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11.
Accurate measurements of cell parameters were performed on the ilmenite phases of ZnSiO3 and MgGeO3 using an X-ray diffraction method under hydrostatic conditions. The linear changes in cell parameter are represented by 1?a/a 0=(1.06±0.04)×10?4 P(kbar) and 1?c/c 0=(2.11±0.04)×10?4 P for ZnSiO3, and 1?a/a 0=(1.37±0.03)×10?4 P and 1?c/c 0=(2.05±0.04)×10?4 P for MgGeO3. A least-squares calculation using the first-order Birch-Murnaghan equation gives K T =2.16±0.02 Mbar and K T =1.87±0.02 Mbar for ZnSiO3 and MgGeO3, respectively. Elastic systematics assuming K T V m =constant give a predicted value K T =2.14 Mbar for the ilmenite phase of MgSiO3. 相似文献
12.
Partition of Fe2+ and Mg between coexisting (Mg, Fe)2SiO4 spinel and (Mg, Fe)SiO3 pyroxene was investigated at pressures 80 and 90 kbar and at temperatures 840 and 1050° C, using tetrahedral-anvil type of high pressure apparatus. Olivine-spinel solid solution equilibria in the system Mg2SiO4-Fe2SiO4 were discussed in the light of the partition reaction. Partition of Fe2+ and Mg in both olivine-spinel and pyroxene-spinel systems can not be regarded as that between ideal solid solutions. By applying the simple solution model for the partition of Fe2+ and Mg, sign of the heat of mixing was estimated to be positive for all olivine, spinel and pyroxene. Relative concentration of Fe2+ in spinel in the pyroxene-spinel system is likely to cause some change in the chemical composition of modified spinel () or spinel () in the transition zone of the mantle. A considerable change is also expected in the transition pressure of to ( + ) and ( + ) to .Presented at the symposium Recent Advances in the Studies of Rocks and Minerals at High Pressures and Temperatures held in Montreal, 1972. Jointly sponsored by the International Mineralogical Association and the Commission on Experimental Petrology. 相似文献
13.
Takatoshi Akimoto Hajimu Kinoshita Toshio Furuta 《Earth and Planetary Science Letters》1984,71(2):263-278
Partially oxidized titanomagnetite grains in various kinds of volcanic rocks were investigated by electron probe microanalyzer (EPMA) in order to clarify the process of oxidation at low temperature. The following results were obtained by the present investigation: (1) Primary composition of titanomagnetite is homogeneous in individual grains, although variation in composition among different grains is observed on each thin section. (2) Migration of Fe cations during low-temperature oxidation is clearly seen in all oxidized grains. Some other constituent cations are also bleached and consequently the relative content of the remaining cations becomes large. (3) The detailed internal structures of titanomagnetite grains are observed as backscattered electron images (BEI) with an electronprobe microanalyzer, and it seems likely that the structures depend upon the degree of low-temperature oxidation. (4) The chemical and physical properties of oxidized titanomagnetites imply that low-temperature oxidation is not a simple process but a complex one. Such an oxidation process is correlatable to both the mobility of cation and the oxidation condition such as a circulation of some active hydrothermal materials at low temperature. 相似文献
14.
Jay D. Bass Donald J. Weidner N. Hamaya M. Ozima S. Akimoto 《Physics and Chemistry of Minerals》1984,10(6):261-272
The single-crystal elastic moduli, c ij x, of the olivine (α) and spinel (γ) polymorphs of nickel orthosilicate have been measured at atmospheric pressure and 20° C by Brillouin spectroscopy. The results are (Mbar), Ni2SiO4 olivine: c 11=3.40(2), c 22=2.38(2), c 33=2.53(2), c 44=0.71(1), c 55=0.87(1), c 66=0.78(1), c 12=1.09(2), c 13=1.10(4), c 23=1.13(3), Ni2SiO4 spinel: c 11=3.66(3), c 44=1.06(1), c 12=1.55(3). In comparing these results with extant elasticity data for olivine- and spinel-type compounds we find distinctive elastic characteristics related to crystal structure, and systematic trends due only to compositional variation. For silicate olivines, the longitudinal moduli decrease in the order c 11>c 33>c 22, regardless of composition. The moduli c 55 and c 66 are approximately equal, and greater than c 44. The former relationship is related to differences in polyhedral linkages along the crystallographic axes, whereas the latter may result from rotational freedom of SiO4 tetrahedra in response to different directions of shear. Composition affects elasticity most directly through the relative magnitudes of \(\bar c_{12} > \; = (c_{12} + c_{13} + c_{23} )/3\) and \(\bar c_{44} = (c_{44} + c_{55} + c_{66} )/3\) . When transition-metal cations are six-coordinated by oxygen \(\bar c_{12} > \bar c_{44}\) , and when alkaline-earth cations are six-coordinated \(\bar c_{44} > \bar c_{12}\) . The longitudinal moduli along and normal to the close-packed directions of spinels are similar, reflecting the framework-like arrangement of octahedra. These longitudinal moduli exhibit little compositional dependence upon tetrahedral cations but vary dramatically with octahedral substitution. Our data indicate that tetrahedral cations affect elastic properties more as the oxygen positional parameter, u, decreases. The u parameter is also directly related to elastic anisotropy. While γ-Ni2SiO4 (u=0.244) is elastically isotropic, anisotropy increases rapidly as u approaches a limiting value near 0.27, and may be related to mechanical stability of the spinel structure. The longitudinal wave velocities along close-packed directions in α and γ Ni2SiO4 are equal. Thus, for an α-γ polymorphic pair, the assumptions of elastic isotropy of the γ phase and equal velocities in close-packed directions of α and γ allows the c ij's and shear modulus of a spinel-structure silicate to be estimated from c 11 of the corresponding α phase and the bulk modulus of the γ phase. 相似文献
15.
