Elemental concentrations and their distribution in two bituminous coals of different paleoenvironments

The vertical distributions of major and minor elements in two high-volatile bituminous coals of Eastern Tennessee are compared. The coals studied are the Pewee, deposited in a fresh-water environment, and the Upper Grassy Spring, previously thought to be influenced by a late incursion of marine water.X-ray fluorescence analyses were performed on a continuous series of specimens obtained from full-face channel samples representing the entire thickness of each seam. Correlation coefficients (r) for all element pairs show high positive correlations for element pairs normally associated with clay minerals. Equally good correlations were observed for (Si, Ti) and (Al, Ti), suggesting that titanium is associated with clay minerals in both coals. Strontium and phosphorous showed a high positive r factor for both the Upper Grassy Spring and the Pewee.Major differences were found to exist in the concentrations and distributions of sulfur, iron, and arsenic in the Upper Grassy Spring and Pewee seams. The Upper Grassy Spring contains an order of magnitude more sulfur than the Pewee as well as several times as much iron and arsenic. The element concentrations and especially their distributions in the Upper Grassy Spring suggest an earlier time for the marine incursion than previously reported. In fact, there is evidence that this coal deposit may have been influenced by marine conditions from its inception.     

The mineralogy,petrology, and composition of anomalous eucrite Emmaville

The Emmaville eucrite is a relatively poorly studied basaltic achondrite with an anomalous oxygen isotope signature. In this study, we report comprehensive mineralogical, petrographic, and geochemical data from Emmaville in order to understand its petrogenesis and relationship with the basaltic eucrites. Emmaville is an unusually fine‐grained, hornfelsic‐textured metabasalt with pervasive impact melt veins and mineral compositions similar to those of typical basaltic eucrites. The major and trace element bulk composition of Emmaville is also typical of a basaltic eucrite. Three separated individual lithologies were also analyzed for O isotopes; a dark gray fraction (E1), a shocked lithology (E2), and a lighter gray portion (E3). Fractions E1 and E2 shared similar O isotope compositions to the bulk sample (E‐B), whereas the lighter gray portion (E3) is slightly elevated in Δ¹⁷O and significantly elevated in δ¹⁸O compared to bulk. No evidence for any exogenous material is observed in the thin sections, coupled with the striking compositional similarity to typical basaltic eucrites, appears to preclude a simple impact‐mixing hypothesis. The O‐isotopes of Emmaville are similar to those of Bunburra Rockhole, A‐881394, and EET 92023, and thus distinct from the majority of the HEDs, despite having similarities in petrology, mineral, and bulk compositions. It would, therefore, seem plausible that all four of these samples are derived from a single HED‐like parent body that is isotopically distinct from that of the HEDs (Vesta) but similar in composition.     

Adapting visual methods: action research with Kampala street children

The paper examines the use of four visual 'action' methods for eliciting information from street children about their interactions with the socio-spatial environment. These methods were adapted and used to encourage child-led activities and minimize researcher input. The advantages and constraints associated with the successful implementation of visual methods with children are examined, followed by a brief examination of the 'real' and ethical considerations surrounding their use. The paper concludes that visual methods allow a high level of child-led participation in research, as well as providing a stimulus for eliciting further oral material.     

Plesiosaur remains from the Jurassic-Cretaceous Purbeck Limestone Group of southern England

Plesiosaur fossils from the uppermost Tithonian (Upper Jurassic) to lower Valanginian (Lower Cretaceous) Purbeck Limestone Group of Dorset, England are important because they constitute a rare record from around the Jurassic-Cretaceous boundary. Where diagnostic, the remains are referred to indeterminate plesiosauroids (Cryptocleidoidea) and represent relatively small animals including a previously undescribed juvenile individual. This observation accords with the lagoonal-lacustrine (with periodic marine influx) depositional setting of the Purbeck Limestone Group strata, a palaeoenvironment that is often associated with juvenile plesiosaur occurrences.     

SOIL DEVELOPMENT AND SPATIAL VARIABILITY ON GEOMORPHIC SURFACES OF DIFFERENT AGE

Twenty-four soil pedons on each of four sandy lake terraces in northwestern lower Michigan that ranged in age from 3000 to 11,000 years BP were studied to assess trends in soil morphological variability with time. After verifying the general uniformity of parent materials within and between the four surfaces, we examined temporal trends in the spatial variability of soil color, cementation, horizon thickness and development. E horizons attained high color values (lightness) by 3000 years and changed little after that time, whereas B horizons continued to get darker with time. Cementation within B horizons increased in strength and amount with time, as did B horizon thickness. Soils ≥4000 years old had deeper eluvial zones but much greater variabilities in the thickness of that zone than did younger soils. Soil development increased with time, but spatial variability in degree of development also increased with time. These patterns are best explained by invoking spatially random soil mixing upon a surface that is otherwise undergoing podzolization. [Key words: podzolization, chronofunction, Michigan, soil variability, soil genesis.]