Light requirements of the seagrass,Zostera muelleri,determined by observations at the maximum depth limit in a temperate estuary,New Zealand

The Kaipara Harbour in New Zealand is one of the largest estuarine systems in the world, containing significant areas of subtidal seagrass habitat (Zostera muelleri). Light availability at the maximum depth limit for Z. muelleri was measured at 2.10 (0.19 SEM) and 4.91 (0.53 SEM) mol photons m^?2 d^?1 during the winter and summer monitoring periods, respectively. The primary drivers of benthic light availability were found to be surface light availability, the timing of the low tide and water clarity. Core sampling analysis suggested that biomass of seagrass growing at the maximum depth limit was low, indicative of light limitation. The results of this study suggest that the subtidal distribution of seagrass in the Kaipara Harbour is light-limited and that reductions in water clarity due to changes in land use are likely to result in significant reductions in the extent and productivity of subtidal seagrass habitat.     

Solubility of palladium in picritic melts: 1. The effect of iron

In order to improve our understanding of HSE geochemistry, we evaluate the effect of Fe on the solubility of Pd in silicate melts. To date, experimentally determined Pd solubilities in silicate melt are only available for Fe-free anorthite-diopside eutectic compositions. Here we report experiments to study the solubility of Pd in a natural picritic melt as a function of pO₂ at 1300 °C in a one atm furnace. Palladium concentrations in the run products were determined by laser-ablation-ICP-MS. Palladium increases from 1.07 ± 0.26 ppm at FMQ-2, to 306 ± 19 ppm at FMQ+6.6. At a relative pO₂ of FMQ the slope in log Pd concentration vs. log pO₂ space increases considerably, and Pd concentrations are elevated over those established for AnDi melt compositions. In the same pO₂ range, ferric iron significantly increases relative to ferrous iron. Furthermore, at constant pO₂ (FMQ+0.5) Pd concentrations significantly increase with increasing X_FeO-total in the melt. Therefore, we consider ferric Fe to promote the formation of Pd²⁺ enhancing the solubility of Pd in the picrite melt significantly.The presence of FeO in the silicate melt has proven to be an important melt compositional parameter, and should be included and systematically investigated in future experimental studies, since most natural compositions have substantial FeO contents.     

Feasibility of co-culture of the Australasian sea cucumber (Australostichopus mollis) with the Pacific oyster (Crassostrea gigas) in northern New Zealand

The Australasian sea cucumber (Australostichopus mollis) has attracted commercial attention for aquaculture development, partly due to its potential for co-culture with shellfish and finfish species. However, minimal attention has been given to the possibility of co-culturing this species with oysters. In this study we evaluated the growth of juvenile sea cucumbers (36.7 ± 0.9 g, wet weight) caged underneath Pacific oyster farms in northern New Zealand. Co-culture started at the end of the summer, and after 304 days the juveniles had doubled in size (79.8 ± 3.3 g, wet weight), but their subsequent growth appeared to be constrained by overstocking of the cages and summer water temperatures, reaching a carrying capacity of 720 g m^?2. Overall, the results of this study indicate that the co-culture of juvenile sea cucumbers with Pacific oysters is feasible, if sea cucumber losses are reduced (between 33% and 52% lost in this study) and careful attention is given to stocking rates and the water temperature regimes of oyster farms in order to maintain adequate growth rates.     

SCUBA photometry of candidate Vega-like sources

New SCUBA measurements at millimetre wavelengths are presented for a sample of Vega-like stars. Six stars were detected, while sensitive upper limits were obtained for a further 11 sources. Most of the sample selected from a recent catalogue of Vega-like stars have infrared excesses similar to those of the prototype Vega-like stars α Lyr and α PsA. Their IR–submm spectral indices are steep, indicating that the submm emission from the discs is dominated by grains which are smaller than the wavelength of observation and that only small grains exist in those dusty discs. HD 98800 has an IR–submillimetre spectral index of less than two, which suggests that grains have grown to more than 0.3 mm in size. Hipparcos parallax data for HD 42137 and HD 123160 suggest that these two stars are giants rather than dwarfs, similar to the situation previously found for HD 233517. Dust masses, or upper limits, were derived for the sample; these indicate that most of the sources do not have as much dust as Herbig Ae/Be or T Tauri stars, but are likely to have dust masses comparable to those of the prototype Vega-like stars.     

‘Where there is fish,is where I put my head’: Challenges of mobile fishers in Elmina fishing community in Ghana

Small-scale fisheries are crucial for improving livelihoods by providing fisher employment, and food security. As part of their work, fishers frequently move to different fishing communities to catch and trade in fish. This paper analyses the living circumstances of artisanal fishers and discusses their mobility patterns, lodging arrangements, and the difficulties they encounter as they carry out their work. This paper is based on a study that involved 385 artisanal fishers in the fishing community of Elmina in the Komenda Edina Equafo Abirem (KEEA) Municipality in the Central Region of Ghana. The results show that there are not many suitable places to stay for fishers when they travel from home to other fishing locations, and the few places that do offer affordable lodging also lack toilets, bathrooms and drinkable water. The paper also reflects on the gendered dynamics of these and related issues of insecurity for women in this case study. District authorities whose economies are heavily dependent on fishing ought to collaborate with private housing developers and the state to build affordable lodging facilities with standard household amenities like water, toilets and baths in fishing destinations to address the housing issues faced by fishers while travelling.     

