Wind-Tunnel and Numerical Simulations of the Coastal Thermal Internal Boundary Layer

Wind-tunnel experiments in a thermally stratified wind tunnel and direct numerical simulations were performed to simulate the thermal internal boundary layer (TIBL) that developed over a coastal area in a sea-breeze flow. The results of the simulations were analyzed to investigate turbulence structure in the TIBL. To study the effects of the atmospheric stability over the sea on the TIBL, two vertical profiles of temperature were created in the upstream portion of the wind-tunnel experiment and the direct numerical simulation. Turbulence statistics of the TIBL changed significantly according to the temperature profile over the sea, indicating that the stability of the flow over the sea has a significant effect on the structure and turbulence characteristics of the TIBL. Furthermore, the TIBL heights were estimated from the vertical profiles of the local Richardson number. The estimated TIBL heights agreed with those predicted by a pre-existing relation, suggesting that both the wind-tunnel experiment and the direct numerical simulation accurately reproduced the growth of the TIBL.     

Petrochemistry of Volcanic Rocks in the Hishikari Mining Area of Southern Japan, with Implications for the Relative Contribution of Lower Crust and Mantle-derived Basalt

Abstract. This study presents the petrographical, mineralogical, and geochemical characteristics of Late Pliocene‐Pleistocene volcanic rocks distributed in the Hishikari gold mining area of southern Kyushu, Japan, and discusses their origin and evolution. The Hishikari volcanic rocks (HVR), on the basis of age and chemical compositions, are divided into the Kurosonsan (2.4–1.0 Ma) and Shishimano (1.7–0.5 Ma) Groups, which occur in the northern and southern part of the area, respectively. Each group is composed of three andesites and one rhyodacite. HVR are characterized by high concentrations of incompatible elements compared with other volcanic rocks in southern Kyushu, and have low Sr/Nd and high Th/U, Th/Pb, and U/Pb ratios compared with typical subduction‐related arc volcanic rocks. Modal and whole‐rock compositions of the HVR change systematically with the age of the rocks. Mafic mineral and augite/hypersthene ratios of the andesites decrease with decreasing age in the Kurosonsan Group, whereas in the Shishimano Group, these ratios are higher in the youngest andesite. Similarly, major and trace element compositions of the younger andesites in the former group are enriched in felsic components, whereas in the latter group the youngest andesite is more mafic than older andesites. Moreover, the crystallization temperature of phenocryst minerals decreases with younger age in the former group, whereas the opposite trend is seen in the latter group. Another significant feature is that rhyodacite in the Shishimano Group is enriched in felsic minerals and incompatible elements, and exhibits higher crystallization temperatures of phenocryst minerals than the rhyodacite of the Kurosonsan Group. Geochemical attributes of the HVR and other volcanic rocks in southern Kyushu indicate that a lower subcontinental crust, characterized by so‐called EMI‐type Sr‐Nd and DUPAL anomaly‐like Pb isotopic compositions, is distributed beneath the upper to middle crust of the Shimanto Supergroup. The HVR would be more enriched in felsic materials derived from the lower crust by high‐alumina basaltic magma from the mantle than volcanic rocks in other areas of southern Kyushu. The Kurosonsan Group advanced the degree of the lower crust contribution with decreasing age from 51 %, through 61 and 66 % to 77 %. In the Shishimano Group, the younger rhyodacite and andesite are derived from hotter magmas with smaller amounts of lower crust component (58 and 57 %) than the older two andesites (65 % and 68 %). We suggest that the Shishimano rhyodacite, which is considered to be responsible for gold mineralization, was formed by large degree of fractional crystallization of hot basaltic andesite magma with less lower crustal component.     

