Characterization of organic matter in sediment cores of the Todos os Santos Bay, Bahia, Brazil, by elemental analysis and 13C NMR

The impact of human activity on the sediments of Todos os Santos Bay in Brazil was evaluated by elemental analysis and ¹³C Nuclear Magnetic Resonance (¹³C NMR). This article reports a study of six sediment cores collected at different depths and regions of Todos os Santos Bay. The elemental profiles of cores collected on the eastern side of Frades Island suggest an abrupt change in the sedimentation regime. Autoregressive Integrated Moving Average (ARIMA) analysis corroborates this result. The range of depths of the cores corresponds to about 50 years ago, coinciding with the implantation of major onshore industrial projects in the region. Principal Component Analysis of the ¹³C NMR spectra clearly differentiates sediment samples closer to the Subaé estuary, which have high contents of terrestrial organic matter, from those closer to a local oil refinery. The results presented in this article illustrate several important aspects of environmental impact of human activity on this bay.     

Influence of electron nongyrotropy and anisotropy on parallel wave propagation: Numerical solution of dispersion relation

This work investigates the influence of a nongyrotropic electron beam on the coupling between the electromagnetic modes of parallel propagation in a background gyrotropic plasma. We explore the importance of the relevant parameters in driving instabilities: the ratio of electron plasma frequency to electron cyclotron frequency, the gyrophase angle, and the temperature anisotropy. We confirm previous results that nongyrotropy can lead to mode coupling for specific values of relevant parameters. More important was to observe that when the anisotropy in the system provides sufficient free energy to start instabilities, the electron nongyrotropy plays an important role to change the growth rate.     

Elastoplastic constitutive modelling of soil–structure interfaces under monotonic and cyclic loading

This paper is dedicated to the non-linear numerical modelling of the soil–structure interface. Thus, in a first part, after the presentation of the constitutive model, the soil–structure interface interaction is treated in terms of direct shear test simulations. A strategy for the interface model parameters’ identification is also presented. This strategy is linked to the similitude of soil–structure interface behavior and the soil behavior, regarding the interface surface roughness. In a second part, the performance of the numerical simulations are verified numerically against published results for soil–structure experimental shear tests. Finally, as an application, interface stress paths are studied in axially loaded pile–soil systems and load transfer mechanisms are identified.     

Inter- and intra-estuarine fish assemblage variability patterns along the Portuguese coast

Estuaries along the Portuguese coast differ considerably in terms of their structure, geomorphologic and hydrologic characteristics. They play an important ecological role for different fish species, namely acting as important nursery areas. The fish assemblages of nine estuaries of the Portuguese coast were investigated in order to evaluate their main inter- and intra-estuarine variability patterns. Fish sampling surveys were conducted in May and July 2006, covering the full estuarine gradient. The different saline areas in each estuary were mapped using a Geographic Information System and fish assemblages’ were described and compared using a functional guilds approach. Generalized linear models were used to relate fish species richness to geomorphologic, hydrologic and environmental characteristics of the estuaries considered and correspondence analyses were performed to evaluate similarities in fish assemblages’ structure. At a large scale, river flow was the most important factor explaining the variability in species richness in estuaries along the Portuguese coast. At a regional scale, different abiotic factors explained the occurrence and abundance of fish species in the estuaries. Nonetheless, the overall role of the estuary was strongly related with the dominant saline zone within each estuary.     

The Rio Capim volcanic–plutonic–sedimentary belt,São Francisco Craton,Brazil: Geological,geochemical and isotopic evidence for oceanic arc accretion during Palaeoproterozoic continental collision

The collision of oceanic arcs with continents is a common plate tectonic process in the Phanerozoic, but its recognition in the Precambrian is hampered by deformation and metamorphism. The Rio Capim volcanic–plutonic–sedimentary belt lies in sharp tectonic contact with Archaean rocks of the Uauá block in the northern part of the São Francisco craton. Field relationships and high-precision geochronology indicated that the Rio Capim basalts, gabbros, diorites, and dacites were emplaced approximately at 2148–2143 Ma, and later intruded by 2128 Ma-old diorite to tonalite plutons. All rocks were metamorphosed under amphibolite to granulite facies conditions mainly between 2080 Ma and 2070 Ma, but deformation may have lasted until about 2040 Ma as estimated from syn-deformation zircon and titanite grains. The association of basalt, andesite, dacite, and their plutonic counterparts, combined with their positive ε_Nd(t) values and incompatible trace element geochemical signatures similar to island arc magmas, support the proposition that the Rio Capim belt was a Palaeoproteorozoic intra-oceanic arc sequence that collided with a continent, of which the Mesoarchaean Uauá block is a remnant. The implications for the regional evolution and metallogenesis are also discussed.     

