Complexation and reduction as factors in the link between metal ion concentrations and organic matter in the Indian River

Complexation of metal ions by organic matter is frequently considered to play a part in metal ion dissolution in natural waters. A field study of a relatively unperturbed stream, high in organics, associates this with the fraction related to soil organic acids (humic acids). The association might have two origins. The first is complexation. However, well known sequences of complexing tendency do not predict the behaviour. A better theory uses the additional factor of the reducing capacity of dissolved organic matter toward Fe(III) and Mn(IV).     

Chemical study of limestone and clay for cement manufacturing in Darukhula,Nizampur District,Nowshera, North West Frontier Province （N.W.F.P.）, Pakistan

Limestone and clay samples were collected from Darukhula and adjoining areas of the Nizampur District Nowshera, N.W.EE, Pakistan, and analyzed for different parameters in order to search for new reserves of suitable material for the manufacture of different types of cements in N.W.F.P. It was found that the area under study contains three types of limestones, including high grade limestone, Darukhula limestone and siliceous limestone, which contain 53%, 49.03% and 45.19% CaO, respectively, and three types of clay, including maroon color, yellow to yel- lowish-green color and green color clay containing 57.76%, 65.47% and 61.24% SiO2, respectively. Chemical analysis of the limestone and clay samples collected from the deposits in the area under study showed that all the elements found in these samples are within the range of permissible limits for the production of high-strength Portland cement, sulphate resisting cement and white cement. This paper covers the detailed version of the potential raw material deposits at Darukhula and adjoining areas of the Nizampur District.     

Residual impact of biochar on cadmium uptake by rice (<Emphasis Type="Italic">Oryza sativa</Emphasis> L.) grown in Cd-contaminated soil

Cadmium (Cd) is the family member of toxic heavy metals, and its accumulation in food crops has become a global environmental constraint. Biochar potentially minimizes the metal contents in plants, but limited work has been reported on its residual effect on subsequent crops. The residual effect of various biochar levels (0, 1.5, 3.0, and 5.0% w/w) on Cd accumulation in rice has been investigated in this study. Biochar treatments enhanced the rice growth, photosynthesis, and antioxidant enzymes, whereas diminished the Cd contents and oxidative stress in rice. Cadmium concentration in shoots decreased by 24.4, 36.6, and 57.5% in 1.5, 3.0, and 5.0% biochar treatments over the control. Biochar supply enhanced the soil pH and electrical conductivity, whereas diminished the soil bioavailable Cd. Overall, the results depicted a significant residual impact of rice straw biochar on rice growth attributes and Cd uptake. However, studies are still needed to explore the long-term sustainability of biochars prepared from different feedstocks on bioavailability of toxic metals in soils and uptake by food crops under field conditions.     

Improvement in Engineering Properties of Expansive Soils using Ground Granulated Blast Furnace Slag

Improvement in engineering properties of expansive soils by mixing ground granulated blast furnace slag (GGBFS) is the main focus of this research. For this purpose two expansive soil samples were collected from DG Khan and Sialkot areas (Pakistan). Classification tests revealed that DG Khan sample belonged to fat clay (CH) while Sialkot soil was lean clay (CL) as classified by Unified Soil Classification System. GGBFS has been added in varying proportions between 0 and 55% in these soil samples to study its role in stabilizing these expansive soils. Based on the laboratory test performed on composite soil samples, it was observed that maximum dry unit weight increased up to 10 % by adding 50% GGBFS in both samples. California bearing ratio (CBR) value showed an increase from 3.2 % to 11.5% for DG Khan soil while CBR values varied from 2.4% to 10.7% for Sialkot soil by mixing 50% GGBFS. Addition of 30 % GGBFS to DG Khan soil reduced swell potential from 8 % to 2 % while in Sialkot soil, 20 % addition of GGBFS reduced swell potential from 5 % to 2 %. Unconfined compressive strength of remoulded sample cured for 28 days increased by about 35% with the addition of 30%GGBFS. The results indicated that mixing of GGBFS in the expansive soil samples have a marked increase in their engineering properties. Also, it is an affective and environmental friendly means to dispose waste of steel industry.     

Gas and fluid venting at the Makran accretionary wedge off Pakistan

The Makran accretionary complex shows a distinct bottom-simulating reflector, indicating a thick gas-hydrate-bearing horizon between the deformational front and about 1350 m water depth which seals off the upward flow of gas-charged fluids. A field of presently inactive mud diapirs with elevations up to 65 m was discovered in the abyssal plain seawards of the deformation front, suggesting that in the past conditions were favorable for periodic but localized vigorous mud diapirism. Regional destabilization of the gas hydrate leading to focused flow was observed where deep-penetrating, active faults reach the base of the gas-hydrate layer, as in a deeply incised submarine canyon (2100–2500 m water depth). At this location we discovered seeps of methane and H₂S-rich fluids associated with chemoautotrophic vent faunas (e.g., Calyptogena sp.). Driven by the accretionary wedge dynamics, the landward part of the gas-hydrate layer below the Makran margin is being progressively uplifted. Due to reduced hydrostatic pressure and rising ocean bottom-water temperatures, gas hydrates are progressively destabilized and dissociated into hydrate water, methane and H₂S. Sediment temperatures lie outside the methane stability field wherever water depth is less than 800 m. Above this depth, upward migration of fluids to the seafloor is unimpeded, thus explaining the abundance of randomly distributed gas seeps observed at water depths of 350 to 800 m. Received: 14 June 1999 / Revision accepted: 6 February 2000     

