Compression studies of gibbsite and its high-pressure polymorph

Various X-ray diffraction methods have been applied to study the compression behavior of gibbsite, Al(OH)₃, in diamond cells at room temperature. A phase transformation was found to take place above 3 GPa where gibbsite started to convert to its high-pressure polymorph. The high-pressure (HP) phase is quenchable and coexists with gibbsite at the ambient conditions after being unloaded. This HP phase was identified as nordstrandite based on the diffraction patterns obtained at room pressure by angle dispersive and energy dispersive methods. On the basis of this structural interpretation, the bulk modulus of the two polymorphs, i.e., gibbsite and nordstrandite, could be determined as 85 ± 5 and 70 ± 5 GPa, respectively, by fitting a Birch-Murnaghan equation to the compression data, assuming their K_o ^′ as 4. Molar volume cross-over occurs at 2 GPa, above which the molar volume of nordstrandite is smaller than that of gibbsite. The differences in the molar volume and structure between the two polymorphs are not significant, which accounts for the irreversibility of the phase transition. In gibbsite, the axial compressibility behaves as c/c _o > a/a _o > b/b _o. This is due to the fact that the dioctahedral sheets along the c-axis are held by the relatively weak hydrogen bonding, which results in the greater compressibility along this direction. In nord- strandite, the axial compressibility is b/b _o > c/c _o > a/a _o, which can also be interpreted as resulting from the the existence of hydrogen bonds along the b-axis. Received: 28 September 1998 / Revised, accepted: 22 December 1998     

Anthropogenic transformations of the Arctic ecosystem of Lake Imandra: Tendencies for recovery after long period of pollution

Transformation of an Arctic aquatic ecosystem (a case study of Lake Imandra) under the impact of a mining industrial complex is considered. Water chemical composition and the ecosystem’s structural components (phyto- and zooplankton, zoobenthos, and ichthiofauna) are analyzed for the following periods: the preindustrial background (reference) conditions, industrial development of mineral resources and strong anthropogenic impact, industrial recession and decreased anthropogenic impact, and stabilization. The main regularities of the aquatic ecosystem successions under the conditions of anthropogenic loads and their decrease are established.     

The application of lead isotope ratios in the Antarctic macroalga Iridaea cordata as a contaminant monitoring tool

Lead (Pb) isotope ratios were measured in the marine macroalga Iridaea cordata collected from four locations in the Windmill Islands, East Antarctica. Based on the masses of thalli collected, samples analysed in this study were likely to be a mixture of one and two year old thalli. For a sample of thalli of various ages (<12 months to 2 years old) from the same site there was no apparent variation in Pb concentration or Pb isotope ratio with thallus mass/age, indicating that contaminant sources had been constant over the lifetime of the thalli sampled. I.cordata samples close to the Thala Valley waste disposal site (Brown Bay Inner) near the Australian Station, Casey, displayed isotopic signatures (²⁰⁸Pb/²⁰⁴Pb 35.99; ²⁰⁶Pb/²⁰⁷Pb 1.066; n = 3; average values shown) trending towards that possessed by major Australian Pb sources (Broken Hill and Mt Isa, ²⁰⁸Pb/²⁰⁴Pb 35.60; ²⁰⁶Pb/²⁰⁷Pb 1.041) suggesting that these samples had been exposed to anthropogenic Pb originating from the Thala Valley waste disposal site. Material collected hundreds of metres from the tip location at Brown Bay Outer had isotopic values (²⁰⁸Pb/²⁰⁴Pb 36.32; ²⁰⁶Pb/²⁰⁷Pb 1.088; n = 10) intermediate between Brown Bay Inner and sites further from the contaminant source at Sparkes Bay and Wilkes (²⁰⁸Pb/²⁰⁴Pb 36.46; ²⁰⁶Pb/²⁰⁷Pb 1.094; n = 4) showing that contaminant transport was predominantly restricted to Brown Bay Inner. This study demonstrates that the isotope ratios of Pb in marine macroalgae can provide valuable information as to the origin and extent of heavy metal flux in a marine environment.     

Utilization of data bank on grid square basis for regional planning

This paper deals with results of case studies using actual magnetic tape records of Statistics on Grid Square Basis and Digital National Land Information which have been compiled since 1965 by governmental agencies on the same grid square basis from census and map reading covering the whole country. The number of items on the records has been increasing, including land information and socio-economic statistics which seem to be useful for land development/conservation planning and regional planning. However, in reality a majority of local governments have not used to date these records enough. In this study the combination analysis of two or more items is made in order to make more effective use of the records for these plannings. The number of grid squares under fixed conditions are calculated and the distribution maps are drawn by means of line printer or X-Y plotter. The themes are as follows: 1. Population distribution and population growth and land use type by landform classification, 2. Proportion of built-up area in city planning area, 3. Selection of possible space for housing development, 4. Division of a given area based on natural conditions for daily life into three areas, namely suitable areas, possible but rather difficult areas, and unsuitable areas. 5. Selection of suitable areas for sightseeing and recreation. The items used for combination analysis are 1970 and 1975 Population Census, ground elevation, angle of inclination, value of relief, landform classification, surface geology classification, soil classification, land use classification, and city planning area. The data of land value and distance from nearest station are produced by map reading for the test area in this study. From these combinations an objective and detailed distribution can be determined. Finally, several examples of the studies are shown.     

