Structuration profonde des dépôts de l'Albien–Maastrichtien en Tunisie centrale : nouvelle limite de l'archipel de Kasserine et implications géodynamiques

The Albian–Maastrichtian seismic horizon analysis in central Tunisia (Gafsa–Sidi Bouzid area) using the reflection seismic sections calibrated to the well data, shows buried structures with deposit distributions and sedimentation geometries varying from the depressive to uplifted zones. Pinch outs, unconformities and hiatuses recognized on the folded high structures are caused by reactivation of the bordering faults. The Turonian–Maastrichtian unconformities correspond to the palaeogeographic limits that outline the Kasserine Islets and correspond to the N120, N180 major wrench-salt-intruded corridors and associated N90, N60 strike-slip faults. Formation of the different structures and evolution of the basins and platforms were controlled by conjugate dextral and sinistral strike-slip movements. These structures allow new palaeogeographic limits of the Kasserine Islets to be identified. To cite this article: T. Zouaghi et al., C. R. Geoscience 337 (2005).     

Vibration analysis of rectangular Mindlin plates on elastic foundations and vertically in contact with stationary fluid by the Ritz method

In this study Free vibration analysis of vertical rectangular Mindlin plates resting on Pasternak elastic foundation and fully or partially in contact with fluid on their one side is investigated for different combinations of boundary conditions. The plate is assumed to be one of vertical rectangular walls of a container in contact with fluid. In order to analyze the interaction of the Mindlin plate with the elastic foundation and fluid system, three displacement components of the plate are expressed in the Ritz method by adopting a set of static Timoshenko beam functions satisfying geometric boundary conditions in a Cartesian co-ordinate system. The method of separation of variables and the method of Fourier series expansion is used to model fluid and to obtain the exact expression of the motion of fluid in the form of integral equations. The fluid domain is finite in depth and width but infinite in the length direction. To demonstrate the accuracy of the present solution, convergence study is first carried out and then a few comparison studies are carried out with the available data in the literature. Finally, natural frequencies of rectangular plates are presented in tabular and graphical forms for different fluid levels, foundation parameters, aspect ratios, thickness to width ratios and boundary conditions.     

Chemical Aspects of Fractional Crystallization of Fatty Acid Methyl Esters Produced from Waste Fats

Fractional crystallization of fatty acid methyl esters (FAME) produced from waste cooking oil or animal fats was performed in a laboratory-scale facility. The raw esters and the “winterization” products were analyzed by determining the FAME pattern, iodine and peroxide numbers as well as oxidation stabilities and element concentrations. Fractionation experiments under air and nitrogen were conducted, but no differences concerning oxidative stability were observed. By improvement of the winterization and washing the filtration residue with methanol, the enrichment of saturated FAME in one step was raised up to a technically sufficient rate of 85%. Absorption of oxygen by FAME at different temperatures was measurable. Volatile decomposition products were registrated after heating the FAME at different temperatures. It was shown that antioxidants like butylhydroxytoluene or α-tocopherol were enriched in the phase of unsaturated FAME. This effect obviously affected the oxidative stability of the fraction of saturated FAME during winterization, although no oxidative damage of FAME was detectable at temperatures up to 20°C.     

Neogene sediment deformations and tectonic features of northeastern Tunisia: evidence for paleoseismicity

