himu-em: The French Polynesian connection

himu, em i andem ii are three of the main geochemical mantle components that give rise to oceanic island basalts [1]. They represent the end members that produce the extreme isotopic compositions measured on intraplate volcanics. In French Polynesia, all three mantle components are represented in volcanic rocks. The characteristichimu signature is found in Tubuai, Mangaia and Rurutu,em i is present in the source of Rarotonga and Pitcairn volcanics andem ii dominates the composition of most Society Islands. Intermediate values between the three end members are found on most islands.We suggest that the three components are not independent but are physically related in the mantle. Thehimu component is thought to be recycled oceanic crust that lost part of its Pb through hydrothermal processes prior to and during subduction.em i andem ii are believed to acquire their isotopic and trace element characteristics through entrainment of sediments that were subducted together with the oceanic crust.The trace element pattern and the isotopic composition ofhimu lavas can be quantitatively modelled using a mixture of 25% old recycledmorb crust and 75% mantle peridotite. The extreme Pb composition is modelled assuming that Pb was lost from oceanic crust when hydrothermal alteration at the ridge leached Pb from the basalt to redeposit it as sulphides on top of and throughout the crust, followed by preferential dissolution of sulphides during dehydration in the subduction zone. These processes led to a drastic increase of theU/Pb ratio of the subducted material which evolved over 2 Ga to very radiogenic Pb isotopic compositions. Pb isotopic compositions similar to those ofem i andem ii are modelled assuming that sediments with average crustal Pb isotopic compositions were subducted and recycled into the mantle together with the underlyingmorb oceanic crust. Pelagic sediments (μ 5 andκ 6) account for the Pb isotopic composition ofem i whereas terrigenous sediments (μ 10 andκ 4.5) evolve towards theem ii end member. A few percent of sediment in the recycled crust-sediment mixture will destroy the characteristic Pb isotopic signature of thehimu component. This, together with the low probability of isolating oceanic crust in the mantle for 2 Ga, explains why the extremehimu composition, as seen on Tubuai and St Helena, is sampled so rarely by oceanic volcanism.     

Dating of granulites involved in the hercynian fold-belt of Europe: An example taken from the granulite-facies orthogneisses at La Picherais,Southern Armorican Massif,France

Situated within the crystalline metamorphic complex of Champtoceaux NE of Nantes, the orthogneiss of La Picherais (near St Mars-du-Désert, Loire Atlantique, France) show relicts of a granulite facies paragenesis. Comparison with other granulitic rocks in the Hercynian fold-belt suggest possible ages ranging from Lower Proterozoic to Phanerozoic. The Rb-Sr whole rock method yields an errorchron of 570±110 m.y. for the Picherais orthogneiss, whereas the U-Pb zircon method indicates an upper intersection on Concordia at 1,880±120 m.y. and a lower intersection at 423±10 m.y. Several interpretations are possible for these data: the granite emplacement age was (1) 1,900 m.y. ago. (2) more likely Upper Proterozoic — Lower Palaeozoic. The zircons concordant at 1,900 m.y. were either present in the granitic magma at its time of origin or were introduced into the magma during emplacement. These zircons could be derived from sedimentary horizons such as found in the Lower Ordovician sandstones of the Armorican massif whose zircon age data are presented here.     

Dynamics of a particle in a gravitational field of a homogeneous annulus disk

We formulate the problem of an infinitesimal particle moving in the space under the influence of the gravitational force induced by a homogeneous annulus disk fixed on a plane. We compute using different coordinates and in terms of an elliptic integral the potential associated to this problem. Also we study the symmetries of the associated potential. After that, we look at the dynamics in some particular cases, namely: in the line perpendicular to the plane that contains the annulus disk and passes through the center of the ring and on the plane that contains the massive annulus.      

Accelerating the convergence of coupled geomechanical‐reservoir simulations

The pressure variations during the production of petroleum reservoir induce stress changes in and around the reservoir. Such changes of the stress state can induce marked deformation of geological structures for stress sensitive reservoirs as chalk or unconsolidated sand reservoirs. The compaction of those reservoirs during depletion affects the pressure field and so the reservoir productivity. Therefore, the evaluation of the geomechanical effects requires to solve in a coupling way the geomechanical problem and the reservoir multiphase fluid flow problem. In this paper, we formulate the coupled geomechanical‐reservoir problem as a non‐linear fixed point problem and improve the resolution of the coupling problem by comparing in terms of robustness and convergence different algorithms. We study two accelerated algorithms which are much more robust and faster than the conventional staggered algorithm and we conclude that they should be used for the iterative resolution of coupled reservoir‐geomechanical problem. Copyright © 2006 John Wiley & Sons, Ltd.     

