Mg distribution was reported from other eclogite-facies metapelites, a model petrogenetic grid was constructed in the FMASH model system considering St, Cld, Ky, Chl, Grt, and assuming the following Fe–Mg partitioning of St>Grt>Cld>Chl. The resulting petrogenetic grid suggests that the core of the superzoned garnet contains incompatible assemblages, such as St–Cld–Chl vs. Cld–Chl–Ky. New and literature data and results of experiments in the KFASH system suggest that: (1) the superzoned garnet was formed under a single prograde high-pressure/ultra high-pressure (HP/UHP) Alpine metamorphism, (2) the almandine inclusion-rich core of the superzoned garnet crystallized at disequilibrium in a pelitic composition system at around 600°C and less than 16 kbar, probably from a former metapelite xenolith included in a Variscan granitoid, and (3) the chemical environment of the host rock suddenly changed from the normal pelite to the whiteschist composition by a metasomatic process during the rim growth, i.e., at a stage close to the UHP climax.     

Temporal changes in benthic communities of seagrass beds impacted by a tsunami in the Andaman Sea,Thailand

Seagrass beds are susceptible to various natural and human-induced disturbances. Disturbances affect not only seagrasses, but also the abundance and diversity of associated macrofaunal communities. The Andaman Sea coast of Thailand was heavily affected by the tsunami of December 26, 2004. To examine its impact on seagrass macrofaunal communities, we compared the abundance, diversity and taxa composition by quantitative samplings in 2001 (before the tsunami) and in 2005 and 2006 (after the tsunami). Macrobenthic animals and sediments were collected from vegetated and nonvegetated areas of two sites that had received different levels of tsunami disturbances. A large decline in abundance and diversity was observed in the nonvegetated areas after the tsunami, whereas an increase was observed in the vegetated areas. The magnitude of decline and subsequent recovery of abundance and diversity of macrobenthic animals in nonvegetated areas were similar between the two sites, suggesting that their temporal changes were not solely related to the magnitude of the tsunami disturbance. Similarity of the benthic animals differed greatly between 2001 and 2005–2006 at the nonvegetated areas, whereas it varied less among the 3 years at the seagrass-vegetated areas. This study demonstrated that the presence of seagrass vegetation alters the patterns of temporal variation in macrofaunal assemblages and subsequent recovery processes following a tsunami.     

Multiple-indicator study of the response of groundwater recharge sources to highly turbid river water after a landslide in the Tedori River alluvial fan,Japan

The large volume of groundwater stored in the Tedori River alluvial fan, Ishikawa Prefecture, Japan, is an important source of local drinking and industrial water. The Tedori River was observed to be highly turbid from the beginning of May 2015 to at least November 2017 due to a landslide in the upper reach of the river. After the landslide, the groundwater level was drawn down by several to 10 m near the middle river section during paddy irrigation periods in 2015 and 2016. This study addresses the impacts of the highly turbid water on groundwater recharge from the river and paddy fields. In 2016, we sampled groundwater, river water, paddy irrigation water, paddy ponding water, and precipitation five times at 2-month intervals. We analysed the H, O, and Sr stable isotopic compositions and major dissolved ion (and Sr) concentrations and compared our data to previous data obtained in June 2011. Ca, Sr, Cl, SO₄, and TN concentrations and δ¹⁸O values were higher in June 2016 than in June 2011; these increases were more extreme along the left bank of the Tedori River than along the right bank. We explored the mixing of Tedori River water with groundwater using a two-endmember mixing model based on their Sr concentrations and isotopic compositions. Compared to June 2011, mixing ratios were decreased near the Tedori River in 2016, and larger decreases were observed along the left bank and in the middle stream area. These results confirm that the contribution to groundwater recharge from the river decreased during the turbidity event, particularly along the left bank.     

