RAGLAND,AN LL3.4 CHONDRITE FIND FROM NEW MEXICO

The Ragland, New Mexico chondrite was found in 1978, and consists of a single stone of 12.16 kg that broke into three pieces. The stone is moderately weathered and has a pronounced chondritic texture. Bulk composition favors an LL classification, and modal analysis and oxygen isotopic composition are consistent with this. The thermoluminescence sensitivity of 0.056 ± 0.020 normalized to Dhajala, compositional variability of olivine (mean Fa 18.3, σ = 10.1) and low-Ca pyroxene (mean Fs 14.6, σ = 6.7), and Ca concentrations in olivine indicate metamorphic subtype 3.4 ± 0.1. The isotopically heavy oxygen composition, which is characteristic of subtypes 3.0–3.1, may be a primary characteristic and not a result of weathering. Low concentrations of radiogenic ⁴⁰Ar and planetary ³⁶Ar suggest noble gas loss.     

Paleomagnetism of the triassic nicola volcanics and geotectonics of the quesnellia subterrane of terrane I, British Columbia

Paleomagnetic data from 46 sites (674 specimens) of the Westcoast Crystalline Gneiss Complex on the west coast of Vancouver Island using AF and thermal demagnetization methods yields a high blocking temperature WCB component (> 560°C) with a pole at 335°W, 66°N (δ_p = 4°, δ_m = 6°) and a lower coercivity WCA component ( 25 mT, < 500°C) with a pole at 52°W, 79°N (δ_p = 7°, δ_m = 8°). Further thermal demagnetization data from 24 sites in the Jurassic Island Intrusions also defines two high blocking temperature components. The IIA component pole is at 59°W, 79°N (δ_p = 7°, δ_m = 8°) and IIB pole at 130°W, 73°N (δ_p = 12°, δ_m = 13°). Combined with previous data from the Karmutsen Basalts and mid-Tertiary units on Vancouver Island and from the adjacent Coast Plutonic Complex, the geotectonic motions are examined for the Vancouver Island segment of the Wrangellian Subterrane of composite Terrane II of the Cordillera. The simplest hypothesis invokes relatively uniform translation for Terrane II from Upper Triassic to Eocene time producing 39° ± 6° of northward motion relative to the North American craton, combined with 40° of clockwise rotation during the Lower Tertiary.     

Morphological response of tidal marshes,flats and channels of the Outer Yangtze River mouth to a major storm

Systematic morphological changes of the coastline of the outer Yangtze River mouth in response to storms versus calm weather were documented by daily surveys of tidal marshes and flats between April 1999 and May 2001 and by boat surveys offshore during this and earlier periods. The largest single event during 1999 to 2001 was Typhoon Paibaian, which eroded the unvegetated tidal flat and lower marsh and led to accretion on the middle-to-upper marsh and in the subtidal channel. The greatest erosion of 21 cm occurred at the border between the marsh and the unvegetated flat due to the landward retreat of the marsh edge during the storm. Strong waves on the flats increased suspended sediment concentration by 10–20 times. On the upper marsh, where the frequency of submergence by astronomical tides is only 3%, Typhoon Paibian led to 4 cm of accretion, accounting for 57% of the net accretion observed over the 2-yr study. Typhoon Paibian led to 4 cm of accretion, accounting for 57% of the net accretion observed over the 2-yr study. Typhoon Paibian and other large storms in the 1990s caused over 50 cm of accretion along the deep axis of the river mouth outlet channel. During calm weather, when hydrodynamic energy was dominated by tides, deposition was centered on the unvegetated flats and lower, marsh with little deposition on the high marsh and erosion in the subtidal channel. Depositional recovery of the tidal flat from typhoon-induced erosion took only several days, whereas recovery of the subtidal channel by erosion took several weeks. A conceptual model for the morphological responses of tidal marshes, flats, and subtidal channels to storms and calm weather is proposed such that sediment continually moves from regions of highest near-bed energy towards areas of lower energy.     

On the relevance of iron adsorption to container materials in small-volume experiments on iron marine chemistry: Fe-aided assessment of capacity, affinity and kinetics

Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron ⁵⁵Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10^− 9 mol/m² or 1.7 × 10^− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log K_Fe'W = 11.0 ± 0.3 m²/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 ⁻⁴–10^− 5 L/s and rate constants for association in the order of 10⁸ L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry.