Constraints on the timing and conditions of high‐grade metamorphism,charnockite formation and fluid–rock interaction in the Trivandrum Block,southern India

Incipient charnockites have been widely used as evidence for the infiltration of CO₂‐rich fluids driving dehydration of the lower crust. Rocks exposed at Kakkod quarry in the Trivandrum Block of southern India allow for a thorough investigation of the metamorphic evolution by preserving not only orthopyroxene‐bearing charnockite patches in a host garnet–biotite felsic gneiss, but also layers of garnet–sillimanite metapelite gneiss. Thermodynamic phase equilibria modelling of all three bulk compositions indicates consistent peak‐metamorphic conditions of 830–925 °C and 6–9 kbar with retrograde evolution involving suprasolidus decompression at high temperature. These models suggest that orthopyroxene was most likely stabilized close to the metamorphic peak as a result of small compositional heterogeneities in the host garnet–biotite gneiss. There is insufficient evidence to determine whether the heterogeneities were inherited from the protolith or introduced during syn‐metamorphic fluid flow. U–Pb geochronology of monazite and zircon from all three rock types constrains the peak of metamorphism and orthopyroxene growth to have occurred between the onset of high‐grade metamorphism at c. 590 Ma and the onset of melt crystallization at c. 540 Ma. The majority of metamorphic zircon growth occurred during protracted melt crystallization between c. 540 and 510 Ma. Melt crystallization was followed by the influx of aqueous, alkali‐rich fluids likely derived from melts crystallizing at depth. This late fluid flow led to retrogression of orthopyroxene, the observed outcrop pattern and to the textural and isotopic modification of monazite grains at c. 525–490 Ma.     

Assessment of dissolved nutrients dispersal derived from offshore fish-farm using nitrogen stable isotope ratios (δ15N) in macroalgal bioassays

In this study, the dispersal of wastes from offshore fish farms was evaluated by analyzing nitrogen stable isotope ratios (δ¹⁵N) in macroalgae incubated in the water column at sites located at an increasing distance from the fish cages. Bioassays were performed at three fish farms situated in separate localities with different nutritional conditions (Canary Islands, Murcia and Catalonia) and varying in size, species of fish reared and annual production. Macroalgal bioassays were carried out in two different directions (DI and DII) and they were replicated at each distance in order to evaluate the effect of small-scale variability on the spatial extent of fish farm wastes. The results obtained with δ¹⁵N contribute to a better understanding of the application of nitrogen stable isotopes ratios in macroalgae as an effective bioindicator for tracing the dispersion of offshore fish farm wastes, and demonstrate that fish farm wastes can be traced even over distances of some km from the pollution source. In the Canary Islands, the maximum distance obtained for detection of fish farm wastes was between 450 and 700 m. Of the three installations studied, Murcia presented the greatest distance for detection of fish farm waste influence, ranging from between 1550 and 2450 m, whilst in Catalonia this distance was less than 120 m. In Catalonia, the results were masked by the influence of other sources of nitrogen, and thus fish farm wastes were detected at more reduced distances than expected. These results confirm that fish farm wastes can be traced using the nitrogen stable isotope ratios of macroalgae and that this method can also be useful for identifying areas of potential risk to some sensitive ecosystems, and as an early signal that changes in the community structure might occur.     

Using hydrogeochemical signatures of stream water to assess pathways for rainfall events: towards a predictive model

Thanks to its simple division into agricultural and forestry land use, the Corbeira catchment (Galicia, Spain) is used as a case study to build a predictive model using hydrogeochemical signatures. Stream data acquired under recessional flow conditions over a one year period were obtained from a sampling station near the downstream end of the catchment, and using principal component analysis, it is shown that some of the analytical parameters are covariant, and some are negatively correlated. These findings support inferences about the pathways of rainfall in the catchment. Specific signatures may be associated with the dominant hydrological source, either surface runoff or subsurface waters: additionally, the dominant land use in that part of the catchment, where the flow originated, can also be predicted. The dominant runoff shows a strong covariance between suspended solids (SS) and particulate phosphorus (PP), with a clear negative correlation with pH. Dissolved organic carbon (DOC) data are associated with this covariant set when these compounds are available in the soils in question. Dissolved phosphorus, total organic nitrogen and dissolved nitrates are also associated with the same covariant set when the runoff flows through areas of extensive agricultural use. The SS ? PP covariance is less significant at lower flows. Typical base flow regimes show a significant covariance between salinity and pH, with a marked negative correlation with SS ? PP set, confirming the dominance of subsurface waters in the baseflow, as expected. Seasonally divergent DOC ? SS behaviour proves to be a useful tracer for rainfall regimes. The DOC trend shows a sinusoidal annual variation in amplitude, determined by the rainfall regime. As a result, flow from the catchment is dominated by surface water whenever there is synchronicity between the peaks of DOC and SS. Copyright © 2013 John Wiley & Sons, Ltd.