Structure and neotectonics of the western Santa Ynez fault system in southern California

Geologic, geomorphic and seismologic data indicate that west of Lake Cachuma the Santa Ynez fault branches into several major W- and NW-trending splay faults. Two of the faults bracket the wedge-shaped Santa Maria basin. The most compelling evidence for the existence of these two faults is the fact that the Santa Maria basin is floored by Franciscan basement overlain only by Miocene and younger sedimentary rocks, whereas across the inferred traces of each of these faults, the adjacent terrains consist of Franciscan basement overlain by thick sequences of Early Tertiary strata, as well as by Miocene and younger rocks. The third splay fault strikes northwestward through the central Santa Maria basin. Narrow zones of tightly appressed, left-stepping en-echelon folds are locally adjacent to the faults along the south edge, and through the center of the basin. The geometrical arrangement of these folds is indicative of formation over buried sinistral wrench faults. Evidence for Holocene surface rupturing is lacking or nebulous at best, but epicenters of damaging historical earthquakes are spatially, and by inference, genetically related to the central Santa Maria basin faults, indicating that they comprise the presently active strands among the several splay faults.     

ISO LWS Observations of H2O from R Cas: A Consistent Model For Its Circumstellar Envelope

We present an ISO LWS 43-197 μm grating spectrum of the oxygen-rich AGB star R Cas. The spectrum is rich of isolated and blended H2O lines. For their identification and in order to determine the physical parameters of the circumstellar envelope, we have constructed a model which treats radiative transfer, chemical exchange and photodissociation reactions, and various heating and cooling processes in a consistent manner. By fitting the observed line fluxes and using stellar parameters based upon the Hipparcos distance, we derived a mass-loss rate of M = 1 10-6 M⊙ yr-1 which is close to the value 6 10-7 M⊙ yr-1 previously derived for W Hya, another oxygen-rich AGB star. This revised version was published online in August 2006 with corrections to the Cover Date.     

Mantle and crustal sources of Archean anorthosite: a combined in situ isotopic study of Pb–Pb in plagioclase and Lu–Hf in zircon

Isotopic analyses of ancient mantle-derived magmatic rocks are used to trace the geochemical evolution of the Earth’s mantle, but it is often difficult to determine their primary, initial isotope ratios due to the detrimental effects of metamorphism and secondary alteration. We present in situ analyses by LA-MC-ICPMS for the Pb isotopic compositions of igneous plagioclase (An_75–89) megacrysts and the Hf isotopic compositions of BSE-imaged domains of zircon grains from two mantle-derived anorthosite complexes from south West Greenland, Fiskenæsset and Nunataarsuk, which represent two of the best-preserved Archean anorthosites in the world. In situ LA-ICPMS U–Pb geochronology of the zircon grains suggests that the minimum crystallization age of the Fiskenæsset complex is 2,936 ± 13 Ma (2σ, MSWD = 1.5) and the Nunataarsuk complex is 2,914 ± 6.9 Ma (2σ, MSWD = 2.0). Initial Hf isotopic compositions of zircon grains from both anorthosite complexes fall between depleted mantle and a less radiogenic crustal source with a total range up to 5 ε_Hf units. In terms of Pb isotopic compositions of plagioclase, both anorthosite complexes share a depleted mantle end member yet their Pb isotopic compositions diverge in opposite directions from this point: Fiskenæsset toward a high-μ, more radiogenic Pb, crustal composition and Nunataarsuk toward low-μ, less radiogenic Pb, crustal composition. By using Hf isotopes in zircon in conjunction with Pb isotopes in plagioclase, we are able to constrain both the timing of mantle extraction of the crustal end member and its composition. At Fiskenæsset, the depleted mantle melt interacted with an Eoarchean (~3,700 Ma) mafic crust with a maximum ¹⁷⁶Lu/¹⁷⁷Hf ~0.028. At Nunataarsuk, the depleted mantle melt interacted with a Hadean (~4,200 Ma) mafic crust with a maximum ¹⁷⁶Lu/¹⁷⁷Hf ~0.0315. Evidence from both anorthosite complexes provides support for the long-term survival of ancient mafic crusts that, although unidentified at the surface to date, could still be present within the Fiskenæsset and Nunataarsuk regions.     