Choosing Between Two Kind of Sampling Patterns Using Geostatistical Simulation: Regularly Spaced or at High Uncertainty Locations?

Data from a mineral deposit are commonly obtained by core drilling. This kind of sampling involves high costs, limiting the number of drill holes. Additional holes should be located to bring the maximum benefit. The benefit can be evaluated by various ways and must take into account the goals of sampling. This article presents a case study where the deposit has been sampled and the new drillings must be added to reduce the uncertainty about a transfer function, Net Present Value (NPV) of the mining project. There are basically two ways to choose locations where new drillings should be placed for cases where the aim of sampling is to reduce uncertainty about a global function: the addition of new drillings outlining a quasi regular grid with previously collected drillings or the addition of new drillings on the locations of high uncertainty about the attribute of interest (or the attribute that is considered most influential in the transfer function). The performances of these patterns on reducing the uncertainty measured by the function selected are compared. The results point out that the most efficient pattern relates to the distribution (histogram) of the uncertainty about the attribute of interest. Thus, the choice of which sampling pattern should be adopted varies depending on data distribution and its influence on the transfer function.     

Distributions of total,inorganic and organic phosphorus in surface and recent sediments of the sub-tropical and semi-pristine Guaratuba Bay estuary,SE Brazil

This study addresses the distribution of total phosphorus (TP) and its inorganic (IP) and organic (OP) fractions, grain-size and organic matter of surface and recent sediments, coupled to the behavior of total and dissolved inorganic phosphorus (TP and DIP) of the water column, of the semi-pristine Guaratuba Bay estuary, SE Brazil. Surface sediment samples were taken at 43 sites spread along the estuarine gradient and recent sediments from 3 short (35 cm long) cores from the upper, central and lower portions of the estuary, respectively. Highest TP and IP concentrations of surface sediments were detected within the upper sector and the transition zone between the upper and central sectors, all characterized by fine sediments, low salinities and water depths. In contrast, the lower sector and its narrow and deep tidal channel, subject to more intense tidal forcing, exhibited a higher fraction of sandy sediments with lower TP, IP and OP contents. In spite of the spatial variability in sediment grain size, IP corresponded to the major fraction of TP in all estuarine sectors and both TP and IP correlated significantly with the fine sedimentary (silt + clay) grain-size fraction. The fine surface sediments acted as a trap for IP at the fresh water–low salinity interface, which also corresponded to the region of a DIP sink in surface waters. In general, the short sediment cores showed that TP and IP contents increased from 15 cm depths to the top layer. Published sedimentation rates from additional cores taken at the sites of the short cores of this study, implied that depositional alterations of TP and IP increased during the early 1970s, which corresponded to the onset of anthropogenic disturbances from crop plantations in the lowland plains of the river end-member and urbanization at the estuary’s mouth and along the adjacent coast.     

Pedo‐Geochemical Signatures of Archeological Sites in the Tapirapé‐Aquiri National Forest in Marabá, Amazonia,Brazil

The present study aims to interpret the occupation of terra firme (nonflooded uplands) archeological sites located at Tapirapé‐Aquiri National Forest in the Brazilian state of Pará, through an integrated analysis of pedological, archeological, and geochemical data. We focus on seven archaeological sites, selected among 22 identified in the region. Radiocarbon and thermoluminescence dating indicate distinct periods of occupation over the past ∼6000 years, and the pedo‐geochemical data identify intra‐ and inter‐site differences in soil. Archaeological, chronometric, and pedo‐geochemical data provide a basis for the functional classification of archeological sites found in the region and help to identify specific human activity areas. The results lead us to infer that many of the archeological sites were the result of multiple occupations that left a persistent pedological signature on the landscape.     

A database for the study of marine mammal behavior: gap analysis, data standardization, and future directions

A relational database that contained published information on the diving behavior and/or movement patterns of marine mammals was compiled to facilitate a modeling effort of the Effects of Sound on the Marine Environment (ESME) program. A total of 448 references from reports, books, and peer-reviewed journal articles were obtained. The metadata describing each animal studied, location of the study, and equipment used were entered into the database as well as empirical data describing the diving behavior and movement patterns of each animal. In total, the database contained 1815 entries from 51 different marine mammal species or subspecies. The majority of animals were seals and sea lions with 1560 entries from 29 individual species. More than half the number of animals studied were from high latitude regions (e.g., Arctic and Antarctic). Other problem areas identified were: 1) Data reduction in summaries, 2) inability to easily summarize qualitative and quantitative data, and 3) lack of standardization in data reporting. A solution is to create a common access data archive where researchers contribute raw published or unpublished geospatially referenced data sets. This would improve access to original data sets with large volumes of data, which, overall, enhances the power to develop robust behavioral or ecological models that could help define critical habitats of marine mammals.