Conflicting structural and geochronological data from the Ibituruna quartz-syenite (SE Brazil): Effect of protracted “hot” orogeny and slow cooling rate?

The Ibituruna quartz-syenite was emplaced as a sill in the Ribeira-Araçuaí Neoproterozoic belt (Southeastern Brazil) during the last stages of the Gondwana supercontinent amalgamation. We have measured the Anisotropy of Magnetic Susceptibility (AMS) in samples from the Ibituruna sill to unravel its magnetic fabric that is regarded as a proxy for its magmatic fabric. A large magnetic anisotropy, dominantly due to magnetite, and a consistent magnetic fabric have been determined over the entire Ibituruna massif. The magmatic foliation and lineation are strikingly parallel to the solid-state mylonitic foliation and lineation measured in the country-rock. Altogether, these observations suggest that the Ibituruna sill was emplaced during the high temperature (~ 750 °C) regional deformation and was deformed before full solidification coherently with its country-rock. Unexpectedly, geochronological data suggest a rather different conclusion. LA-ICP-MS and SHRIMP ages of zircons from the Ibituruna quartz-syenite are in the range 530–535 Ma and LA-ICP-MS ages of zircons and monazites from synkinematic leucocratic veins in the country-rocks suggest a crystallization at ~ 570–580 Ma, i.e., an HT deformation > 35My older than the emplacement of the Ibituruna quartz-syenite. Conclusions from the structural and the geochronological studies are therefore conflicting. A possible explanation arises from ⁴⁰Ar–³⁹Ar thermochronology. We have dated amphiboles from the quartz-syenite, and amphiboles and biotites from the country-rock. Together with the ages of monazites and zircons in the country-rock, ⁴⁰Ar–³⁹Ar mineral ages suggest a very low cooling rate: < 3 °C/My between 570 and ~ 500 Ma and ~ 5 °C/My between 500 and 460 Ma. Assuming a protracted regional deformation consistent over tens of My, under such stable thermal conditions the fabric and microstructure of deformed rocks may remain almost unchanged even if they underwent and recorded strain pulses separated by long periods of time. This may be a characteristic of slow cooling “hot orogens” that rocks deformed at significantly different periods during the orogeny, but under roughly unchanged temperature conditions, may display almost indiscernible microstructure and fabric.     

Short-term impact of reservoir cleaning on the microhabitat use of three non-salmonid fishes in a piedmont river in south west France

As with many rivers of the Pyrenees Mountains, reservoirs on the River Ariège (SW Francc) are used for hydroelectricity generation, irrigation and to maintain summer flows in the River Garonne. Two river reservoirs on the River Ariège were simultaneously emptied in April 1991 to remove accumulated sediment. Fish and ten environmental variables were sampled using Point Abundance Sampling by electrofishing before (February 1991) and one year later (February 1992) at three study sites downstream of the dams. We examined the short-term impact of reservoir cleaning on the relative abundance, habitat availability and habitat use of three species of small fish: minnow Phoxinus phoxinus (L.), gudgeon Gobio gobio (L.) and stone loach Barbatula barbatula (L.).¶After the reservoir cleaning, areas covered by gravel, sand and mud increased significantly as the result of the sediment release. The three species did not react in the same manner to these environmental changes. Stone loach appeared to be the most sensitive species, with its relative abundance decreasing at all sites. Conversely, minnow seemed to be the most resistant species and as such is a leading pioneer species for colonizing new or impacted stretches of rivers channels. Finally, the number of gudgeon decreased particularly at the most downstream site where large deposits of mud were recorded.     