Exsolution and shock microstructures of igneous pyroxene clasts in the Northwest Africa 7533 Martian meteorite

Northwest Africa (NWA) 7533 is a Martian regolith breccia. This meteorite (and its pairings) offers a good opportunity to study (near‐) surface processes that occurred on early Mars. Here, we have conducted a transmission electron microscope study of medium‐ and coarse‐grained (a few tens to hundreds of micrometers) Ca‐rich pyroxene clasts in order to define their thermal and shock histories. The pyroxene grains have a high‐temperature (magmatic) origin as revealed by the well‐developed pigeonite–augite exsolution microstructure. Exsolution lamella characteristics (composition, thickness, and spacing) indicate a moderately slow cooling. Some of the pyroxene clasts display evidence for local decomposition into magnetite and silica at the submicron scale. This phase decomposition may have occurred at high temperature and occurred at high oxygen fugacity at least 2–3 log units above the QFM buffer, after the formation of the exsolution lamellae. This corresponds to oxidizing conditions well above typical Martian magmatic conditions. These oxidizing conditions seem to have prevailed early and throughout most of the history of NWA 7533. The shock microstructure consists of (100) mechanical twins which have accommodated plastic deformation. Other pyroxene shock indicators are absent. Compared with SNC meteorites that all suffered significant shock metamorphism, NWA 7533 appears only mildly shocked. The twin microstructure is similar from one clast to another, suggesting that the impact which generated the (100) twins involved the compacted breccia and that the pyroxene clasts were unshocked when they were incorporated into the NWA 7533 breccia.     

Limnology of Morton dam and upper Karori reservoir,Wellington, New Zealand

Chemical and biological data were collected between 1947 and 1967 from Morton Dam and Upper Karori Reservoir, two artificial lakes which are part of the water supply of Wellington City, New Zealand.

Chemical analyses included the major ions, nutrients, and physical and chemical properties of engineering importance. The emphasis in biological analyses was on the dominant phytoplankters. Bacteriological results are presented as tables of plate counts and “most probable numbers” of confirmed faecal coli‐forms; iron‐fixing bacteria were identified.

Primary productivity has accelerated since 1940–42: annual maxima have increased 30‐fold at Morton Dam, and 10‐fold in Upper Karori Reservoir. In 1942, Morton Dam was believed to be oligotrophic, but the type and quantity of phytoplankton at present indicate a rapid progression to eutrophy.

Despite the extent of biological changes, no dramatic changes in the physical and chemical characteristics of either reservoir can be detected.     

Lanthanide sorption on smectitic clays in presence of cement leachates

Due to their potential retention capacity, clay minerals have been proposed for use in the engineered barriers for the storage of high-level radioactive actinides in deep geological waste repositories. However, there is still a lack of data on the sorption of actinides in clays in conditions simulating those of the repositories. The present article examines the sorption of two lanthanides (actinide analogues) in a set of smectitic clays (FEBEX bentonite, MX80 bentonite, hectorite, saponite, Otay montmorillonite, and Texas montmorillonite). Distribution coefficients (K_d) were determined in two media: water and 0.02 mol L⁻¹ Ca, the latter representing the cement leachates that may modify the chemical composition of the water in contact with the clay. The K_d values of the lanthanides used in the experiments (La and Lu) varied greatly (25-50 000 L kg⁻¹) depending on the ionic medium (higher values in water than in the Ca medium), the initial lanthanide concentration (up to three orders of magnitude decrease inversely with lanthanide concentration), and the examined clay (up to one order of magnitude for the same lanthanide and sorption medium). Freundlich and Langmuir isotherms were used to fit sorption data to allow comparison of the sorption parameters among smectites. The model based on the two-site Langmuir isotherms provided the best fit of the sorption data, confirming the existence of sorption sites with different binding energies. The sites with higher sorption affinity were about 6% of the total sorption capacity in the water medium, and up to 17% in the Ca medium, although in this latter site sorption selectivity was lower. The wide range of K_d values obtained regarding the factors examined indicated that the retention properties of the clays should also be considered when selecting a suitable clay for engineered barriers.     