RXTE observation of NGC 6240: a search for the obscured active nucleus

We present new data taken at 850 μm with SCUBA at the James Clerk Maxwell Telescope for a sample of 19 luminous infrared galaxies. Fourteen galaxies were detected. We have used these data, together with fluxes at 25, 60 and 100 μm from IRAS , to model the dust emission. We find that the emission from most galaxies can be described by an optically thin, single temperature dust model with an exponent of the dust extinction coefficient ( k _λ ∝ λ ^{− β} ) of β ≃1.4–2. A lower β ≃1 is required to model the dust emission from two of the galaxies, Arp 220 and NGC 4418. We discuss various possibilities for this difference and conclude that the most likely is a high dust opacity. In addition, we compare the molecular gas mass derived from the dust emission, M _850 μm, with the molecular gas mass derived from the CO emission, M _CO, and find that M _CO is on average a factor 2–3 higher than M _850 μm.     

On the Role of Lightning NOx in the Formation of Tropospheric Ozone Plumes: A Global Model Perspective

A series of ozone transects measured each year from 1987 to 1990 over thewestern Pacific and eastern Indian oceans between mid-November andmid-Decembershows a prominent ozone maximum reaching 50–80 ppbv between 5 and 10 kmin the 20° S–40° S latitude band. This maximum contrasts with ozonemixing ratios lower than20 ppbv measured at the same altitudes in equatorial regions. Analyses witha globalchemical transport model suggest that these elevated ozone values are part ofa large-scale tropospheric ozone plume extending from Africa to the western Pacific acrosstheIndian ocean. These plumes occur several months after the peak in biomassburninginfluence and during a period of high lightning activity in the SouthernHemispheretropical belt. The composition and geographical extent of these plumes aresimilar to theozone layers previously encountered during the biomass burning season in thisregion.Our model results suggest that production of nitrogen oxides from lightningstrokes sustains the NO_x (= NO+NO₂) levels and the ozonephotochemical productionrequired in the upper troposphere to form these persistent elevated ozonelayers emanating from biomass burning regions.     

Progressive evolution of whole‐rock composition during metamorphism revealed by multivariate statistical analyses

The geochemical evolution of metamorphic rocks during subduction‐related metamorphism is described on the basis of multivariate statistical analyses. The studied data set comprises a series of mapped metamorphic rocks collected from the Sanbagawa metamorphic belt in central Shikoku, Japan, where metamorphic conditions range from the pumpellyite–actinolite to epidote–amphibolite facies. Recent progress in computational and information science provides a number of algorithms capable of revealing structures in large data sets. This study applies k‐means cluster analysis (KCA) and non‐negative matrix factorization (NMF) to a series of metapelites, which is the main lithotype of the Sanbagawa metamorphic belt. KCA describes the structures of the high‐dimensional data, while NMF provides end‐member decomposition which can be useful for evaluating the spatial distribution of continuous compositional trends. The analysed data set, derived from previously published work, contains 296 samples for which 14 elements (Si, Ti, Al, Fe, Mn, Mg, Ca, Na, K, P, Rb, Sr, Zr and Ba) have been analysed. The KCA and NMF analyses indicate five clusters and four end‐members, respectively, successfully explaining compositional variations within the data set. KCA indicates that the chemical compositions of metapelite samples from the western (Besshi) part of the sampled area differ significantly from those in the east (Asemigawa). In the west, clusters show a good correlation with the metamorphic grade. With increasing metamorphic grade, there are decreases in SiO₂ and Na₂O and increases in other components. However, the compositional change with metamorphic grade is less obvious in the eastern area. End‐member decomposition using NMF revealed that the evolutional change of whole‐rock composition, as correlated with metamorphic grade, approximates a stoichiometric increase of a garnet‐like component in the whole‐rock composition, possibly due to the precipitation of garnet and effusion of other components during progressive dehydration. Thermodynamic modelling of the evolution of the whole‐rock composition yielded the following results: (1) the whole‐rock composition at lower metamorphic grade favours the preferential crystallization of garnet under the conditions of the garnet zone, with biotite becoming stable together with garnet in higher‐grade rock compositions under the same P–T conditions; (2) with higher‐grade whole‐rock compositions, more H₂O is retained. These results provide insight into the mechanism suppressing dehydration under high‐P metamorphic conditions. This mechanism should be considered in forward modelling of the fluid cycle in subduction zones, although such a quantitative model has yet to be developed.     