Nonporphyritic chondrules and chondrule fragments in enstatite chondrites: Insights into their origin and secondary processing

Sixteen nonporphyritic chondrules and chondrule fragments were studied in polished thin and thick sections in two enstatite chondrites (ECs): twelve objects from unequilibrated EH3 Sahara 97158 and four objects from equilibrated EH4 Indarch. Bulk major element analyses, obtained with electron microprobe analysis (EMPA) and analytical scanning electron microscopy (ASEM), as well as bulk lithophile trace element analyses, determined by laser ablation inductively coupled plasma–mass spectrometry (LA‐ICP‐MS), show that volatile components (K₂O + Na₂O versus Al₂O₃) scatter roughly around the CI line, indicating equilibration with the chondritic reservoir. All lithophile trace element abundances in the chondrules from Sahara 97158 and Indarch are within the range of previous analyses of nonporphyritic chondrules in unequilibrated ordinary chondrites (UOCs). The unfractionated (solar‐like) Yb/Ce ratio of the studied objects and the mostly unfractionated refractory lithophile trace element (RLTE) abundance patterns indicate an origin by direct condensation. However, the objects possess subchondritic CaO/Al₂O₃ ratios; superchondritic (Sahara 97158) and subchondritic (Indarch) Yb/Sc ratios; and chondritic‐normalized deficits in Nb, Ti, V, and Mn relative to RLTEs. This suggests a unique nebular process for the origin of these ECs, involving elemental fractionation of the solar gas by the removal of oldhamite, niningerite, and/or another phase prior to chondrule condensation. A layered chondrule in Sahara 97158 is strongly depleted in Nb in the core compared to the rim, suggesting that the solar gas was heterogeneous on the time scales of chondrule formation. Late stage metasomatic events produced the compositional diversity of the studied objects by addition of moderately volatile and volatile elements. In the equilibrated Indarch chondrules, this late process has been further disturbed, possibly by a postaccretional process (diffusion?) that preferentially mobilized Rb with respect to Cs in the studied objects.     

Gold contents of sulfide minerals in granitoids from southwestern New Brunswick,Canada

The abundance of gold and selected trace elements in magmatic sulfide and rock-forming minerals from Silurian–Devonian granitoids in southwestern New Brunswick were quantitatively analyzed by laser-ablation inductively coupled plasma mass-spectrometry. Gold is mainly hosted in sulfide minerals (i.e., chalcopyrite, pyrrhotite, and pyrite), in some cases perhaps as submicron inclusions (nanonuggets). Gold is below detection (<0.02 ppm) in major rock-forming minerals (i.e., plagioclase, K-feldspar, biotite, hornblende, and muscovite) and oxides (i.e., magnetite, and ilmenite). Gold distribution coefficients between sulfide and granitoid melt are calculated empirically as: . This result suggests that gold behavior in the granitoid systems is controlled by the conditions of sulfur saturation during magmatic evolution; the threshold of physiochemical conditions for sulfur saturation in the melts is a key factor affecting gold activity. Gold behaves incompatibly prior to the formation of sulfide liquids or minerals, but it becomes compatible at their appearance. Gold would be enriched in sulfur-undersaturated granitoid magmas during fractionation, partitioning into evolved magmatic fluids and favoring the formation of intrusion-related gold deposits. However, gold becomes depleted in residual melts if these melts become sulfur-saturated during differentiation, leading to gold precipitation in the early sulfide phases of a granitoid suite. Late-stage Cl-bearing magmatic–hydrothermal fluids with low pH and relatively high oxidation state derived from either progressively cooling magmas at depth or convective circulation of meteoric water buffered by reduced carbon-bearing sediments, may scavenge gold from early sulfide minerals. If a significant amount of gold produced in this manner is concentrated in a suitable geological environment (e.g., shear zones or fracture systems), intrusion-related gold deposits may also be generated. Exploration for intrusion-related gold systems should focus on the areas around evolved phases of granitoid suites that remained sulfur-undersaturated. For sulfur-saturated granitoid suites, the less differentiated phase and associated structures are the most prospective targets.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.     