A thermodynamic model for Fe–Mg dioctahedral K white micas using data from phase-equilibrium experiments and natural pelitic assemblages

The purpose of this study is to derive a solid-solution model for potassic white micas (KWM) encountered in rocks of various bulk compositions, over a wide range of P-T conditions. A compilation of phengite compositions lead us to propose a seven-thermodynamic-component (muscovite, Fe²⁺-Al-celadonite, Mg-Al-celadonite, annite, phlogopite, pyrophyllite and paragonite) ionic solid-solution model which accounts for the Tschermak, Fe-Mg, di/trioctahedral, pyrophyllitic and paragonitic substitutions observed in nature. A four-site mixing model with symmetric Margules parameters to model the Tschermak substitutions, asymmetric Margules parameters to model the other substitutions, and ideal intersite interaction has been adopted. In contrast to previous models, the relevant thermodynamic data and solid-solution properties are calibrated with independent sets of published experiments conducted for the KMASH, KFASH, KFMASH, and KNASH systems, as well as about 200 natural data involving KWM assemblages. The constraints span a wide range of pressure and temperature conditions (150 to 750 °C, 0.5 to 30 kbar), so that our model does not need to be extrapolated outside the calibration range to be used for P-T thermobarometric purposes. The calculated thermodynamic data are interconsistent with the TWQ thermodynamic database and solid-solution models, including that recently published for chlorites.     

P–T–t estimation of deformation in low‐grade quartz‐feldspar‐bearing rocks using thermodynamic modelling and 40Ar/39Ar dating techniques: example of the Plan‐de‐Phasy shear zone unit (Briançonnais Zone,Western Alps)

Pressure–Temperature–time (P–T–t) estimates of the syn‐kinematic strain at the peak‐pressure conditions reached during shallow underthrusting of the Briançonnais Zone in the Alpine subduction zone was made by thermodynamic modelling and ⁴⁰Ar/³⁹Ar dating in the Plan‐de‐Phasy unit (SE of the Pelvoux Massif, Western Alps). The dated phengite minerals crystallized syn‐kinematically in a shear zone indicating top‐to‐the‐N motion. By combining X‐ray mapping with multi‐equilibrium calculations, we estimate the phengite crystallization conditions at 270 ± 50 °C and 8.1 ± 2 kbar at an age of 45.9 ± 1.1 Ma. Combining this P–T–t estimate with data from the literature allows us to constrain the timing and geometry of Alpine continental subduction. We propose that the Briançonnais units were scalped on top of the slab during ongoing continental subduction and exhumed continuously until collision.     

Influence of Random Inclusion of Synthetic Wicks Fibers of Hair on the Behavior of Clayey Soils

Several soil improvement methods are used to enhance the engineering properties of soil, among which, reinforcement by fibers is considered as an effective ground improvement method because of its cost effectiveness, and easy adaptability. The present investigation chooses synthetic wick and vinifera raphia fibers as reinforcement. The synthetic wick fiber was randomly included into the soil at four different percentages i.e. 0, 2, 4, 6% by volume of raw soil. Vinifera raphia fiber was used at one percentage (4%) as control. The main objective of this research is to focus on the strength behavior of clayey soil reinforced with randomly included synthetic wick fiber. The physical and mineralogical characterization was carried out on ten soil samples. The compression, flexion, abrasion, water absorption and capillarity tests were performed on synthetic wick reinforced specimens with various fiber contents. The results of these tests have clearly shown an improvement in the compression strength values from 1.65 to 2.84 MPa for the wicks fibers, and the flexural strength values which varied between 1.08 and 1.96 MPa. Hence, the waste of synthetic wick fibers is therefore an efficient reinforcement for compressed earth blocks, which are very significant for construction of durable and economic infrastructures.     

Wind-Flow Dynamics Over a Vineyard

Wind-flow dynamics has been extensively studied over horizontally uniform canopies, but agricultural plantations structured in rows such as vineyards have received less attention. Here, the wind flow over a vineyard is studied in neutral stratification from both large-eddy simulation (LES) and in situ measurements. The impact of row structure on the wind dynamics is investigated over a range of wind directions from cross-row to down-row, and a typical range of row aspect ratio (row separation/height ratio). It is shown that the mean flow over a vineyard is similar to that observed in uniform canopies, especially for wind directions from cross-row to diagonal. For down-row winds, the mean flow exhibits noticeable spatial variability across each elementary row-gap pattern, as the wind is channeled in the inter-row. This spatial variability increases with the aspect ratio. With down-row winds the turbulent structures are also more intermittent and generate larger turbulent kinetic energy and momentum flux. The displacement height and roughness length of the vineyard vary with the aspect ratio in a way similar to their variation with canopy density in uniform canopies. Both parameters take smaller values in down-row wind flow, for which the canopy appears more open. The analysis of velocity spectra and autocorrelation functions shows that vineyard canopies share similar features to uniform canopies in terms of turbulent coherent structures, with only minor changes with wind direction.     

