Epigenetic salt accumulation and water movement in the active layer of central Yakutia in eastern Siberia

Observations of soil moisture and salt content were conducted from May to August at Neleger station in eastern Siberia. Seasonal changes of salt and soil moisture distribution in the active layer of larch forest (undisturbed) and a thermokarst depression known as an alas (disturbed) were studied. Electric conductivity EC_e of the intact forest revealed higher concentrations that increased with depth from the soil surface into the active layer and the underlying permafrost: 1 mS cm^?1 at 1·1 m, to 2·6 mS cm^?1 at 160 cm depth in the permafrost. However, a maximum value of 5·4 mS cm^?1 at 0·6 m depth was found in the dry area of the alas. The concentration of ions, especially Na⁺, Mg²⁺, Ca²⁺, SO₄^2? and HCO₃^? in the upper layers of this long‐term disturbed site, indicates the upward movement of ions together with water. A higher concentration of solutes was found in profiles with deeper seasonal thawing. The accumulation of salts in the alas occurs from spring through into the growing season. The low concentration of salt in the surface soil layers appears to be linked to leaching of salts by rainfall. There are substantial differences between water content and electric conductivity of soil in the forest and alas. Modern salinization of the active layer in the alas is epigenetic, and it happens in summer as a result of spring water collection and high summer evaporation; the gradual salt accumulation in the alas in comparison with the forest is controlled by the annual balance of water and salts in the active layer. Present climatic trends point to continuous permafrost degradation in eastern Siberia increasing the risk of surface salinization, which has already contributed to changing the landscape by hindering the growth of forest. Copyright © 2006 John Wiley & Sons, Ltd.     

Geomorphological significance of Ontario Lacus on Titan: Integrated interpretation of Cassini VIMS,ISS and RADAR data and comparison with the Etosha Pan (Namibia)

Ontario Lacus is the largest lake of the whole southern hemisphere of Titan, Saturn’s major moon. It has been imaged twice by each of the Cassini imaging systems (Imaging Science Subsystem (ISS) in 2004 and 2005, Visual and Infrared Mapping Spectrometer (VIMS) in 2007 and 2009 and RADAR in 2009 and 2010). We compile a geomorphological map and derive a “hydrogeological” interpretation of Ontario Lacus, based on a joint analysis of ISS, VIMS and RADAR SAR datasets, along with the T49 altimetric profile acquired in December 2008. The morphologies observed on Ontario Lacus are compared to landforms of a semi-arid terrestrial analog, which resembles Titan’s lakes: the Etosha Pan, located in the Owambo Basin (Namibia). The Etosha Pan is a flat-floored depression formed by dissolution, under semi-arid conditions, of a surface evaporitic layer (calcretes) controlled by groundwater vertical motions. We infer that Ontario Lacus is an extremely flat and shallow depression lying in an alluvial plain surrounded by small mountain ranges under climatic conditions similar to those of terrestrial semi-arid regions. Channels are seen in the southern part of Ontario Lacus in VIMS and RADAR data, acquired at a 2-years time interval. Their constancy in location with time implies that the southern portion of the depression is probably not fully covered by a liquid layer at the time of the observations, and that they most probably run on the floor of the depression. A shallow layer of surface liquids, corresponding to the darkest portions of the RADAR images, would thus cover about 53% of the surface area of the depression, of which almost 70% is located in its northern part. These liquid-covered parts of the depression, where liquid ethane was previously identified, are interpreted as topographic lows where the “alkanofer” raises above the depression floor. The rest of the depression, and mostly its southern part, is interpreted as a flat and smooth exposed floor, likely composed of a thick and liquid-saturated coating of photon-absorbing materials in the infrared. This hypothesis could explain its dark appearance both in the infrared and radar data and the persistence of channels seen on the depression floor over the time. Shorelines are observed on the border of Ontario Lacus suggesting past high-stand levels of the alkanofer table. The analogy with the Etosha Pan suggests that Ontario Lacus’ depression developed at the expense of a soluble layer covering the region. Dissolution of this layer would be controlled by vertical motions of the alkanofer table over the time. During flooding events, liquid hydrocarbons covering the depression floor would dissolve the surface layer, increasing progressively the diameter of the depression on geological timescales. During drought episodes, liquid hydrocarbons of the underground alkanofer would evaporate, leading to crystallization of “evaporites” in the pores and at the surface of the substratum, and to the formation of the regional soluble layer. The presence of specific landforms (lunette dunes or evaporites) is compatible with such evaporitic regional settings. Alternatively, but not exclusively, the surface soluble layer might have formed by accumulation on the ground of soluble compounds formed in the atmosphere.     

