Atmospheric lead fallout over the last century recorded in Gulf of Lions sediments (Mediterranean Sea)

Six marine sediment cores from the Gulf of Lions continental slope (700-1700 m water depth) were analyzed for stable lead isotopes and (210)Pb geochronology in order to reconstruct lead atmospheric fallout pattern during the last century. The detrital lead contribution is 25 microg g(-1) and the mean sediment anthropogenic inventory is 110+/-7 microg cm(-2), a little bit higher than atmospheric deposition estimate. Anthropogenic lead accumulation in sediments peaked in early 1970s (1973+/-2) in agreement with lead emissions features. For the period 1986-1997, the sediment signal also reflect the decrease of atmospheric lead described by independent atmospheric fallout investigations. The anthropogenic Pb deposition in the late 1990s was similar to the 1950s deposition, attesting thus of the output of European environmental policies.     

地震电磁发射前兆的特性

分析了日本60多个有关地震前兆的电磁发射数据的事件。分析指出,主震震级(M)越大,可观测到信号的地点距震中的距离(D_(max))越大。M—D_(max)间的关系与其他地球物理前兆相一致。没有观测到前兆时间和震级M的关系,这种情况与前震前兆是非常相同的。电磁发射前兆的平均前兆时间为0.26天,因此前兆基本上是短期的。     

Application of trichloroacetic acid (TCA) to extraction of soft body for the determination of tissue Cd, Cu, Pb and Zn in the prosobranch Hydrobia ulvae (Pennant)

The application of trichloroacetic acid (TCA) as a shell extractant for preparation of soft body parts with reference to tissue metal concentrations (Cd, Cu, Pb, Zn) in shellfish has been evaluated on the example of the mud snail Hydrobia ulvae, a small marine prosobranch densely present in rocky and soft-bottom habitats of the eastern Atlantic. A solution of 0.1 M TCA was tested on individuals treated according to two different protocols: (1) thawed after freezing ("non-dried") and (2) thawed and air-dried to a constant weight ("dried"). Two points were investigated in detail to improve the method: individual soft tissue dry weight and tissue metal concentration following a standard digestion method. In both instances, the results were compared with those from manually dissected snails. Conditions for total shell decalcification of 60 individuals (3-4 mm long) were 5.5 h in 20 ml of 0.1 M TCA.No differences in individual soft tissue weight were observed between the treatments, indicating good efficiency of the TCA extraction with respect to weight of soft body parts. In contrast, tissue metal concentrations varied among treatments. The TCA extraction of the dried animals had a good recovery for Cd, most likely due to the lower solubility of Cd vital cellular components (proteins and mineral concretions) from the dried tissue. Satisfactory recoveries of the tissue concentrations of Cu and Pb were obtained for the non-dried individuals. This might be related to the specific distribution of metals in the organism (namely in the digestive glands and gonads) and their different chemical reactivity with TCA after the tissue was dried. Limited susceptibility of Zn-bearing protein bindings to complexing with TCA also accounts for significantly lower concentrations of Zn in the mud snail's soft tissue that was extracted. The 0.1 M TCA solution is therefore recommended for extraction of the shells of Hydrobia ulvae for tissue determination of Cd, Cu and Pb; however the treatment protocol does affect metal recovery and thus a consistent procedure should be followed.The extracted metals from the soft tissues and shells of the mud snails (on the basis of both metal concentrations and contents) were ranked in order of increasing contribution of soft body parts to the total (shell+tissue): Pb相似文献   

Flow depletion in a small stream caused by ground water abstraction from wells

The interaction between a gaining stream and a water-table aquifer is studied at an outwash plain. The aquifer is hydraulically well connected to the stream. Pumping tests were carried out in 1997 and 1998 in two wells 60 m from the stream, screening different depths of the aquifer. Drawdown was measured on both sides of the stream. Hydraulic head, drawdown, and stream depletion data were analyzed using numerical flow models. Similar models were fitted to each of two different data sets: Model A was fitted to steady-state hydraulic head and streamflow gain data not influenced by pumping; and model B was fitted to drawdown data measured during the 1998 pumping test. Each calibrated model closely fits its calibration data; however, predictions were biased if model A was used to predict the calibration data of model B, and vice versa. To further test the models, they were used to predict streamflow depletion during the two pumping tests as well as the drawdown during the 1997 test. Neither of these data were used for calibration. Model A predicted the measured depletions fairly accurately during both tests, whereas the predicted drawdowns in 1997 were significantly larger than actually measured. Contrary to this, the 1997 drawdowns predicted by model B were nearly unbiased; the predicted depletions deviate significantly from the measured depletions in 1997, but they compare well with the observations in 1998. Thus, although field work and analyses were extensive and done carefully to develop a ground water flow model that could predict both drawdown and streamflow depletion, the model predictions are biased. Analyses indicate that the deviations between model and data may be because of error in the models' representations of either the release of water from storage or of the hydrology in the riparian zone.     