Multiple‐indicator study of groundwater flow and chemistry and the impacts of river and paddy water on groundwater in the alluvial fan of the Tedori River,Japan

To investigate the source, flow paths, and chemistry of rich resources of high‐quality, shallow groundwater in the alluvial fan between the Tedori and Sai rivers in central Japan, we analysed stable isotope ratios of H, O, and Sr and concentrations of major dissolved ions and trace elements in groundwater, river water, and paddy water. The ⁸⁷Sr/⁸⁶Sr ratios of the groundwater are related to near‐surface geology: groundwater in sediment from the Tedori River has high ⁸⁷Sr/⁸⁶Sr ratios (>0.711), whereas that from the Sai River in the north of the fan has low ⁸⁷Sr/⁸⁶Sr ratios (<0.711). δ²H and δ¹⁸O values and ⁸⁷Sr/⁸⁶Sr ratios indicate that groundwater in the central and southern fans is recharged by the Tedori River, whereas recharge in the north is from the Sai River. Mg²⁺, Ca²⁺, Sr²⁺, HCO₃^?, and SO₄^2? concentrations and δ²H and δ¹⁸O values in the groundwater are high in the central fan and, except for the northern area, tend to increase with distance from the Tedori River. There are linear relationships between ⁸⁷Sr/⁸⁶Sr ratio and the reciprocal concentrations of Sr²⁺, Mg²⁺, and Ca²⁺. These geochemical characteristics suggest that as groundwater recharged from the Tedori River flows towards the central fan, it mixes with waters derived from precipitation and paddy water that have become enriched in these components during downward infiltration. These results are consistent with our hydrological analysis and numerical simulation of groundwater flow, thus verifying the validity of the model we used in our simulation of groundwater flow. Copyright © 2016 John Wiley & Sons, Ltd.     

Analysis of narrow spikes in two cosmic gamma-ray bursts

An analysis has been made of the narrow intensity spikes occurring in two cosmic gammaray bursts which were observed with a fast time resolution germanium spectrometer on board the low altitude polar orbiting satellite 1972-076B (Imhofet al., 1974a, 1975; Nakanoet al., 1974a). The bursts on 18 December, 1972 and 21 July, 1973, were also recorded on the Vela satellite system. The durations of three spikes were observed to be 0.06 s with the limits being 0.03 to 0.10 s. Four other narrow spikes were measured to have time width limits between 0.001 and 0.10 s. An additional eight spikes had widths less than 0.9 s. During the spikes, the gamma-ray intensities increased by factors of 2 to 10, with a median value of 3. These and other characteristics of the fast time structure are presented.Paper presented at the COSPAR Symposium on Fast Transients in X- and Gamma-Rays, held at Varna, Bulgaria, 29–31 May, 1975.     

Short-Range Prediction Experiments with Operational Data Assimilation System for the Kuroshio South of Japan

The short-range (one month) variability of the Kuroshio path was predicted in 84 experiments (90-day predictions) using a model in an operational data assimilation system based on data from 1993 to 1999. The predictions started from an initial condition or members of a set of initial conditions, obtained in a reanalysis experiment. The predictions represent the transition from straight to meander of the Kuroshio path, and the results have been analyzed according to previously proposed mechanisms of the transition with eddy propagation and interaction acting as a trigger of the meander and self-sustained oscillation. The reanalysis shows that the meander evolves due to eddy activity. Simulation (no assimilation) shows no meander state, even with the same atmospheric forcing as the prediction. It is suggested therefore that the initial condition contains information on the meander and the system can represent the evolution. Mean (standard deviation) values of the axis error for all 84 cases are 13, 17, and 20 (10, 10, and 12) km, in 138.5°E, in the 30-, 60-, and 90-day predictions respectively. The observed mean deviation from seasonal variation is 30 km. The predictive limit of the system is thus about 80 days. The time scale of the limit depends on which stage in the transition is adopted as the initial condition. The gradual decrease of the amplitude in a stage from meander to straight paths is also predicted. The predictive limit is about 20 days, which is shorter than the prediction of the opposite transition. This revised version was published online in July 2006 with corrections to the Cover Date.     

