Bentonite clay is a micro-inhomogeneous material, which consists of clay minerals (mainly montmorillonite), macro-grains (mainly quartz), water, air and others. Properties of the saturated bentonite clay are essentially characterized by the montmorillonite and water (i.e. montmorillonite hydrate). We analyze the molecular behavior of sodium montmorillonite hydrate Na1/3Al2[Si11/3Al1/3]O10(OH)2·nH2O by applying a molecular dynamics (MD) simulation method. And by using the MD results we calculate the swelling property of the montmorillonite hydrate, and compare with an experimental result. Next, by using the same MD procedure we treat a montmorillonite mineral with a large number of external water molecules to check the properties of the water. Here we treat pure- and salt-water. Then we calculate the diffusivity and viscosity of water molecules and Na+ and Cl− ions.
For extending the microscopic characteristics of constituent materials to a macroscopic seepage behavior of the micro-inhomogeneous material we apply a homogenization analysis (HA). That is, starting with the Navier–Stokes equation with distributed viscosity that is calculated by the former MD procedure we determine macroscopic permeability characteristics of bentonite for both cases of pure- and salt-water. Then, by using the permeability property we calculate long-term consolidation behavior of buffering clay, which is planed to be used for high-level radioactive waste (HLRW) management. Here the deformation is treated under the well-defined Cam clay model. 相似文献
The stable growth condition of a segregated ice layer is studied by the use of the principle of mass and heat conservation. This condition evidently depends upon the properties of a thin transitional zone, which is believed to exist between the boundary of an ice layer and a 0[°C] isotherm. All probable models of the transitional zone are classified and the conditions for each model is derived. The effect of the small amount of soil minerals contained in an ice layer is also studied. 相似文献
The forming star grows by mass inflow from the parent cloud core, mainly through the accretion disk. However, the core matter which has not yet contracted much is seriously disturbed by the activities of the forming star. We consider mass outflow and emission of ultraviolet radiation as such activities and determine the stellar mass as a function of the physical quantities of the parent cloud core. 相似文献
The magma–ore deposit relationship of most low-sulfidation epithermal ore deposits is still unclear, partly because many stable isotopic studies of such deposits have indicated the predominance of meteoric waters within hydrothermal fluids. However, it is certainly true that hydrothermal systems are ultimately driven by magmatic intrusions, and epithermal gold deposits might therefore be produced by magmatic activity even in deposits having has no obvious links to a magma. We re-examine the genesis of two typical low-sulfidation epithermal gold deposits, the Kushikino and Hishikari deposits, using structural simulations and isotope data.Many epithermal gold deposits including the Kushikino and Hishikari deposits have been discovered in Kyushu, southwestern Japan. The Kushikino deposit comprises fissure-filling veins within Neogene andesitic volcanics that overlie unconformably Cretaceous sedimentary basement. The veins consist of gold- and silver-bearing quartz and calcite with minor amounts of adularia, sericite and sulfides. Although carbon and oxygen isotopic data for the veins indicate a meteoric origin of the ore fluid, finite element simulations suggest that the vein system might have formed in direct response to magma intrusion. In particular, geophysical data suggest that intruding magma has uplifted the basement rocks, thereby producing fractures and veins and a positive Bouguer anomaly, and providing the heat necessary to drive an ore-forming hydrothermal system.The second component of this study has been to investigate the nature and evolution of the Kushikino and Hishikari epithermal systems. Isotope data document the geochemical evolution of the hydrothermal fluids. We conclude that the existence of sedimentary basement rocks at depth might have affected the strontium and carbon isotopic ratios of the Kushikino and Hishikari ore fluids. The 87Sr/86Sr ratios and δ13C–δ18O trend reveal that major ore veins in the Hishikari deposit can be distinguished from shallow barren veins. It was suggested isotopically that fluids responsible for the barren veins in nearby shallow and barren circulation systems were only controlled by the shallow host rocks. Such multi-isotope systematics provide a powerful tool with which to determine the center of hydrothermal activity and thereby document the evolution of hydrothermal fluids. 相似文献
Siphonaria pectinata is a marine gastropod distributed across the shores of the Western and Eastern Atlantic. Although previous studies have indicated that the species could be a recent introduction to Central and North America from Western Africa and Europe, other authors have questioned this statement. In fact, a recent study has shown that individuals from both sides of the Atlantic are genetically disconnected, rejecting the idea of a recent invasion. However, genetic information on this species is very scarce and based only on a single study using a limited number of specimens and sites. The data reported in the present study represent one step forward, collecting information from 119 specimens from 22 sites that cover the entire distributional range of the species. Populations from the Western Atlantic separated from eastern ones around 1.4?1.9 Mya, whereas the centre of dispersion is located on the eastern side of the Atlantic. Siphonaria pectinata should be considered native to the Western Atlantic and cannot be considered as a species with an amphi‐atlantic distribution owing to the lack of genetic connection between both sides of the Atlantic, as previous authors have pointed out. The presence of a star‐shaped phylogeny is discussed in the context of Plio‐Pleistocene glaciations. 相似文献
We have developed new systems capable of profiling to >1000 m for measuring in situ pH and fugacity of CO2 (fCO2) in the ocean using spectrophotometric analysis (pH and CO2 profilers). The in situ pH is determined by detecting the color change of the pH indicator (m-cresol purple). It can withstand ambient pressure to 1000 m depth. The CO2 profiler analyzed in situ fCO2 by detecting the change of pH in an inner solution, equilibrated with the seawater through a gas permeable membrane. It can
be operated to 2500 m depth. We used an amorphous fluoropolymer tubing form of AF-2400 for the gas permeable membrane due
to its high gas permeability coefficients. The inner solution was a mixture of 2 μM bromocresol purple (BCP) and 5 μM sodium
hydroxide. This system gave us a response time of 1 minute, which is twice as fast as previous systems. The precisions of
pH and CO2 profilers were within 0.002 and 2.5% respectively. We have used these profilers to study the North Pacific, obtaining good
agreement with the difference between the data from profilers and a discrete bottle of 0.002 ± 0.005 pH (SE, n = 25) and −0.4
± 3 μatm (SE, n = 31). 相似文献
The detailed structures of baroclinic eddies, that is, an anticlockwise circulation in the upper layer and a clockwise one in the lower layer south of Cheju Island in the East China Sea have been revealed by intensive field observation. Such baroclinic eddies are accompanied by the southward spreading of the Yellow Sea Bottom Cold Water. 相似文献
The seiches occurring in two adjacent bays, Koaziro Bay and Moroiso Bay, situated in Miura Peninsula at the mouth of Tokyo Bay, are very regular, and the phenomenon of beat appears in their amplitudes of oscillation. Nakano once presented a theoretical explanation of this phenomenon, considering two rectangular bays of the same size and form as well as of uniform depth, by assuming that a kind of coupling takes place between the two bays through a portion of water flowing across the mouth of each bay. In the present paper, the validity of the theory has been proved in a series of hydraulic model experiments. The experiments have shown that, in the case of the two adjacent rectangular bays mentioned above, there are two distinct modes of oscillation viz. (i) the co-phasic oscillation and (ii) the contra-phasic oscillation, and since the frequencies of these oscillations are close to each other, when they come to interfere, the beat phenomenon occurs.It has also been found that, when a tsunami wave enters the two bays, the mode of oscillation of the seiches occurring in them changes in the following manner: the co-phasic oscillation the oscillation accompanied with the beat phenomenon the contra-phasic oscillation. As regards this phenomenon, the authors have presented a possible explanation by considering the dissipation of energy due to wave scattering. 相似文献