Calibration and testing of an empirical chloritoid-chlorite Mg-Fe exchange thermometer and thermodynamic data for daphnite

A compilation of literature data on the Fe-Mg composition of coexisting chlorite and chloritoid from metapelites metamorphosed at various P - T  conditions shows that the logarithm of the Fe-Mg partitioning (ln K _D) varies linearly with the inverse of temperature, from about 2.4 at 300  °C to about 1.3 at 600  °C. In contrast, no trend was observed with pressure, and the molar volumes of Mg- and Fe-chlorite end-members suggest that the pressure dependence of ln K _D is not significant. Therefore, the chloritoid-chlorite Mg-Fe exchange reaction is a potential thermometer and has been empirically calibrated using the analyses of 112 chloritoid-chlorite pairs from 28 different localities. Temperatures estimated using the Chl-Cld thermometer were checked against independent estimates for 20 samples not involved in the calibration (Beni Mzala window, Morocco), and the results are in fair agreement with independent temperature estimates. However, the analytical uncertainties and errors are too large to obtain reliable temperature estimates for extremely Mg-rich or Fe-rich compositions. The Chl-Cld thermometer is unreliable at XMg-_CLD<0.2 and XMg-_CLD>0.8 at 700  °C, and XMg-_CLD<0.1 and XMg-_CLD>0.9 at 300  °C. Using the results of the empirical calibration, we calculated new thermodynamic data for daphnite. Implementing these data, it becomes possible to estimate T  and P conditions of metamorphism for the invariant chlorite-chloritoid-quartz-aluminosilicate assemblage that is widespread in low-grade metapelites. These estimates appear to be relevant only in the stability field of kyanite, whereas the uncertainties on the calculated pressure conditions are very large in the stability field of kaolinite and pyrophyllite.     

Ecohydrological modelling with EcH2O‐iso to quantify forest and grassland effects on water partitioning and flux ages

We used the new process‐based, tracer‐aided ecohydrological model EcH₂O‐iso to assess the effects of vegetation cover on water balance partitioning and associated flux ages under temperate deciduous beech forest (F) and grassland (G) at an intensively monitored site in Northern Germany. Unique, multicriteria calibration, based on measured components of energy balance, hydrological function and biomass accumulation, resulted in good simulations reproducing measured soil surface temperatures, soil water content, transpiration, and biomass production. Model results showed the forest “used” more water than the grassland; of 620 mm average annual precipitation, losses were higher through interception (29% under F, 16% for G) and combined soil evaporation and transpiration (59% F, 47% G). Consequently, groundwater (GW) recharge was enhanced under grassland at 37% (~225 mm) of precipitation compared with 12% (~73 mm) for forest. The model tracked the ages of water in different storage compartments and associated fluxes. In shallow soil horizons, the average ages of soil water fluxes and evaporation were similar in both plots (~1.5 months), though transpiration and GW recharge were older under forest (~6 months compared with ~3 months for transpiration, and ~12 months compared with ~10 months for GW). Flux tracking using measured chloride data as a conservative tracer provided independent support for the modelling results, though highlighted effects of uncertainties in forest partitioning of evaporation and transpiration. By tracking storage—flux—age interactions under different land covers, EcH₂O‐iso could quantify the effects of vegetation on water partitioning and age distributions. Given the likelihood of drier, warmer summers, such models can help assess the implications of land use for water resource availability to inform debates over building landscape resilience to climate change. Better conceptualization of soil water mixing processes and improved calibration data on leaf area index and root distribution appear obvious respective modelling and data needs for improved simulations.