Preferential dissolution of SiO<Subscript>2</Subscript> from enstatite to H<Subscript>2</Subscript> fluid under high pressure and temperature

Stability and phase relations of coexisting enstatite and H₂ fluid were investigated in the pressure and temperature regions of 3.1–13.9 GPa and 1500–2000 K using laser-heated diamond-anvil cells. XRD measurements showed decomposition of enstatite upon heating to form forsterite, periclase, and coesite/stishovite. In the recovered samples, SiO₂ grains were found at the margin of the heating hot spot, suggesting that the SiO₂ component dissolved in the H₂ fluid during heating, then precipitated when its solubility decreased with decreasing temperature. Raman and infrared spectra of the coexisting fluid phase revealed that SiH₄ and H₂O molecules formed through the reaction between dissolved SiO₂ and H₂. In contrast, forsterite and periclase crystals were found within the hot spot, which were assumed to have replaced the initial orthoenstatite crystals without dissolution. Preferential dissolution of SiO₂ components of enstatite in H₂ fluid, as well as that observed in the forsterite H₂ system and the quartz H₂ system, implies that H₂-rich fluid enhances Mg/Si fractionation between the fluid and solid phases of mantle minerals.     

Geochemical assessment of arsenic contamination in well water and sediments from several communities in the Nawalparasi District of Nepal

Arsenic contamination of well water is a serious issue in the Nawalparasi District of the Terai region in Nepal. A local investigation was carried out on 137 tube wells in 24 communities of the district in December 2011. The investigation revealed that the average arsenic concentration in the tube wells was 350 μg/L, and that nearly 98 % of the wells exceeded the WHO guideline arsenic level limit of 10 μg/L. Highly contaminated well water, with more than 400 μg/L of arsenic, was found within the limited depth ranges of 18–22 and 50–80 m. High arsenic levels exceeding 500 μg/L were detected in shallower wells at Patkhauli, Mahuawa, Thulokunwar, and Goini located between 27.517° and 27.543°N and between 83.648° and 83.748°E. Boring sampling at five communities of Kashiya, Goini, Sanokunwar, Thulokunwar, and Mahuawa revealed two aquifers located at the two depths around 14–22 and 41–50 m in each community. Dark gray or black-colored peaty clay layers rich in organic matter were distributed at depths of 18–21 m beside the upper aquifers with high arsenic concentration in each community. Positive correlations were shown between iron and arsenic in the sediments from the five communities. It can be inferred that these results were caused by dissolution of iron-oxyhydroxide molecules with arsenic from solid phases. Microbial metabolisms have a great potential to induce the dissolution and release arsenic attached on the solid phases into aqueous phases depending on the level of redox potential and pH.     

Occurrence of hydroxylated polychlorinated biphenyls in the brain of cetaceans stranded along the Japanese coast

Levels of hydroxylated polychlorinated biphenyls (OH-PCBs) and PCBs were measured in the brain of melon-headed whales (MW: Peponocephala electra), striped dolphins (SD: Stenella coeruleoalba) and finless porpoises (FP: Neophocaena phocaenoides) stranded along the Japanese coast during 2002-2003. Levels of OH-PCBs (including identified and unknown OH-P(5)CB, -H(6)CB, -H(7)CB and O(8)CB congeners) in the brain of MW, SD and FP were in the range of 20-290, 21-330 and 170-240pg/g wet wt., respectively. Observed OH-PCB levels were 2-3 orders of magnitude lower than PCBs in the same individuals. OH-PCBs/PCBs ratios in MW, SD and FP brain were lower than those in blood of humans and wildlife and in the brain of polar bears reported previously. OH-PCBs were also detected in maternal and fetal brain of SD (1 pair), suggesting transfer of OH-PCBs into the fetal brain of odontocete cetaceans. When fetus/dam concentration ratios of OH-PCB congeners detected in maternal and fetal brain were estimated, the values were higher than those of PCB congeners, implying that OH-PCBs in maternal blood could be more easily transferred into fetal brain via placenta than PCBs.