The influence of industrial immissions on the magnetic susceptibility of soils in upper Silesia

Summary Samples of metallurgical dusts and fly ashes from coal power plants and iron works in Upper Silesia as well as soil profiles in the close vicinity of these plants and in Ojcow National Park (ca. 25 km east of the industrial area) have been studied magnetically and mineralogically. The metallurgical dusts and fly ashes are highly enriched in ferromagnetic minerals. The topsoils from profiles collected near the plants have very high values of magnetic susceptibility while susceptibility in the fermentation and humic subhorizons in soil profiles from Ojcow National Park is considerably increased. The magnetic properties of the metallurgical dusts and fly ashes such as frequency dependence of susceptibility, saturation remanence or coercivity are similar to those observed in the top horizons of the soils. They are mostly related to the occurrence of large (multidomain) grains of non-stoichiometric magnetite ranging from 1 to 20 μm. The similarity of the magnetic particles in the soils is taken as evidence of an anthropogenic origin. They are responsible for the high soil susceptibilities in Upper Silesia and in adjacent areas. Some of the magnetic particles carry substantial quantitities of trace elements such as Pb, Ni, Zn and Cu. Field and laboratory susceptibility measurements can therefore be used as a simple and costeffective method of detecting the presence of heavy metals in the soils of this area.     

Floods at the northern foothills of the Tatra Mountains — A Polish-Swiss research project

The present paper introduces the topical area of the Polish-Swiss research project FLORIST (Flood risk on the northern foothills of the Tatra Mountains), informs on its objectives, and reports on initial results. The Tatra Mountains are the area of the highest precipitation in Poland and largely contribute to flood generation. The project is focused around four competence clusters: observation-based climatology, model-based climate change projections and impact assessment, dendrogeomorphology, and impact of large wood debris on fluvial processes. The knowledge generated in the FLORIST project is likely to have impact on understanding and interpretation of flood risk on the northern foothills of the Tatra Mountains, in the past, present, and future. It can help solving important practical problems related to flood risk reduction strategies and flood preparedness.     

Formaldehyde in Various Forms of Atmospheric Precipitation and Deposition from Highly Urbanized Regions

Formaldehyde levels were determined in various forms of atmospheric precipitation (rain, snow, road and roof runoff, throughfall) and deposition (rime, hoarfrost, dew) collected over twelve months at various locations in two large urban agglomerations and along two highways. HCHO was found in 303 of 500 samples analyzed, with concentrations ranging from 0.05 to 10.7 mg/dm³. The results confirmed the significant effect of vehicular traffic on formaldehyde levels in various forms of wet deposition. Correlations of formaldehyde levels with other parameters commonly monitored in precipitation and/or deposition were also examined. No correlation was found between HCHO levels and rain volume. On the other hand, positive correlations were found for hydrogen peroxide, non-sea-salt sulphate, nitrate, ammonia, and total organic carbon (TOC). In addition, the effect of selected meteorological parameters (temperature, wind speed, wind direction, rainfall) on the concentration of formaldehyde in various forms of precipitation and runoff (road runoff, roof runoff, throughfall) was studied. The only correlation found was that between HCHO concentration and daily rainfall.     

Applying numerical modeling for designing strategies of effective groundwater remediation

Selection of effective groundwater remediation scenarios is a complex issue that requires understanding of contaminants’ transport processes. The effectiveness of cleanup measures may be verified by fate and transport numerical modeling. The goal of this work was to present the usefulness of fate and transport modeling for planning, verification and fulfillment of effective groundwater remediation methods. Selection methodology was developed, which is based on results of numerical flow and transport modeling. A field site located in south-east Poland was selected as a case study, in which groundwater contamination of trichloroethene and tetrachloroethene was detected. The results indicated that “pump and treat” was the most effective among the studied remediation methods, followed by permeable reactive barrier and in situ chemical oxidation. Natural attenuation-based remediation was demonstrated to be the least suitable, as it requires the longest time to reach predefined remediation goals, principally due to low sorption capacity and unfavorable hydrogeochemical conditions for biodegradation. Fate and transport numerical modeling allowed simulating different remediation strategies, and thus the decision-making process was facilitated.     