Pulse-like ground motion observed during the 6 February 2023 MW7.8 Pazarcık Earthquake (Kahramanmaraş, SE Türkiye)

In this study, we analyzed 100 three-component strong ground motion records observed within 200 km of the causative fault of the 6 February 2023 M_W7.8 Pazarcık (Kahramanmaraş) Earthquake in SE Türkiye. The wavelet method was utilized to identify and analyze the characteristics of pulse-like ground motions in the near-fault region, while considering the uncertainty of the pulse orientation during the analysis. Our investigation focused on the effects of the focal mechanism and rupture process on the spatial distribution, pulse orientation, and maximum pulse direction of the observed pulse-like ground motion. We also analyzed the amplitude and period of the observed ground pulses and the effect of long-period amplification on the ground motion response spectra. Our results indicated the following: (1) A total of 21 typical ground velocity pulses were observed during this earthquake, exhibiting complex characteristics due to the influence of the strike-slip mechanism and rupture directivity. Most ground pulses (17 out of 21) were recorded within 20 km of the fault, in a wide range of orientations, including normal and parallel to the fault direction. The waveforms exhibited unidirectional features, indicating the effects of left-lateral fault slip. Distinct pulses observed more than 20 km from the fault were mainly oriented normal to the fault. The waveforms were bidirectional with double- or multi-round trips as a result of rupture directivity. (2) The amplitudes of the observed pulses ranged from 30.5 to 220.0 cm/s, with the largest peak velocity of 220.0 cm/s observed at Station 3138. The pulse periods ranged from 2.3 to 14.5 s, with the longest pulse period of 14.5 s observed at Station 3116. The amplitude and period of the pulses observed during this earthquake were comparable to those of similar-magnitude global earthquakes. The amplitude of the pulses decreased significantly with increasing fault distance, whereas the pulse period was not significantly affected by the fault distance. (3) Compared with non-pulse records, the velocity pulse records had a pronounced amplification effect on the acceleration response spectra near the pulse period, with factors ranging from 2.1 to 5.8. The larger velocity pulses also significantly amplified the velocity response spectra, particularly over the long periods. This significant amplification effect of the pulses on the response spectra leads to empirical models underestimating the long-period earthquake ground motion.     

GIS技术在城市地下水重金属浓度识别与分级中的应用（英文）

Groundwater is the most appropriate and widely used source of drinking water,which is increasingly threatened by pollution from industrial and agricultural activities.To check the severity of the problem,156 groundwater samples were collected from various depths(60-110 ft) of 52 different localities in Faisalabad city,the third largest metropolis in Pakistan,and analyzed for the metals(Zn,Cu,Cd,Ni,Pb,Mn and Fe) concentration in 2009.Quantification was done by using Flame Atomic Absorption Spectrophotometer technique and the results were compared with WHO standards for drinking water quality.Results showed that the levels of Cu,Mn and Fe were below the WHO standards while the concentrations of Zn,Cd,Ni and Pb were above the recommended levels of safe drinking water.Correlation analysis among the occurrence of these heavy metals revealed a highly significant and positive correlation of Mn with Zn and Fe.A significant and positive correlation of Cd was also found with Cu and groundwater depth showing that there is strong association between Cu-Cd pair and that the Cd concentration varies with depth of groundwater in the study area.Regional patterns of heavy metals occurrence were mapped using Geographical Information System(GIS) for the identification and demarcation of risk areas.The concentration maps may be used by policymakers of the city to mitigate groundwater pollution.     

Addition of Phosphorus and Nitrogen Support the Invasiveness of Alternanthera Philoxeroides Under Water Stress

Coordination of plant functional traits with changes in the environment is helpful to understand the mechanisms underlying both invasiveness and adaptation of plants. Thus, to investigate the performance and functional traits in invasive Alternanthera philoxeroides (Mart.), an experiment of water stress is conducted with different nutrient concentrations. Alternanthera philoxeroides plants are grown under natural and nutrient soils and subjected to three levels of nitrogen (N) and phosphorus (P) solution: ambient P and N concentration (P?N?), P addition with an ambient N concentration (P+N?), and P addition with high N concentration (P+N+) in combination with three different irrigation water levels as 1) 100% irrigation, 2) 50% irrigation, and 3) 25% deficit irrigation. Based on results, A. philoxeroides produces significantly higher biomass in both soils under 100% irrigation with P+N? treatment and exhibits higher values of leaf area and root length. However, 25% irrigation with P?N? treatment in both soils exerts a significant negative effect on relative growth rate and root/shoot ratio of A. philoxeroides plants. Under 50% irrigation in soils with both P+N? and P+N+ treatments, high values of leaf nitrogen are recorded. Moreover, nutrient soil is more supportive to A. philoxeroides than natural soil.     

Random Forest and Bayesian Network Techniques for Probabilistic Prediction of Flyrock Induced by Blasting in Quarry Sites

Natural Resources Research - Flyrock is one of the most important environmental and hazardous issues in mine blasting, which can affect equipment and people, and may lead to fatal accidents....