Advances in our understanding of the gem corundum deposits of the West Pacific continental margins intraplate basaltic fields

Recent discoveries over the last decade of new gemfields, exploitation of new and existing deposits, and application of relatively new techniques have greatly increased our knowledge of the basalt-derived gem sapphire–ruby–zircon deposits. In this paper we focus on the Late Mesozoic to Cenozoic intraplate basaltic fields of the West Pacific continental margins. We review advances made in understanding the genesis of these deposits, based on the application of newer techniques. We also critically review existing data on the gem corundum deposits, in order to further refine a model for their origin.In some of the intraplate basaltic fields, corundum-bearing xenoliths have been found showing a range of PT formation conditions from 790 °C at 0.85 GPa to as much as 1100 to 1200 °C at 1.0 to 2.5 GPa. Although most magmatic sapphires contain syngenetic inclusions of columbite-group phases, zircon, spinel and rutile, some contain additional nepheline and K-feldspar, suggesting crystallization from more undersaturated alkaline magma while the Weldborough field of NE Tasmania also contains molybdenite and beryl, suggesting at least some interaction with more fractionated ‘granitic-type’ magmas. There is a large range in PT conditions calculated for the metamorphic rubies (from 780 to 940 °C, through 800 to 1150 °C up to 1000 to 1300 °C). Fluid/melt inclusion studies on magmatic corundums generally suggest that they formed in a CO₂-rich environment from a ‘syenitic’ melt under a range of T conditions from 720 to 880 °C up to 1000 to 1200 °C. Oxygen isotope studies reveal that typical magmatic corundums have values of + 4.4 to 6.9‰, whereas metamorphic corundums from the same basaltic host have lower values of + 1.3 to 4.2‰.Geochronological studies have shown that some fields produced a simple eruptive and zircon/corundum crystallization event while others had multiple eruptive events but only one or two zircon crystallization events. For a few fields, some corundums/zircons crystallized in storage regions and then remained relatively inert for periods of 200 to 400 Ma without significant change before transport to the surface in the Cenozoic. Tectonic studies of the Australian region suggest that many of the corundums crystallized from magmas related to episodic basaltic volcanism in a tectonic regime of extension, associated with the opening of the Tasman and Coral Seas. For the Asian region, the magmatic–polygenetic corundums within the basaltic fields largely crystallized in a tectonic regime of distributed E–W extension, whereas the metamorphic-metasomatic corundums crystallised in a transpressional regime associated with the collision of the Indian Plate with the Eurasian Plate (e.g., [Garnier, V., Giuliani, G., Maluski, H., Ohnenstetter, D., Deloule, E., 2003. Ar–Ar and U–Pb ages of marble-hosted ruby deposits from Central and South-east Asia. Geophysical Research Abstracts 5, 03751; Garnier, V., Giuliani, G., Ohnenstetter, D., and Schwarz, D., 2004. Les gisements de corindon: classification et genese. Les placers a corindon gemme. Le Regne Mineral 55, 7-47; Garnier, V., Ohnenstetter, D., Giuliani, G., Maluski, H., Deloule, E., Phan Trong, T., Pham Van, L., Hoang Quang, V., 2005a. Age and significance of ruby-bearing marble from the Red River Shear Zone, Northern Vietnam. Canadian Mineralogist 43, 1315–1329]).     

安徽铜陵狮子山矿田岩浆岩锆石SHRIMP定年及其成因意义

铜陵狮子山矿田发育大量岩浆岩,且与矿田中的铜金多金属成矿关系密切。锆石SHRIMP同位素精确定年表明,矿田中的岩浆侵位年龄在132.4～142.9Ma之间,即晚侏罗世—早白垩世,属燕山早期晚阶段。矿田岩浆岩体是在同期岩浆活动中多次侵位形成的,岩浆侵入活动可以划分为分别起始于140Ma前后和约136Ma的早晚两次。从岩浆上升侵位到冷却结晶的时间间隔均较短,但其中白芒山辉石二长闪长岩冷却史相对较长,且经历了早期深部岩浆房中的分离结晶作用和后期构造脉动、岩浆上升侵位、减压受热、早期晶体再熔蚀及冷却结晶的过程。结合主量元素和微量元素地球化学研究认为,狮子山矿田岩浆演化的后期,即起源于上地幔或下地壳的原生岩浆在同化了壳源物质并聚集到岩浆房中以后,在滞留的过程中发生了一定程度的分离结晶作用,但尚未固结,成分上显示了一定的带状分布,在区域构造应力松弛及构造事件诱发下,随机地沿发育的构造裂隙先后上升侵位,冷凝结晶。     

Zircon U–Pb and Hf isotopic study of gneissic rocks from the Chinese Altai: Progressive accretionary history in the early to middle Palaeozoic