Textural trends in turbidites and slurry beds from the Oligocene flysch of the East Carpathians, Romania

Deep‐water sandstone beds of the Oligocene Fusaru Sandstone and Lower Dysodilic Shale, exposed in the Buz?u Valley area of the East Carpathian flysch belt, Romania, can be described in terms of the standard turbidite divisions. In addition, mud‐rich sand layers are common, both as parts of otherwise ‘normal’ sequences of turbidite divisions and as individual event beds. Eleven units, interpreted as the deposits of individual flows, were densely sampled, and 87 thin sections were point counted for grain size and mud content. S₃/T_a divisions, which form the bulk of most sedimentation units, have low internal textural variability but show subtle vertical trends in grain size. Most commonly, coarse‐tail normal grading is associated with fine‐tail inverse grading. The mean grain size can show inverse grading, normal grading or a lack of grading, but sorting tends to improve upward in most beds. Fine‐tail inverse grading is interpreted as resulting from a decreasing effectiveness of trapping of fines during rapid deposition from a turbidity current as the initially high suspended‐load fallout rate declines. If this effect is strong enough, the mean grain size can show subtle inverse grading as well. Thus, thick inversely graded intervals in deep‐water sands lacking traction structures do not necessarily imply waxing flow velocities. If the suspended‐load fallout rate drops to zero after the deposition of the coarse grain‐size populations, the remaining finer grained flow bypasses and may rework the top of the S₃ division, forming well‐sorted, coarser grained, current‐structured T_t units. Alternatively, the suspended‐load fallout rate may remain high enough to prevent segregation of fines, leading to the deposition of significant amounts of mud along with the sand. Mud content of the sandstones is bimodal: either 3–13% or more than 20%. Two types of mud‐rich sandstones were observed. Coarser grained mud‐rich sandstones occur towards the upper parts of S₃/T_a divisions. These units were deposited as a result of enhanced trapping of mud particles in the rapidly deposited sediment. Finer grained mud‐rich units are interbedded with ripple‐laminated very fine‐grained sandy T_c divisions. During deposition of these units, mud floccules were hydraulically equivalent to the very fine sand‐ and silt‐sized sediment. The mud‐rich sandstones were probably deposited by flows that became transitional between turbidity currents and debris flows during their late‐stage evolution.     

U‐Pb Detrital Zircon Analysis – Results of an Inter‐laboratory Comparison

Inter‐laboratory comparison of laser ablation ICP‐MS and SIMS U‐Pb dating of synthetic detrital zircon samples provides an insight into the state‐of‐the art of sedimentary provenance studies. Here, we report results obtained from ten laboratories that routinely perform this type of work. The achieved level of bias was mostly within ± 2% relative to the ID‐TIMS U‐Pb ages of zircons in the detrital sample, and the variation is likely to be attributed to variable Pb/U elemental fractionation due to zircon matrix differences between the samples and the reference materials used for standardisation. It has been determined that ~ 5% age difference between adjacent age peaks is currently at the limit of what can be routinely resolved by the in situ dating of detrital zircon samples. Precision of individual zircon age determination mostly reflects the data reduction and procedures of measurement uncertainty propagation, and it is largely independent of the instrumentation, analytical technique and reference samples used for standardisation. All laboratories showed a bias towards selection of larger zircon grains for analysis. The experiment confirms the previously published estimates of the minimum number of grains that have to be analysed in order to detect minor zircon age populations in detrital samples.