闽粤晚白垩世古地磁学研究

在福建沙县至上杭、广东兴宁至河源上白垩统采集古地磁学定向样品３９０个（３９个采点）,进行了古地磁学研究,研究表明,闽粤两地的晚白垩世地磁学数据具有廊的重合性,福建：古地磁偏角１１．７°,地磁倾角４２．９°,地磁极位置北纬７９．４°,东径２１０．３°;广东;古地磁偏角１０．７°,古地磁倾角４４．０°,古地磁有位置北纬８０．１°,东径１９３．４°,该古寺磁学数据反映了中国华南地区自晚白垩世至今曾经厍过     

Marine artificial structures as amplifiers of Aurelia aurita s.l. blooms: a case study of a newly installed floating pier

Increase of marine artificial structures, providing more substrate for jellyfish polyps, has been argued to increase jellyfish outbreaks, although no explicit evidence exists. We report a case study demonstrating a remarkable increase of Aurelia aurita s.l. ephyrae after the installation of a floating pier (48 × 6 m) in a fishing port on the Inland Sea of Japan. Monitoring of ephyrae from January 2010, prior to the installation of the floating pier in April 2010, to July 2011, revealed that their time-weighted average density increased 3.5 fold, from 1.1 to 3.9 ephyrae m^?3, and the integrated number of ephyrae exported from the port increased 4.3 fold, from 5.7 × 10⁶ to 25 × 10⁶ ephyrae, after the installation. However, in a nearby port, a control site, the abundance of ephyrae decreased by ca. one third during the same period. Monitoring of polyps showed that they initially colonized the undersurface of the pier by August 2010, followed by a rapid population increase. They strobilated from December 2010 to May 2011. We computed the number of ephyrae released from the strobilae to be ca. 25 × 10⁶, very close to the net increase of ephyrae produced and exported from the port. This study corroborates that the installation of an artificial structure provides new a substrate for polyps, which allows them to produce more ephyrae to induce medusa blooms.     

The impact of Eurasian dust storms and anthropogenic emissions on atmospheric nutrient deposition rates in forested Japanese catchments and adjacent regional seas

Bulk precipitation and stream water chemistry data from 1993 to 2005 are used to analyze the relationship between Eurasian dust storms and nutrient deposition rates in the Kutsuki experimental forest (near Lake Biwa). From 2000 to 2005, atmospheric deposition, total nitrogen (TN), total phosphorus (TP) and dissolved silica (DSi) deposition rates increased by 26%, 132%, and 38%, respectively in the Kutsuki experimental forest. These TN and TP increases are associated with three seasonal factors: the increasing frequency and intensity of Eurasian spring dust events (March/April); the annual typhoon period (late August/September); and autumn/early winter (October to December) monsoons. The annual typhoon and monsoon winter periods are drivers for atmospheric TP and DSi deposition due to the correlation between the deposition and precipitation. In addition, increased spring dust deposition is a primarily driver for TN deposition changes. Increased emissions from urbanized areas in China (and likely Korea) affect the chemical properties of aerosols reaching downwind Japanese regions. Aerosol processes are responsible for increasing TN in aerosols, which are affected primarily by anthropogenic emissions. From 2000 to 2005, coal burning emissions from East Asia have contributed to an increase in TP (and possibly DSi) deposition rates. The observed increase in nutrient deposition did not noticeably impact short-term (5 year) stream water fluxes in the Kutsuki experimental forest. Due to plant uptake, the forest ecosystem retained atmospherically deposited N and P. Finally, the observed increases in nutrient deposition rates over the East China Sea and the Sea of Japan may significantly influence intra-annual net primary production. It is recommended that earth system modelling incorporate changes in atmospheric nutrient deposition rates and their impacts on the regional carbon cycle as well as aquatic and terrestrial ecosystems.