Distribution of Mantle Up-welling Determined from Plate Motions: A Case for Large-scale Bénard Convection

—?The number and geometric distribution of putative mantle up-welling centers and the associated convection cell boundaries are determined from the lithospheric plate motions as given by the 14 Euler poles of the observational NUVEL model. For an assumed distribution of up-welling centers (called “cell-cores”) the corresponding cell boundaries are constructed by a Voronoi division of the spherical surface; the resulting polygons are called “Bénard cells.” By assuming the flow-kinematics within a cell, the viscous coupling between the flow and the plates is estimated, and the Euler poles for the plates are computed under the assumption of zero-net-torque. The positions of the cell-cores are optimized for the HS2-NUVEL1 Euler poles by a method of successive approximation (“subplex”); convergence to one of many local minima occurred typically after ～20,000 iterations. Cell-cores associated with the fourteen HS2-NUVEL1 Euler poles converge to a relatively small number of locations (8 to 10, depending on interpretation), irrespective of the number of convection cells submitted for optimized distribution (from 6 to 50). These locations are correlated with low seismic propagation velocities in tomography, uniformly occur within hotspot provinces, and may specifically be associated with the Hawaiian, Iceland, Reunion/Kerguelen (Indian Ocean), Easter Island, Melanesia/Society Islands (South Pacific), Azores/Cape Verde/Canary Islands, Tristan da Cunha (South Atlantic), Balleny Islands, and possibly Yellowstone hotspots. It is shown that arbitrary Euler poles cannot occur in association with mantle Bénard convection, irrespective of the number and the distribution of convection cells. Nevertheless, eight of the observational Euler poles – including the five that are accurately determined in HS2-NUVEL1 (Australia, Cocos, Juan de Fuca, Pacific, and Philippine) – are “Bénard-valid” (i.e., can be explained by our Bénard model). Five of the remaining six observational poles must be relocated within their error-ellipses to become Bénard-valid; the Eurasia pole alone appears to be in error by ～115°, and may actually lie near 40°N, 154°E. The collective results strongly suggest Bénard-like mantle convection cells, and that basal shear tractions are the primary factor in determining the directions of the plate motions as given by the Euler poles. The magnitudes of the computed Euler vectors show, however, that basal shear cannot be the exclusive driving force of plate tectonics, and suggest force contributions (of comparable magnitude for perhaps half of the plates) from the lithosphere itself, specifically subducting slab-pull and (continental) collision drag, which are provisionally evaluated. The relationship of the putative mantle Bénard polygons to dynamic chaos and turbulent flow is discussed.     

Instability of gradient dependent elasto-viscoplasticity for clay

A gradient-dependent viscoplastic constitutive model for water saturated clay is proposed to describe the strain localization phenomena and pattern formation during deformation. Second- and fourth-order gradients of volumetric viscoplastic strain are introduced into the constitutive equations to account for the non-local effects due to the motion of microstructures. A linear perturbation analysis is applied to this model. The instability of the government equations (i.e. the constitutive equations and the equations of motion for the clay skeleton and pore water) is discussed for both the one-dimensional and the two-dimensional situations. In addition, issues concerned with the formulation of boundary value problems by finite element analysis in relation to the formulation and the boundary conditions are presented. Copyright © 1999 John Wiley & Sons, Ltd.     

Performance analysis of the spaceborne laser ranging system

The Spaceborne Laser Ranging System is a proposed short pulse laser on board an orbiting spacecraft.^1,2,3,4 It measures the distance between the spacecraft and many laser retroreflectors (targets) deployed on the Earth’s surface. The precision of these range measurements is assumed to be about ±2 cm (M. W. Fitzmaurice, private communication). These measurements are then used together with the orbital dynamics of the spacecraft, to derive the relative position of the laser ground targets. Assuming a six day observing period with 50% cloud cover, uncertainties in the baseline for target separations of 50 km to 1200 km were estimated to be on the order of 1 to 3 cm and the corresponding values in the vertical direction, ranged from 1 cm to 12 cm. By redetermining the measurements of the relative target positions, the estimated precision in the baseline for a target separation of 50 km is less than 0.3 cm and for a separation of 1200 km is less than 1 cm. In the vertical direction, the estimated precision ranged from 0.4 cm to 4.0 cm respectively. As a result of the repeated estimation of the relative laser target positions, most of the non-temporal effects of error sources as exemplified by the errors in geopotential are reduced. The Spaceborne Laser Ranging System’s capability of determining baselines to a high degree of precision provides a measure of strain and strain rate as shown byCohen, 1979. These quantities are essential for crustal dynamic studies which include determination and monitoring of strain near seismic zones, land subsidence, and edifice building preceding volcanic eruptions. It is evident that such a system can also be used for geodetic surveys where such precisions are more than adquate.     

A soil chronosequence in Late Glacial and Neoglacial moraines, Humboldt Glacier, northwestern Venezuelan Andes

Late Glacial and Neoglacial (Little Ice Age) deposits on the Humboldt Massif were analyzed for relative-age dating parameters, including geomorphic and weathering characteristics, geochemical and soil properties. The soil chronosequence, formed in chemically uniform parent materials, provides an important database to study soil evolution in a tropical alpine environment. Extractable and total Fe and Al concentrations, examined to assess their use in relative-age determination, and as paleoenvironmental indicators, provide an important measure of the accumulation and downward profile movement over time of organically-bound Al, ferrihydrite and other crystalline forms (hematite and goethite) of extractable Fe. Ferrihydrite is particularly useful in determining former perched water levels in soils with relation to paleoclimate. The ratios of most Fe extracts are time dependent. The Fe_d/Fe_t ratio, within statistical limits, shows a slow increase from LIA (Little Ice Age) to Late Glacial soils, which closely correlates with other alpine soil studies in the middle latitudes and other tropical alpine locales. Values of Al_d (dithionite) and Al_o (oxalate extractable) generally do not correlate with time; however, Al_p (pyrophosphate extractable) measured against Al_t (total) provides insight on the downward translocation over time of organically-bound Al. Low leaching rates in this chronosequence are further supported by clay mineralogy trends and the geochemical data.