Gneissic rocks in the Chinese Altai Mountains have been interpreted as either Paleozoic metasedimentary rocks or Precambrian basement. This study reports geochemical and geochronological data for banded paragneisses and associated gneissic granitoids collected along a NE–SW traverse in the northwestern Chinese Altai. Petrological and geochemical data suggest that the protoliths of the banded gneisses were possibly immature sediments with significant volcanic input and that the gneissic granitoids were derived from I-type granites formed in a subduction environment. Three types of morphological features can be recognized in zircons from the banded gneisses and are interpreted to correlate with different sources. Zircons from five samples of banded paragneiss cluster predominantly between 466 and 528 Ma, some give Neoproterozoic ages, and a few yield discordant Paleoproterozoic to Archean ages. Zircon Hf isotopic compositions indicate that both juvenile/mantle and crust materials were involved in the generation of the source rocks from which these zircons were derived. In contrast, zircons occur ubiquitously as elongated euhedral prismatic crystals in the four samples of the gneissic granitoids, and define single populations for each sample with mean ages between 380 and 453 Ma. The general absence of Precambrian inheritance and positive zircon ?Hf values for these granitoids suggest insignificant crustal contribution to the generation of the precursor magmas. Our data can be interpreted in terms of a progressive accretionary history in early to middle Palaeozoic times, and the Chinese Altai may possibly represent a magmatic arc built on a continental margin dominated by Neoproterozoic rocks.     

Atmospheric mercury near Salmon Falls Creek Reservoir in southern Idaho

Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were measured over 2-week seasonal field campaigns near Salmon Falls Creek Reservoir in south-central Idaho from the summer of 2005 through the fall of 2006 and over the entire summer of 2006 using automated Tekran Hg analyzers. GEM, RGM, and particulate Hg (HgP) were also measured at a secondary site 90 km to the west in southwestern Idaho during the summer of 2006. The study was performed to characterize Hg air concentrations in the southern Idaho area for the first time, estimate Hg dry deposition rates, and investigate the source of observed elevated concentrations. High seasonal variability was observed with the highest GEM (1.91 ± 0.9 ng m⁻³) and RGM (8.1 ± 5.6 pg m⁻³) concentrations occurring in the summer and lower values in the winter (1.32 ± 0.3 ng m⁻³, 3.2 ± 2.9 pg m⁻³ for GEM, RGM, respectively). The summer-average HgP concentrations were generally below detection limit (0.6 ± 1 pg m⁻³). Seasonally averaged deposition velocities calculated using a resistance model were 0.034 ± 0.032, 0.043 ± 0.040, 0.00084 ± 0.0017 and 0.00036 ± 0.0011 cm s⁻¹ for GEM (spring, summer, fall and winter, respectively) and 0.50 ± 0.39, 0.40 ± 0.31, 0.51 ± 0.43 and 0.76 ± 0.57 cm s⁻¹ for RGM. The total annual RGM + GEM dry deposition estimate was calculated to be 11.9 ± 3.3 μg m⁻², or about 2/3 of the total (wet + dry) deposition estimate for the area. Periodic elevated short-term GEM (2.2–12 ng m⁻³) and RGM (50–150 pg m⁻³) events were observed primarily during the warm seasons. Back-trajectory modeling and PSCF analysis indicate predominant source directions to the SE (western Utah, northeastern Nevada) and SW (north-central Nevada) with fewer inputs from the NW (southeastern Oregon and southwestern Idaho).     

概率图解法软件研制及其在东升庙矿床研究中的应用

文章根据概率图解法原理,利用VB可视化编程技术,完成了概率图筛分软件的研制.并通过该软件对东升庙矿床矿石品位混合总体进行筛分处理,探究其成矿期次信息.已有研究结果表明:一次成矿作用形成的矿床,其矿石品位的累积概率图是一条直线.而东升庙矿床的8条代表性勘探线中4种主要成矿元素TS、An、Pb、Cu品位的累积概率图均为曲线且出现明显拐点,经多次作图检验证实有效拐点数为1,由此得到新的成矿期次信息,揭示该矿床经历了两期成矿作用,即中元古代同沉积-海底喷气矿化期和后生改造矿化期,这对于研究其成矿物质来源和成矿机理具有重要的意义.     

松辽盆地尚家—太平川地区石油地质条件及勘探方向分析

通过对尚家—太平川地区构造演化、烃源岩特征、沉积特征、储盖组合、油水关系及油藏类型和油气成藏特征的分析,研究了本区的石油地质条件,认为烃源岩具有较好的生、排烃能力,分流河道砂体为油气聚集提供较好的沉积环境,良好的储盖组合有利于油气的聚集与保存。研究区没有统一油水界面,尚家地区以岩性—构造油藏为主,太平川地区以构造—岩性油藏为主。区内扶余—杨大城子油层油气成藏受有效性圈闭、优势运移通道、过剩压力、储集条件和构造诱导作用控制。据上述认识确定了研究区下一步的勘探方向,并已在指导勘探实践中取得了较好的效果。     