The Neogene stratigraphic series is characterized by predominant clayey facies alternated by other sand layers. The outcrop and subsurface studies show varied and complex styles of deformations and lead to relate the structures to paleoseismic events. The seismicity of eastern onshore and offshore Tunisian margin follows the master fault corridors oriented globally N–S, E–W, and NW–SE that correspond to the bordering faults of grabens and syncline corridors and associated faulted drag fold structures oriented NE–SW. Epicenters of magnitudes between 3 and 5 are located along these border fault corridors. The Neogene strata record brittle structures, including numerous and deep faults and fractures with straight and high-angle dipping planes. The structuring of NE–SW en echelon folds and synclines inside and outside NW–SE and E–W right lateral and N–S and NE–SW left lateral tectonic corridors indicates the strike-slip type of bordering faults and their seismogenic nature. Wrench fault movements that induce mud and salt diapirs, mud volcanoes, and intrusive ascensions are related to seismic shocks. Seismic waves caused by activity along one, or most likely, several tectonic structures would have propagated throughout the Quaternary cover producing seismites. The similarity of deposits, structuring, and seismites between the Tunis-Bizerte to the North and Hammamet-Mahdia to the South accredits the hypothesis that the seismic episodes might have affected sedimentation patterns along the Sahalian large geographic area. The paleoseismic events in northeastern Tunisia might be related to tectonic fault reactivations through time. This hypothesis is consistent with the geomorphologic context of the study area, characterized by several morphostructural lineaments with strong control on the sediment distribution, as well as uplifted and subsiding terrains. The estimated magnitude of the seismic events and the great regional tectonically affected areas demonstrate that the northeastern Tunisia experienced stress through the last geological episodes of its evolution. This Neogene kinematic reconstruction highlights the neotectonic system inducing the actual seismicity on this margin. Therefore, there is a straight relationship between deepseated faults and seismicity.     

Flame Atomic Absorption Spectrometry Determination of Trace Amounts of Cadmium and Zinc in Water Samples after Preconcentration onto Modified Amberlite XAD‐4 Resin

In the present article, a procedure for the simultaneous separation and preconcentration of trace amounts of cadmium and zinc is proposed. It is based on the adsorption of cadmium and zinc ions onto a column of Amberlite XAD‐4 resin loaded with aluminon reagent. Cadmium and zinc ions are quantitatively retained on the column in the pH range from 6.5–7.5, at a flow rate of 2 mL min^–1. The cadmium and zinc ions are eluted with 5.0 mL of 5 mol L^–1 HNO₃ solution. Cadmium and zinc are measured by flame atomic absorption spectrometry (FAAS). In the present case, 0.1 μg of cadmium and 0.5 μg of zinc can be concentrated in the column from 1000 mL of aqueous sample, where their concentrations are as low as 0.1 and 0.5 ng mL^–1, respectively. The relative standard deviations, for seven replicated determinations of 1.0 μg mL^–1 of cadmium and zinc, are 1.2 and 1.1%, respectively. The detection limits for cadmium and zinc in the original solution are 0.02 and 0.11 ng mL^–1, respectively. The interference of a large number of anions and cations has been studied and the optimized conditions are utilized for the determination of trace amounts of cadmium and zinc in different environmental and standard samples.     

Heavy metal concentrations in surficial sediments from Wadi El Natrun saline lakes, Egypt

Heavy metal concentrations of Wadi El Natrun saline lakes were investigated. Pb, Zn, Mn, Cu, Cd, Ni, Fe and Al were measured in surficial sediments. The heavy metal concentrations largely indicate the influence of weathering of terrigenous sources on land. In comparison with the average in sedimentary rocks, the concentrations of the heavy metals studied are higher than the global average sandstone. This is also reflected in the high enrichment factors. The heavy metal concentration in lakes II and III decrease in the order Pb > Zn > Cu, while in lake I the decreasing order is Cu > Zn > Pb. Sediments with microbial mats were found to concentrate heavy metals above background sediment values.     

Proposing a formula for evaporation measurement from salt water resources

Evaporation involves the change in state of a liquid to a vapour. The evaporation rate from salt‐water resources depends mostly on saturated vapour pressure above its surface. On the other hand, the saturated vapour pressure is affected by the ion activity coefficient, which stems from the chemical salt concentration of water. Thus, an increase in concentration of water results in a reduction of saturated vapour pressure. In order to acquire the actual rate of evaporation from salt‐water resources, a uniform set of evaporation pans with different but specified salt concentrations were used, in a meteorological station under the same conditions. The difference in evaporation rate of each pan can only stem from the difference in chemical salt concentration and, indeed, the molar fraction of water in each saline solution. Therefore, by applying the water molar fraction in the pressure term of fresh‐water evaporation measurement formulas, these equations were developed further for determination of evaporation rate from salt‐water resources. The proposed formulas using very simple terms seem to be suitable for determination of evaporation rate from any water (typically saline, semi‐saline and fresh water) with a satisfactory precision. Copyright © 2007 John Wiley & Sons, Ltd.