Trace elements in skin of Dall's porpoises (Phocoenoides dalli) from the northern waters of Japan: an evaluation for utilization as non-lethal tracers

Concentrations of Fe, Zn, Cu, Se, Mn, Mo, Hg, Cd, Cr, Ag, Pb, Sr and V were determined in skins of Dall's porpoises (Phocoenoides dalli) of the Pacific coast truei-type population (PT population) (N=45), and the Sea of Japan-Okhotsk dalli-type population (JD population) (N=31) from the northern waters of Japan. Cutaneous Hg concentrations in both PT and JD populations were significantly correlated with age, indicating a possible alternative method of age estimation. A significant correlation was also noted between Hg concentrations in skin and liver, suggesting that biopsy samples of skin can provide a non-lethal surrogate for monitoring Hg contamination in this species. Trace element accumulation patterns differed strongly between PT and JD populations, when analyzed by principal component analysis, suggesting these patterns could be utilized as non-lethal tracers of population identification.     

Subcellular distribution of trace elements in the liver of sea turtles

Subcellular distribution of Cu, Zn, Se, Rb, Mo, Ag, Cd and Pb was determined in the liver of green turtles (Chelonia mydas) and hawksbill turtles (Eretmochelys imbricata) from Yaeyama Islands, Japan. Also, hepatic cytosol from sea turtles was applied on a Sephadex G-75 column and elution profiles of trace elements were examined. Copper, Zn, Se, Rb, Ag and Cd were largely present in cytosol in the liver of both species, indicating that cytosol was the significant site for the accumulation of these elements in sea turtles. In contrast, Mo and Pb were accumulated specifically in nuclear and mitochondrial fraction and microsomal fraction, respectively. Gel filtration analysis showed that Cu, Zn, Ag and Cd were bound to metallothionein (MT) in the cytosol of sea turtles. To our knowledge, this is the first report on the association of trace elements with MT in sea turtles.     

慢震复合性质的进一步证据:1997年4月28日爱德华王子岛地震

1997年4月28日爱德华王子岛转换断层地震(M_u6.8)的地震图清楚地显示了两类破裂的重叠,一种是正常地震,一种是在低频辐射能量的慢成分。我们将低频谱数据和P波波形数据结合起来,反演满足0.001～2.5 Hz数据的震源时间函数。结果表明地震开始于快主震前约15s的一个慢事件,它是持续时间在30s以上慢震的一部分。在地区性台站P波到时初始部分期间,从高频能量低振幅推断初始事件的平滑度。方向性分析表明,破裂的这两种成分发生在不同断层上。慢事件发生在主转换断层上,快事件发生在以东40 km的一个平行断层上。1994年罗曼什转换断层上发生过一个包括慢成分和快成分的近似的复合序列,且在多个断层上都发生了破裂。慢震的这些结果和其他结果表明,海洋转换断层上的许多大地震都是复合事件。     

灌溉后的黄土剪切特征变化

在中国甘肃省的黑方台阶地上从上世纪60年代开始出现人类定居和开垦活动,并自1968年发展为灌溉农业。随着灌溉的进行地面已出现沉陷和滑坡。地表沉陷是由灌溉水的充填引起黄土结构崩塌造成的。然而崩塌和湿润化对剪切特征的影响目前还不清楚。为了研究湿化后的黄土剪切特征的变化,进行了对马兰黄土未经扰动和重塑土样的直接剪切盒测试。结果显示未扰动土样的粘合力和内摩擦角在湿润化后都下降了,而所观察到的重塑土的弹度参数只有少许变化。未扰动土的不饱合粘合力,据认为其受胶结物质的影响,在饱合后消失了。经灌溉的土的不饱合强度参数与未灌溉土相比表现出差异,它们可能受土壤水分的强烈影响。     

Diamond Discovered in Dangqiong Ophiolite, Western Yarlung-Zangbu Suture Zone, Tibet

<正>The first diamonds from ophiolite were found in peridotite of Luobusa ophiolite along Yarlung Zangbu suture zone in Tibet,China(IGCAGS,1981),and then more and more diamonds found in harzgurgite(Bai et al.,1993;Yang et al.,2007a;Robinson et al.,2014;Xu et al.,     

Diopside and Magnetite Exsolutions in Olivine from Lower Cr# Dunite in the Dongbo Ophiolite, Southern Tibet

<正>Diopside and magnetite exsolutions occur as oriented intergrowths within olivine of the lower Cr~#dunite in the Dongbo ophiolite,Tibet.The fresh lower Cr~#dunite has a mineral assemblage of olivine,spinel and diopside.The Fo content of its olivine is 90–92,which is lower than that of the higher Cr~#dunite lenses(Fo92-Fo94)without