Robustness of pattern scaled climate change scenarios for adaptation decision support

Pattern scaling offers the promise of exploring spatial details of the climate system response to anthropogenic climate forcings without their full simulation by state-of-the-art Global Climate Models. The circumstances in which pattern scaling methods are capable of delivering on this promise are explored by quantifying its performance in an idealized setting. Given a large ensemble that is assumed to sample the full range of variability and provide quantitative decision-relevant information, the soundness of applying the pattern scaling methodology to generate decision relevant climate scenarios is explored. Pattern scaling is not expected to reproduce its target exactly, of course, and its generic limitations have been well documented since it was first proposed. In this work, using as a particular example the quantification of the risk of heat waves in Southern Europe, it is shown that the magnitude of the error in the pattern scaled estimates can be significant enough to disqualify the use of this approach in quantitative decision-support. This suggests that future application of pattern scaling in climate science should provide decision makers not just a restatement of the assumptions made, but also evidence that the methodology is adequate for purpose in practice for the case under consideration.     

Spatial simulation of evapotranspiration of semi-arid Inner Mongolian grassland based on MODIS and eddy covariance data

In semi-arid regions of Central Asia, water shortage results from low annual precipitation (P) with high interannual variability. Evapotranspiration (ET) dominates water balance losses entirely. Previous studies showed large differences between individual grassland sites in the partitioning of ET into evaporation and transpiration, but only little difference in the evaporative ratio ET/P. The hydrological model BROOK90 was applied to the Xilin river catchment in Inner Mongolia (China) in combination with data from moderate resolution imaging spectroradiometer (MODIS) and ET measurements. The ET part of the model was parameterised using several years of eddy covariance (EC) measurements over grasslands differing in grazing intensity and leaf area index (LAI). Using a relatively well-established relationship of LAI and P as well as LAI and temperature derived from MODIS, the water balance components of a 16 km2 sample area in the catchment were modelled with a 1 km2 resolution for the vegetation period of 2006. All pixels were modelled assuming a similar ET control as at the EC sites. Spatial variation in ET as well as in the partitioning of ET between transpiration and evaporation could be identified. The results indicate the potential of using MODIS data and BROOK90 to upscale ET of semi-arid grasslands from site to larger grass dominated catchments.     

Geochemical modeling and low-frequency geoelectrical methods to evaluate the impact of an open dump in arid and deltaic environments

In Mexico, open dumps that are maintained by the municipality but provide no covering of waste are not uncommon. Further, disposal at these sites is often performed by burning. The aim of this study was to determine the leachate plume from an open dump located in a depositional deltaic environment, with arid climate, low rainfall and where the water table is about 2 m below the surface. The methodology comprised analysis of groundwater monitoring wells and geophysical and geochemical prospecting techniques. The 3D geoelectric interpretation shows a typical area of these depositional environments with low resistive values (10–20 Ω-m) associated with the presence of sands and clays interbedded. However, there is a very low resistivity zone associated with the dump’s impact which reaches values below 5 Ω-m, and it is located where the disposal and burning of wastes occurred. Another zone with values above 16 Ω-m appears as a limit for the advance of the saline. This is interpreted as a sandy lenses area. These sandy lenses with higher porosity transport aquifer’s water. Thus the dump is in direct contact by this conduct with clean groundwater. Piper diagrams constructed with the chemical data analysis reveal that the groundwater in the area corresponds to the chlorinated and/or sulfated sodium type, showing the impact caused by the dump. The monitoring well (NP8, on-site) with the highest dissolved solids content behaves anomalously and belongs to the more conductive zone according to the geoelectric profiles. The subsoil geochemical behavior is influenced by the seasonal water table variations provoking the dissolution of burned and unburned wastes, but the effects of slow flows in the direction of the regional flow are not discarded. Although the most impacted area within the dump is characterized to a depth of 10 m, there is a slow flow in the direction of the regional flow that has been moving pollutants out of the dumpsite during its almost 20 years of operation. The results of this study provide valuable information for the authorities to carry out an appropriate restoration project.     