新疆北部库尔提蛇绿岩中角闪片岩的原岩恢复及其成因

库尔提角闪片岩产于库尔提蛇绿岩南部岩片中,与斜长花岗岩呈互层产出。这套角闪片岩的不相容微量元素组分显示了大洋中脊和岛弧玄武岩的双重特征,主要表现为大离子亲石元素(LILE)富集,高场强元素(HFSE)亏损以及平坦到亏损的轻稀土(LREE)配分模式。原岩恢复的结果表明,该角闪片岩的原岩为亚碱性的拉斑玄武岩类。库尔提角闪片岩亏损的LREE、高ε_(Nd)(t),以及关键元素比值(Th/Nb,La/Yb和Th/Yb)呈正相关都表明,其源区可能以MORB地幔为主,同时还伴有少量弧组分。因此,我们认为其形成于弧后盆地环境,同时推断该区弧后盆地存在一个二阶段的熔融演化模式:第一阶段,大约在晚古生代早期,古亚洲洋向西伯利亚板块发生北向俯冲,在会聚板块边界,弧火山岩被从含水的地幔楔中提取出来,留下一个亏损地幔;第二阶段,随着古亚洲洋板块持续消减,在中-晚泥盆世形成了库尔提弧后盆地,下部的亏损地幔发生了小比例的部分熔融形成了这套角闪片岩的原岩。     

中祁连东段什川杂岩基的岩石化学特征及年代学研究

祁连造山带被托菜南山-了高山构造带及宗务隆山-贵得构造带分为北祁连、中祁连及南祁连构造带。什川岩基位于中祁连构造带东部,由闪长岩、斜长花岗岩、二长花岗岩组成;对二长花岗岩进行U-Pb单颗粒锆石微区LA-ICP-MS同位素测定,获得444.6Ma及414.3Ma两组加权平均年龄,前者代表岩石的形成年龄,后者代表构造热事件年龄。二长花岗岩主量元素W(SiO_2)=68.66%～80.77%,w(K_2O)/w(Na_2O)>1和A/CNK介于0.95～1.21间,总体为钾质钙碱性过铝质花岗岩。岩石富集LILE元素(K、Th、Rb、Ba等),亏损HFSE元素(Ta、Nb、Y等);稀土元素总量较高(∑REE多介于109.05×10~(-6)～322.66×10~(-6)),轻重稀土强烈分馏(∑LREE/∑HREE介于7.92～31.68),稀土元素分配模式为轻稀土富集型,具中等-强Eu负异常(δEu=0.26～0.58)。岩石矿物组合及岩石地球化学特征共同表明,什川岩基为中上地壳泥砂质岩石部分熔融而成,形成温度较低,为加厚地壳拆沉熔融成因。这为祁连造山带构造演化及其深部动力学机制研究提供了新的资料。     

巴拉贡矿区低品位坡缕石粘土的成胶性能探讨

以改良库布齐沙漠为目的,结合坡缕石粘土特有的成胶性、吸附性和保水性能,用巴拉贡矿区的低品位坡缕石粘土进行了粘土成胶性能的研究.结果表明,在加入聚合物PAAS含量相同的条件下(与水的体积比为0.05mL/100 mL),球磨成胶和胶磨成胶的效果较好,两者的最佳土水比值相近,约20～21 g/100 mL,略高于棒磨成胶的18 g/100 mL,远高于均质成胶的6 g/100 mL.本研究为改良沙漠化土壤提供了新思路,同时为坡缕石矿物找到了新的应用领域,拓宽了低品位坡缕石粘土的市场.     

浙江省长兴县煤山剖面二叠—三叠系过渡地层中的黑碳记录及其地质意义

首次报道了浙江煤山二叠-三叠系界线地层中黑碳的含量及其碳同住素的变化特征。黑碳含量在26层存在一个明显的峰值,含量高达0．51％。黑碳与总有机碳比值从25层底部开始持续升高,在26层达到最高,稳定在0．40以上。黑碳的碳同位素在24层和25层之间有一个陡然的降低,降低幅度达2‰,在25和26层中则存在一个幅度达3‰的缓慢降低,总降低幅度达5‰。黑碳是动植物和化石燃料燃烧的天然记录,浙江煤山二叠-三叠系界线附近黑碳特征反映了二叠纪末期陆地生态系统发生了突然的衰退,发生了强烈的天然大火。根据事件层大火燃烧的长期性或频繁的特征,以及黑碳同位素大幅度陡然降低和缓慢降低,认为燃烧源除了陆地植被外,还有其他富含轻碳的化石燃料,即大火的燃烧源除了植被外,还可能有煤和甲烷水合物等。浙江煤山剖面的黑碳记录,反映了二叠-三叠纪之交地球陆地环境的剧烈变化,有助于理解和揭示生物大灭绝的过程和原因。