Occurrence and concentration of caffeine in Oregon coastal waters

Caffeine, a biologically active drug, is recognized as a contaminant of freshwater and marine systems. We quantified caffeine concentrations in Oregon's coastal ocean to determine whether levels correlated with proximity to caffeine pollution sources. Caffeine was analyzed at 14 coastal locations, stratified between populated areas with sources of caffeine pollution and sparsely populated areas with no major caffeine pollution sources. Caffeine concentrations were measured in major water bodies discharging near sampling locations. Caffeine in seawater ranged from below the reporting limit (8.5 ng/L) to 44.7 ng/L. Caffeine occurrence and concentrations in seawater did not correspond with pollution threats from population density and point and non-point sources, but did correspond with storm event occurrence. Caffeine concentrations in rivers and estuaries draining to the coast ranged from below the reporting limit to 152.2 ng/L. This study establishes the occurrence of caffeine in Oregon's coastal waters, yet relative importance of sources, seasonal variability, and processes affecting caffeine transport into the coastal ocean require further research.     

Partitioning of Cu, Ni, Au, and platinum-group elements between monosulfide solid solution and sulfide melt under controlled oxygen and sulfur fugacities

We have performed six experiments in which we equilibrated monosulfide solid solution (mss) with sulfide melt in evacuated silica capsules containing solid buffers to fix oxygen and sulfur fugacity, at temperatures of 950°C, 1000°C and 1050°C at bulk concentrations of ∼50 ppm for each of the PGE and Au, 5% Ni, and 7% Cu. Concentrations of O, S, Fe, Ni and Cu were determined by electron microprobe, whereas precious metal concentrations were determined by laser-ablation inductively-coupled mass spectrometry. Partition coefficients of all elements studied show minimal dependences on oxygen fugacity from the IW to the QFM buffers when sulfur fugacity is fixed at the Pt-PtS buffer. Cu, Pt, Pd and Au are strongly incompatible and Ru remains moderately to strongly compatible under all conditions studied. At all oxygen fugacities, at the Pt-PtS sulfur buffer, Ir and Rh remain highly compatible in mss. In the single run at both low oxygen and low sulfur fugacity Ir and Rh were found to be strongly incompatible in mss. At QFM and Pt-PtS the partition coefficient for Ni shows weak temperature dependence, ranging from 0.66 at 1050°C to 0.94 at 950°C. At lower oxygen and sulfur fugacity Ni showed much more incompatible behavior. Comparison with the compositions of sulfide ores from the Lindsley deposit of Sudbury suggests that the sulfide magma evolved under conditions close to the QFM and Pt-PtS buffers. The compatible behavior observed for Ni, Ir and Rh at Lindsley and most other magmatic sulfide deposits hosted by mafic rocks requires equilibration of mss and sulfide liquid at moderately high sulfur fugacity and low temperatures near to the solidus of the sulfide magma. We argue that this constraint requires that the sulfide magma must have evolved by equilibrium crystallization, rather than fractional segregation of mss as is commonly supposed.     

Comparing tiltmeters for crustal deformation measurement--a preliminary report

A collection of high-precision tiltmeters is being operated at Pinon Flat Observatory, southern California, both to compare instruments and to measure tectonic deformation. We report on 1.2 years of data from four of these: two Michelson-Gale long fluid tiltmeters, one long center-pressure tiltmeter, and a shallow borehole tiltmeter. The three long-base instruments are all located on the same baseline, with a precise leveling line running between their end-monuments. At nontidal frequencies, only the two Michelson-Gale instruments show some coherence (gamma 2 = .3 for periods of 2 to 4 days), while the center-pressure instrument is correlated with air temperature at periods from a few days to a few weeks. The most stable tilt record shows a secular rate of 0.28 mu rad/a, which may be real. Over much longer times, leveling to specially stabilized bench-marks should confirm this. Comparing instruments has identified more and less successful measurement techniques; it appears that low-noise data will most probably be produced only by relatively complex and expensive instruments, though even for these, the operating costs over any reasonable lifetime will exceed the capital cost. Even the best existing sensors must be improved to measure continuous tectonic motions.     

Trends in Analytical Developments and Earth Science Applications in LA-ICP-MS and LA-MC-ICP-MS for 2004 and 2005

This review of laser ablation-inductively coupled plasma-mass spectrometry includes research that employed quadrupole instruments, and single-collector and multicollector magnetic sector field instruments. The most important trend in 2004–2005 was the growing appreciation that small matrix effects in LA-(MC)-ICP-MS need to be addressed in order to produce highly precise and accurate data by the method. The issue is most acute for isotope ratio measurements that require standard-sample-standard bracketing but can also be important for certain elemental analysis. Matrix-dependent elemental and isotopic fractionations were studied from the standpoint of laser-sample interactions and the behaviour of laser-generated particles in the ablation cell, transfer tubing and ICP torch. Innovations in LA-(MC)-ICP-MS involved signal smoothing, in torch laser ablation, on-line isotope dilution and molecular oxide monitoring. Other important research was carried out on the calibration and homogeneity of various reference materials; and the exploration of mature ( in situ U-Pb geochronology) and emerging (apatite fission-track chronometry, U-Th/He thermochronology, boron/strontium/uranium-series isotopic microanalysis) applications in the Earth sciences.