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地下水污染的"原位修复"是当今国际上净化地下水最具发展前景的新技术,但对铬污染地下水"原位修复"尚未有科学有效的评价方法。定量评价地下水中Cr(Ⅵ)的被还原程度成为保护与修复铬污染地下水的关键问题。通过室内Cr(Ⅵ)的还原实验,分析Cr(Ⅵ)在还原过程中铬稳定同位素变化规律,研究其分馏机理,探索利用铬同位素定量评价地下水中Cr(Ⅵ)还原程度的可行性。研究结果表明:Cr(Ⅵ)在被还原成Cr(Ⅲ)过程中,发生明显的同位素分馏,即反应物中53Cr逐渐富集,同时生成物中52Cr逐渐富集;分馏过程可用瑞利分馏模型描述,分馏系数α为常数0.99842。表明δ53Cr能够定量评价水体中Cr(Ⅵ)的还原程度,为评价地下水铬污染修复提供了新途径。 相似文献
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以坡缕石粘土、淀粉、水玻璃为原料,研究了固定化酶载体的制备工艺,探究了固定化酶载体在辣根过氧化酶(HRP)降解硝基酚废水中的作用,并探讨了反应时间、酶浓度、H2O2及硝基酚浓度对降解效果的影响。结果表明,固定化酶载体的最佳制备工艺为:水玻璃12%,淀粉20%,煅烧温度550℃,煅烧时间2 h;固定化酶对硝基酚的去除效果明显高于原酶;固定化酶去除水中硝基酚的最佳反应条件为:反应时间1.5 h,加酶量150 U,H2O2浓度0.12%,硝基酚浓度100 mg/L;固定化酶重复使用7次后对硝基酚的去除率仍高于60%。 相似文献
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The bacteria and plants were associated to remove diesel oil pollutants from soil.Three efficiently degrading bacteria(named strains Q10,Q14 and Q18,respectively) were isolated.Two plants(alfalfa and Indian mustard) were selected to form the association.Biodegradation of diesel oil pollutants in soil was accelerated by bacteria-plants association.The main results are summarized as follows.The plants-bacteria association was more effective in biodegradation of diesel oil pollutants in soil than in respective experiments carried out with plants or bacteria alone.Strain Q18-Indian mustard association resulted in the maximum diesel oil reduction(69.18%).The activities of catalase and polyphenol oxidase in soil were enhanced and microbial populations in soil,especially in rhizosphere,were also stimulated in the treatment of bacteria-plant association.Overall,the soil conditions might be improved by alfalfa or Indian mustard to benefit the growth of bacteria,which resulted in degradation of diesel oil pollutants more effective by the bacteria-plant association.The bacteria-plants association may be a better approach to the removal of diesel oil pollutants from soil. 相似文献
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Pyrenoids found in green algae Order Ulvales have taxonomical significance.Their morphology,microstructure,and the location and number in the cells have been widely used as identification criteria. As these traits can be affected by environmental conditions,it is necessary to look for other different characteristics.Here pyrenoids in several algae species collected along the Qingdao coast were studied for such purpose. The morphology and distribution of pyrenoids in the cells,as well as their change in diff... 相似文献
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Ji-ning Song Lin Lu Bin Teng Han-il Park Guo-qiang Tang Hao Wu 《Ocean Engineering》2011,38(11-12):1308-1322
Laboratory tests have been conducted on vortex-induced vibration (VIV) of a long flexible riser towed horizontally in a wave basin. The riser model has an external diameter of 16 mm and a total length of 28.0 m giving an aspect ratio of about 1750. Reynolds numbers ranged from about 3000 to 10,000. Fiber optic grating strain gages are adopted to measure the dynamic response in both cross-flow and in-line directions. The cross-flow vibrations were observed to vibrate at modes up to 6 and the in-line reached up to 12. The fundamental response frequencies can be predicted by a Strouhal number of about 0.18. Multi-mode responses and the asymmetry of the bare pipe response in uniform flow were observed and analyzed. The experimental results confirmed that the riser pipe vibrated multi-modally despite it being subject to a uniform current profile and all of the excited modes vibrated at the Strouhal frequency. The asymmetrical distribution of displacement mainly resulted from the modal composition. Higher harmonics of the VIV response such as the third, fourth and fifth harmonics frequencies were found to be steady over the entire duration of the test even if they varied along the length of the riser pipe. 相似文献
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提要:达连河油页岩含矿区位于黑龙江省依兰地区,该区是一个半地堑式断陷盆地。古近系达连河组为一个完整的三级层序,油页岩形成于水进体系域和高水位体系域发育时期。本文认为达连河组油页岩存在两种成矿模式,即湖泊-沼泽相油页岩成矿模式、浅湖相-半深湖相油页岩成矿模式;不同成矿类型油页岩分布于层序的不同体系域,古地貌型、沉积密集段型油页岩成矿常分布于水进体系域,沉积密集段型、气候型油页岩成矿位于高水位体系域。 相似文献