Dehydration of dioctahedral aluminous phyllosilicates: thermodynamic modelling and implications for thermobarometric estimates

We propose a solid-solution model for dioctahedral aluminous phyllosilicates accounting for the main compositional variations, including hydration, observed in natural smectites, interlayered illite/smectite, illites, and phengites from diagenetic to high-grade metamorphic conditions. The suggested formalism involves dehydrated micas and hydrated pyrophyllite-like thermodynamic end-members. With these end-members, the equilibrium conditions of quartz + water + K-bearing mica-like phyllosilicates of fixed 2:1 composition are represented by a line in P–T space along which the interlayer water content varies. The relevant thermodynamic properties required for the calculation of equilibrium conditions were derived using a set of 250 natural data of known maximal temperature and pressure conditions, which covers a range between 25°C and few MPa to 800°C and 5 GPa. The temperatures calculated at fixed pressure with our model are in fair agreement with those reported in the literature for the 250 natural data. At low temperature and pressure, the amount of interlayer water in K-deficient phengite and illite is predicted to reach 100% of the apparent vacancies, which is consistent with previous values reported in the literature. Although the amount of interlayer water is predicted to decrease with pressure and temperature, it is calculated to be significant in K-deficient phengite from LT–HP pelites metamorphosed at about 350°C, 10 kbar. The presence of molecular water in the interlayer site of such phengites has been confirmed by FTIR mapping. Its implications for P–T estimates are discussed.     

Turbulent Structures in a Pine Forest with a Deep and Sparse Trunk Space: Stand and Edge Regions

Forested landscapes often exhibit large spatial variability in vertical and horizontal foliage distributions. This variability may affect canopy-atmosphere exchanges through its action on the development of turbulent structures. Here we investigate in neutral stratification the turbulent structures encountered in a maritime pine forest characterized by a high, dense foliated layer associated with a deep and sparse trunk space. Both stand and edge regions are considered. In situ measurements and the results of large-eddy simulations are used and analyzed together. In stand conditions, far from the edge, canopy-top structures appear strongly damped by the dense crown layer. Turbulent wind fluctuations within the trunk space, where the momentum flux vanishes, are closely related to these canopy-top structures through pressure diffusion. Consequently, autocorrelation and spectral analyses are not quite appropriate to characterize the vertical scale of coherent structures in this type of canopy, as pressure diffusion enhances the actual scale of structures. At frequencies higher than those associated with canopy-top structures, wind fluctuations related to wake structures developing behind tree stems are observed within the trunk space. They manifest themselves in wind velocity spectra as secondary peaks in the inertial subrange region, confirming the hypothesis of spectral short-cuts in vegetation canopies. In the edge region specific turbulent structures develop just below the crown layer, in addition to canopy-top structures. They are generated by the wind shear induced by the sub-canopy wind jet that forms at the edge. These structures provide a momentum exchange mechanism similar to that observed at the canopy top but in the opposite direction and with a lower magnitude. They may develop as in plane mixing-layer flows, with some perturbations induced by canopy-top structures. Wake structures are also observed within the trunk space in the edge region.     

西昆仑山北部早古生代构造－岩浆带的发现

1987年以来,先后做了4条横穿昆仑山的综合路线地质调查。它们是:中-巴公路沿线;新-藏公路沿线;于田县普鲁村-苏巴什-硫磺达坂路线;青海茫崖镇-祁曼塔格路线。在西昆仑山北部的调查区内,都有钙-碱性的深成岩体出露。通过对这些岩体系统地做U-Pb、Ar-Ar及Rb-Sr定年研究,发现它们具有早古生代年龄(384-480Ma),延伸上千公里,形成于活动大陆边缘或碰撞后的构造环境,常与属于蛇绿岩套的组分相伴生。这充分说明在青藏高原内部存在一条新发现的缝合带。