On-site treatment of textile yarn dyeing effluents using an integrated biological–chemical oxidation process

This paper reports the results of the treatment of a yarn dyeing effluent using an integrated biological–chemical oxidation process. In particular, the biological unit was based on a sequencing batch biofilter granular sludge reactor (SBBGR), while the chemical treatment consisted of an ozonation step. Biological treatment alone was first performed as a reference for comparison. While biological treatment did not produce an effluent for direct discharge, the integrated process assured good treatment results, with satisfactory removal of chemical oxygen demand (up to 89.8 %), total nitrogen (up to 88.2 %), surfactants (up to 90.7 %) and colour (up to 99 %), with an ozone dose of 110 mg of ozone per litre of wastewater. Biomass characterization by fluorescence in situ hybridization has revealed that filamentous bacteria represented about 20 % of biomass (coherently with high sludge volume index values); thanks to its special design, SBBGR guaranteed, however, stable treatment performances and low effluent suspended solids concentrations, while conventional activated sludge systems suffer from sludge bulking and even treatment failure in such a condition. Furthermore, biomass characterization has evidenced the presence of a shortcut nitrification–denitrification process.     

Comparison of methods for the analysis of New Zealand sea lion,Phocarctos hookeri,milk

Abstract

The milk composition of New Zealand sea lion, Phocarctos hookeri, was determined using standard analytical methods, a MilkoScan? FT 120 and an accelerated solvent extractor (ASE) for fat concentration. The results for fat, protein and total solid concentrations between the different analytical methods were assessed using different measures of statistical fitness including coefficient of determination, concordance correlation coefficient, mean prediction error, and intraclass correlation coefficient. The repeatability and reliability of the results obtained with the calibrated MilkoScan? FT 120 were comparable with those obtained using standard methods, the Roese‐Gottlieb method for fat, Kjeldahl method for protein and gravimetric method for total solids. The MilkoScan? FT 120s are fast and cost‐effective and are widely used in dairy laboratories around the world, which should make them readily accessible to ecologists/biologists studying the milk composition of non‐domestic animals.     

Layered intrusions and volcanic sequences in Central Brazil: Geological and geochronological constraints for Mesoproterozoic (1.25 Ga) and Neoproterozoic (0.79 Ga) igneous associations

A 350-km long belt of layered complexes and associated volcano-sedimentary sequences forms a continental-scale feature exposed along the internal portion of the Neoproterozoic Brasília Belt in central Brazil. This study provides new geochronological results and a critical review of the available data of these igneous associations of central Brazil. Precise age dating combined with geological and petrological studies indicate that this belt consists of two distinct igneous rock associations. The 1.25 and 0.79 Ga igneous episodes are constrained by reliable U–Pb zircon ages (SHRIMP and ID-TIMS) obtained in different regions and lithotypes of this belt. Both igneous associations were affected by high-grade metamorphism and tectonism at ca. 0.76 Ga, which partially disrupted the original igneous stratigraphy of the layered complexes and volcano-sedimentary sequences. The present configuration of this belt results from later events, probably caused by final ocean closure and continental collision between the São Francisco and Amazonian continents at ca. 0.63 Ga.     

Influence of hydrology on phytoplankton species composition and life strategies in a subtropical coastal lagoon periodically connected with the Atlantic Ocean

A survey was carried out to investigate the relationship of phytoplankton biovolume, structure, and species life strategies with major abiotic factors in a subtropical choked coastal lagoon (34°33′S, 54°22′W) naturally connecting with the Atlantic Ocean several times a year. Marine and limnetic influence areas were sampled on a monthly basis during two periods, one of low rainfall and high conductivity (August 1996 to February 1998) and a second period with the opposite tendency (December 1998 to March 2000). Photosynthetically active radiation availability was high and reached the bottom (>1% of the incident light), while dissolved inorganic nitrogen (0.6–18.4 μM), soluble reactive phosphorus (<0.3–2.7 μM), and reactive silica (5–386 μM) were highly variable. Life strategies were identified in the phytoplankton as a function of morphology. C-strategists, invasive planktonic and epipelic species of small size, and R-strategists, mixing-dependent species of medium size, characterized this permanently mixed system. High frequency of exchange with the ocean prevented high biomass accumulation. Phytoplankton biomass was lower in the second period of high rainfall (2.3 and 1.1 mm³ 1⁻¹ for period 1 and 2 respectively). A canonical correspondence analysis showed that conductivity, nitrogen, phosphorus, and silica were the main environmental variables explaining phytoplankton species composition patterns. During the first period, Bacillariophyceae (mostly pennate species) and the potentially toxicPrococentrum minimum were dominant; during the second period a higher contribution of flagellates (Cryptophyceae, Euglenophyceae, Prasinophyceae, and flagellates <7 μm) was found. Differences of phytoplankton biomass, main taxonomic groups, and strategies were found between periods but not between limnic and marine areas, suggesting that hydrological dynamic is more relevant than seasonal and spatial differences.