Macrocrystic corundum and Fe–Ti oxide minerals entrained in alkali basalts from the Eger (Ohře) Rift: Mg−Fe3+-rich ilmenite as tracer of an oxidized upper mantle

Macrocrysts of corundum, ilmenite, and spinel-group minerals from alluvial deposits of the Eger Rift were studied for composition, texture, and mineral inclusions. All macrocrysts show usually magmatic corrosion textures indicating disequilibrium with the transporting alkali-basalt magma. Corundum grains, exclusively sapphires, were classified by trace-element signatures as magmatic and metamorphic types. Some sapphire grains show erratic compositions that may have resulted from a metasomatic overprint. The inclusion inventory of magmatic corundum suggests crystallization from a differentiated alkaline silicate melt. Corundum itself was never observed as an inclusion mineral. Magnesium- and Fe³⁺-rich ilmenite, described as typical mantle-derived species, is the dominant heavy mineral in almost all alluvial deposits of the Eger Rift. Most discrete macrocrysts are similar in appearance and composition to kimberlite- and basanite-related ilmenite. Ilmenite included in alluvial corundum and zircon grains differ from the bulk of discrete ilmenite grains by larger concentrations of Nb and Mn. The mantle origin of the Mg–Fe³⁺-rich ilmenite is confirmed by compositional and thermo-barometric comparison with ilmenite from clinoproxenitic and hornblenditic xenoliths, which probably originated in the Moho region. The Fe–Ti two-oxide geothermometry and oxygen-barometry of coexisting ilmenite–magnetite pairs yield equilibrium temperatures between 900 and 1,080 °C and oxygen fugacities log₁₀fO₂ between ?0.1 and 1.1 (relative to the NNO buffer), which indicate that the upper mantle as well as the mantle/crust transition zone below the rift is at least partially oxidized. The ilmenite macrocrysts were transported from the source region to the surface by explosive alkali-basalt magmas, as implied by the presence of basaltic-pipe breccias in close vicinity to some placer deposits.     

Long-term variability of occurrence of precipitation forms in winter in Kraków, Poland

The paper discusses long-term change in snowfall, rainfall and mixed precipitation viewed in conjunction with air temperature and North Atlantic Oscillation (NAO) in winter (December–February). In the study of contemporary climate change and its effect on the hydrological cycle it is useful to focus on winter precipitation forms. A 146-year secular observation series from Kraków, spanning the period 1863–2008, was used to extract data on the number of days with precipitation and on precipitation amount broken down by form. Statistically significant trends were found in total and mixed precipitation, but not in snowfall and rainfall. The climate warming effect has contributed to a material decrease in the snowfall to total winter precipitation ratio during the second half of the 20th c. The highest impact of air temperature was found in the wintertime variation in number of days with snowfall while the NAO had a significant influence on the frequency and amount of both rainfall and snowfall.     

Mesolite from Horní Jílové, Bohemia

Summary Hey(1936) called attention to discrepancies in the identification of the metascolecite (Michel, 1920) from the Horní Jílové (Ober Eulau) locality in Bohemia. In a check study this mineral has been determined as mesolite, a zeolite hitherto not described from this locality. The mineral was identified using optical, chemical, thermal, IR-spectroscopic and X-ray methods. Radial aggregates of mesolite occur in fissures of contact metamorphosed marls in the proximity of a phonolite intrusion. In terminal parts mesolite often changes into scolecite.

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Mesolit aus Horní Jílové, Böhmen

Zusammenfassung Hey(1936) hat auf die Widersprüche in der Bestimmung des Metaskolezites (Michel, 1920) aus der Horní Jílové (Ober Eulau) Lokalität in Nordböhmen aufmerksam gemacht. Auf Grund einer Revisionsstudie wurde dieses Mineral als ein aus dieser Lokalität bisher nicht beschriebener Zeolit, nämlich Mesolit, bestimmt. Das Mineral wurde mit optischen, chemischen, thermischen, IR-spektroskopischen und röntgenometrischen Methoden identifiziert. Die radial-strahligen Aggregate des Mesolits kommen in den Phonolitintrusionen vor. In terminalen Teilen gehen sie oft in Skolezit über.

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With 4 Figures     

Geological prognosis of potential zinc and lead resources for Triassic formations in the Silesian-Cracow region in southern Poland

Geological prognosis of zinc and lead potential resources for Triassic formations was carried out for the Olkusz district in the southeast part of Silesian-Cracow region. Known deposits, typical phenomena in surrounding rocks, and quantitative methods for metallic ores for the perspective region or formation were a basis for the models. Statistical analysis of zinc and lead distributions and their interpretation were used to distinguish between the populations of background, anomalies, and ore bodies. Estimated values of the thresholds in the Triassic formations, i.e., 0.5 (anomalies) and 1.1 (ore bodies) wt. % of Zn, and 0.3 and 0.7 wt. % of Pb, respectively, represent the natural limits of concentration for both metals. Similar values of the thresholds obtained by other authors for other districts indicate regional regularities of zinc and lead concentration in the Triassic formations in the whole Silesian-Cracow region. Using these threshold values, the perspective zones of metals concentration can be proposed in the poorly explored areas of this region. In known deposits, the natural limit of zinc used as a cut-off value increase the reserves by about 30–40%.