Accuracy and efficiency of time integration methods for 1D diffusive wave equation

The diffusive wave approximation of the Saint-Venant equations is commonly used in hydrological models to describe surface flow processes. Numerous numerical approaches can be used to solve this highly nonlinear equation. Nonlinear time integration schemes—also called methods of lines (MOL)—were proven very efficient to solve other nonlinear problems in geosciences but were never considered to deal with surface flow modeling with the diffusive wave equation. In this paper, we study the relative performance of different time and space integration schemes by comparing the results obtained with classical approaches and with nonlinear time integration approaches. The results show that (i) the integration method with a higher order in space shows high accuracy regarding an integrated indicator such as the global mass balance error but is less accurate regarding local indicators, and (ii) nonlinear time integration techniques perform better than classical ones. Overall, it seems that integration techniques combining nonlinear time integration and a low spatial order need to be considered when developing hydrological modeling tools owing to their simplicity of implementation and very good performance.     

Machine Learning Feature Selection Methods for Landslide Susceptibility Mapping

This paper explores the use of adaptive support vector machines, random forests and AdaBoost for landslide susceptibility mapping in three separated regions of Canton Vaud, Switzerland, based on a set of geological, hydrological and morphological features. The feature selection properties of the three algorithms are studied to analyze the relevance of features in controlling the spatial distribution of landslides. The elimination of irrelevant features gives simpler, lower dimensional models while keeping the classification performance high. An object-based sampling procedure is considered to reduce the spatial autocorrelation of data and to estimate more reliably generalization skills when applying the model to predict the occurrence of new unknown landslides. The accuracy of the models, the relevance of features and the quality of landslide susceptibility maps were found to be high in the regions characterized by shallow landslides and low in the ones with deep-seated landslides. Despite providing similar skill, random forests and AdaBoost were found to be more efficient in performing feature selection than adaptive support vector machines. The results of this study reveal the strengths of the classification algorithms, but evidence: (1) the need for relying on more than one method for the identification of relevant variables; (2) the weakness of the adaptive scaling algorithm when used with landslide data; and (3) the lack of additional features which characterize the spatial distribution of deep-seated landslides.     

Geology and activity around volcanoes on Io from the analysis of NIMS spectral images

The last two successful flybys of Io by Galileo in 2001 (orbits I31, I32) allowed the Near Infrared Mapping Spectrometer to enrich its collection of IR spectral image cubes of the satellite. These data cover hemispheric portions of Io, several volcanic centers as well as their surroundings with a spatial resolution ranging from 2 to 93 km pixel⁻¹. They map thermal emission from the hot-spots and the distribution of solid SO₂ in the 1.0-4.7 μm spectral range. We obtain maps of SO₂ abundance and granularity from the NIMS data using the method of Douté et al. (2002, Icarus 158, 460-482). The maps are correlated to distinguish four different physical units that indicate zones of SO₂ condensation, metamorphism and sublimation. We relate these information with visible images from Galileo's Solid State Imaging System and with detailed mapping of the thermal emission produced by Io's surface. Our principal goal is to understand the mechanisms controlling how lava, pyroclastics and gas are emitted by different types of volcanoes and how these products evolve. The 800 km diameter white ring of fallout created by a violent “Pillanian” eruption during summer of 2001 is at least partly composed of solid SO₂ and has enriched preexisting regional deposits. Orange materials have been recently or are currently emplaced 240 km south from the main eruption site, possibly as sulfur flows. A similar event may have taken place in the past at Ababinili Patera (12.5° N, 142° W). Carefull study of SO₂ maps covering the Emakong region also suggests that sulfur forms the bright channel-fed flow emerging from the south eastern side of the caldera. Within the main caldera of Tvashtar Catena completely cooled patches of crust exist. Elsewhere, the caldera is still cooling from previous episodes of flooding. We confirm that Amirani emits constantly large amount of SO₂ gas by interaction of fresh lava with the volatiles of the underlying plains. Nevertheless SO₂ frost is not the major component of the bright white ring seen in the SSI images. Over the whole Gish Bar region, SO₂ frost seems barely stable and is constantly regenerated. The stability increases along gray filamentary structures which could be faults filled with materials having peculiar thermal properties. Northwest of Gish Bar Patera, a localized bright deposit shows an unusual spectral signature potentially indicative of H₂O molecules forming ice crystals or being trapped in a nonidentified matrix. The Chaac region may present a thickened old crust reducing the geothermal flux to levels lower than 0.5 W m⁻² and thus creating a cold trap for SO₂. Looking at the abundance and degree of metamorphose of SO₂, we establish the relative age of different flows and ejecta for the Sobo Fluctus. Finally the assumption that the white patches in visible images indicate SO₂ rich deposits is once again challenged. In the Camaxtli region we identify a topographically controlled compact white deposit showing only moderate SO₂ abundance. In contrast, we detect two spots of quite pure SO₂ ice on the gray flanks of Emakong. Furthermore, the close association of fumarolic SO₂ and red S₂ already noted for several volcanic centers is observed at Tupan.