Magnetic properties of the Lower Old Red Sandstone lavas in the Midland Valley,Scotland; palaeomagnetic and tectonic considerations

Thermal demagnetization studies of lavas in the Strathmore area of the Midland Valley, Scotland, support overall palaeomagnetic data found in previous studies of these rocks. Reduced directional scatter as compared to some earlier studies, is attributed to more effective demagnetization, resolving some of the directional complexity of previous studies. Combined magnetic fabric and directional analysis suggest that at least some deviating directions may be explained by local tectonism. The existence of almost antiparallel directional groups and field tests give supporting evidence for a “primary” (deuteric) origin of the main magnetization of these rocks. Additionally, a second remanence component having shallow reverse directions of magnetization, is attributed to later remagnetization in Old Red Sandstone time. The Midland Valley results are seen in conjunction with other Palaeozoic palaeomagnetic results and possible geodynamic implications are discussed.     

Biosorption of Rare-Earth Elements and Yttrium by Heterotrophic Bacteria in an Aqueous Environment

This paper reports the results of the experimental determination of the coefficient of sorption of rare-earth elements and yttrium (REY) under conditions of acidic pH using several strains of heterotrophic bacteria (Microbacterium sp., Curtobacterium sp., Bacillus subtilis, Pseudomonas putida, and Bacillus pumilis) that are widespread in natural and technogenic waters of the Far East (Russia). Insignificant fractionation between heavy and light rare-earth elements, negative cerium and dysprosium anomalies, and a positive europium anomaly were revealed. The selectivity of REY biosorption by gram-positive and gram-negative bacteria, as well as inertia of the biosorption process under more acidic conditions of the medium, were shown.     

PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia)

The results of the first study of the PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia) are presented here. The complex character of evolution of the PGE composition in the Deformed lherzolites is assumed to be the result of silicate metasomatism. At the first stage, growth in the amount of clinopyroxene and garnet in the rock is accompanied by a decrease in the concentration of the compatible PGE (Os, Ir). During the final stage, the rock is enriched with incompatible PGE (Pt, Pd) and Re possible due to precipitation of submicron-sized particles of sulfides in the interstitial space of these mantle rocks.     

Is there a fuelwood crisis in rural Mali?

The study takes a conventional supply and demand approach to the study of fuelwood use. It compares estimated wood production in West African bush and forest formations based on an available equation using rainfall data with own collected data on local wood consumption in a village in southern Mali. To allow comparison, data from 49 other villages in the same area are analysed. This study, toget her with an earlier study in northern Mali, indicates that locally induced deforestation caused by fuelwood use does not represent an immediate problem in rural Mali. Local use of fuelwood does not seem to be exceeding forest regeneration. However, where there is external pressure on the forest represented by commercial exploitation of wood for sale in the urban centres, fuelwood depletion might occur.     

Ferromanganese crusts from submarine volcanoes of backarc basins as a new genetic type of gallium deposits

Study of the material composition of Fe-Mn crusts from submarine rises in the central part of the Sea of Japan, with modern precision methods applied, has yielded a high (up to 854 g/t) concentration of gallium contained in sorbed form. The new data obtained have allowed a new genetic type of gallium deposits—hydrothermal-sedimentary—to be distinguished.     

A study of bernalite,Fe(OH)3, using Mössbauer spectroscopy,optical spectroscopy and transmission electron microscopy

To study the crystal chemistry of bernalite, Fe(OH)₃, and the nature of the octahedral Fe³⁺ environment, Mössbauer spectra were recorded from 80 to 350 K, optical spectra were recorded at room temperature and a sample was studied using transmission electron microscopy. The Mössbauer spectrum of bernalite consists of a single six-line magnetic spectrum at 80 K. A broadened six-line magnetic spectrum with significantly less intensity is observed at higher temperatures, and is attributed to a small fraction of bernalite occurring as small particles. The variation of hyperfine magnetic field data for bulk bernalite with temperature is well described by the Weiss molecular field model with parameters of H ₀ = 55.7±0.3 T and T _N = 427±5K. The centre shift data were fitted to the Debye model with parameters ₀=0.482±0.005 mm/s (relative to -Fe) and _M=492±30 K. The quadrupole shift is near zero at 300 K, and does not vary significantly with temperature. Absorption spectra in the visible and near infrared range show three crystal field bands of Fe³⁺ at 11 300, 16000 and 23 200 cm^-1, giving a crystal field splitting of 14 570 cm^-1 and Racah parameters of B=629 cm^-1 and C=3381 cm^-1. Infrared reflection spectra show two distinct OH-stretching frequencies, which could correspond to two structurally different types of OH groups. A band was also observed at 2250 cm^-1, suggesting the presence of molecular CO₂ in the large cation site. Analytical transmission electron microscopy indicates that Si occurs within the bernalite structure as well as along domain boundaries. Electron diffraction and imaging show that bernalite is polysynthetically twinned along {100} planes with twin domains ranging from 3 to 20 nm in thickness. Results are discussed with respect to the nature of the octahedral Fe³⁺ site, and compared with values for other iron oxides and hydroxides.     

The Role of the Magnetic Field in the Ascension of the 22nd and 23rd Cycles of Activity

The first small active regions of the last two new cycles seem to be formed, in its very first, preparatory stage, close to the equator with uncertain magnetic orientation, and as secondary products at the periphery of equatorial `magnetic bubbles' of the new magnetic flux still belonging to the old cycle. At the real beginning of the new cycle, at the periphery of its higher-latitude `magnetic bubbles', the opposite applies to the secondary regions of the ending cycle. It seems that two modes of magnetic flux supply the visible layers of the photosphere during the cycle transition phase: the emergence of the magnetic flux from the depth of the convective zone, and the mutual interaction of the earlier emerging fluxes, or the action of the `local dynamo', giving rise to the new local magnetic field concentrations.     

Carbon-Oxidizing and Sulfate-Reducing Bacteria in Mozhaisk Reservoir Soils

The population and distribution of carbon-oxidizing and sulfate-reducing bacteria in the soils of the Mozhaisk Reservoir are studied.