Izumi Nakai Junji Akimoto Masayuki Imafuku Ritsuro Miyawaki Yoshinori Sugitani Kichiro Koto 《Physics and Chemistry of Minerals》1987,15(2):113-124
X-ray absorption spectroscopy using synchrotron radiation has been applied to the investigation of the coordination geometries around Y, Zr and Nb atoms in metamict zircon, gadolinite, fergusonite, euxenite and samarskite. EXAFS and XANES spectra of their crystalline counterparts and synthetic compounds including ZrO2, Y2O3, YNbTiO6, YNbO4, LiNbO3, and NiNb2O6 were also measured for comparison. Metamict zircon shows a significant decrease in its Zr-O bond distances accompanying an increase in distortion of the Zr-O coordination polyhedra as compared with crystalline zircon. On the contrary, the average Nb-O bond distances and the symmetry of the coordination polyhedra around the Nb atoms in metamict euxenite and samarskite resemble those in the crystalline euxenite. Compared with crystalline fergusonite, a decrease in the distortion of the Nb-O octahedra is observed in metamict fergusonite. The structures of the second nearest neighbors (the metal-metal interactions) are largely disrupted in the metamict specimens except for metamict zircon and samarskite with high trivalent iron concentration. Nb in metamict samarskite is in octahedral coordination by oxygen and is similar to that in euxenite. 相似文献
16.
This paper evaluated the impacts of climate change mitigation technology options on CO2 emission reductions and the effects of model representations regarding renewable intermittency on the assessment of reduction by using a world energy systems model. First, different diffusion scenarios for carbon dioxide capture and storage (CCS), nuclear power, and wind power and solar PV are selected from EMF27 scenarios to analyze their impacts on CO2 emission reductions. These technologies are important for reducing CO2 intensity of electricity, and the impacts of their diffusion levels on mitigation costs are significant, according to the analyses. Availability of CCS in particular, among the three kinds of technologies, has a large impact on the marginal CO2 abatement cost. In order to analyze effects of model representations regarding renewables intermittency, four different representations are assumed within the model. A simplistic model representation that does not take into consideration the intermittency of wind power and solar PV evaluates larger contributions of the energy sources than those evaluated by a model representation that takes intermittency into consideration. Appropriate consideration of renewables intermittency within global energy systems models will be important for realistic evaluations of climate change mitigation scenarios. 相似文献
17.
The Models-3 Community Multi-scale Air Quality modeling system (CMAQ) coupled with the Regional Atmospheric Modeling System
(RAMS) is used to simulate three-dimensional concentration distributions of hydroxyl (OH) and hydroperoxyl (HO2) radicals over the western Pacific Ocean during the NASA Transport and Chemical Evolution over the Pacific (TRACE-P) field
campaign. Modeled values of OH and HO2 and their closely related chemical species and photolysis rates are compared with observational data collected onboard the
DC-8 aircraft. Comparison shows that the model reasonably reproduced these observed values over a broad range of conditions
with an overall tendency to overestimate the measured OH and HO2 by a factor of 1.56 and 1.24, respectively. A case study of OH, HO2 and their closely related chemical species and photolysis rates along the DC-8 flights 11 and 12 conducted on 17–18 March
2001 shows that the model reproduces the temporal and spatial variations reasonable well, and produces more reliable OH and
HO2 concentrations in the polluted environment than in the clean marine boundary layer. 相似文献
18.
The system Mg2SiO4MgOH2O was investigated at pressures between 85 and 160 kbar and at temperatures between 750 and 1200°C. In runs for a gel with Mg/Si ratio of 3 and with 4.0 wt.-percent H2O, a dense hydrous magnesian silicate, denoted phase B by Ringwood and Major, was found at pressures from about 100 kbar to at least 160 kbar in the whole temperature range studied. In the following table the crystallographic parameters and chemical formula of phase B, determined in this study, are compared with those of the other dense hydrous silicates in Mg2SiO4MgOH2O.
Phase | Composition | Space group | Cell parameters | Density (g cm?3) | |||
β | |||||||
(Å) | (Å) | (Å) | (°) | ||||
Chondrodite | Mg5Si2O10H2 | 7.914 | 4.752 | 10.350 | 108.71 | 3.06 | |
Clinohumite | Mg9Si4O18H2 | 13.695 | 4.747 | 10.284 | 100.64 | 3.14 | |
Phase A | Mg7Si2O14H6 | 7.860 | 9.573 | 2.96 | |||
Phase B | Mg23Si8O42H6 | 10.600 | 14.098 | 10.092 | 104.05 | 3.32 |