Simple and multiple regression models for relationship between electrical resistivity and various soil properties for soil characterization

Precise determination of engineering properties of soil is essential for proper design and successful construction of any structure. The conventional methods for determination of engineering properties are invasive, costly and time-consuming. Electrical resistivity survey is an attractive tool for delineate subsurface properties without soil disturbance. Reliable correlations between electrical resistivity and other soil properties will enable us to characterize the subsurface soil without borehole sampling. This paper presents the correlations of electrical resistivity with various properties of soil. Soil investigations, field electrical resistivity survey and laboratory electrical resistivity measurements were conducted. The results from electrical resistivity tests (field and laboratory) and laboratory tests were analyzed together to understand the interrelation between electrical resistivity and various soil properties. The test results were evaluated using simple and multiple regression analysis. From the data analysis, significant quantitative and qualitative correlations have been obtained between resistivity and moisture content, friction angle and plasticity index. Weaker correlations have been observed for cohesion, unit weight of soil and effective size (D ₁₀).     

Assessment of Trace Metal Contamination of Drinking Water in the Pearl Valley,Azad Jammu and Kashmir

The aim of this study was to assess trace metal contamination of drinking water in the Pearl Valley, Azad Jammu and Kashmir (Pakistan). The objectives were to determine physical properties and the dissolved concentration of five trace metals, i. e., lead, copper, nickel, zinc, and manganese, in drinking water samples collected from various sites of municipal water supply, natural water springs and wells in the valley. Concentrations of the metals in the water samples were determined by flame atomic absorption spectrometry. Results showed physical parameters, i. e., appearance, taste and odor within acceptable limits and pH was between 5.5 and 7.0. The observed concentrations of the metals varied between sources of water samples and between sampling sites. Maximum dissolved concentration observed was 4.7 mg/L for Pb and Mn, 4.6 mg/L for Zn, 2.9 mg/L for Ni and 2.8 mg/L for Cu. The observed concentrations of the metals were compared with the World Health Organization's guideline values for drinking water. Overall, the quality of water samples taken from the water springs at Mutyal Mara and Bonjosa was good; however, the water quality was unsuitable for drinking in Kiraki, Kharick, and Pothi Bala localities particularly. Finally, the authors discuss possible causes for increased concentrations of the trace metals in drinking water in the study area.     

Competitive Sorption of Antimony with Zinc,Nickel, and Aluminum in a Seaweed Based Fixed‐bed Sorption Column

The removal of heavy metals such as Ni(II), Zn(II), Al(III), and Sb(III) from aqueous metal solutions was investigated using novel, cost effective, seaweed derived sorbents. Studies with a laboratory scale fixed‐bed sorption column, using a seaweed waste material (referred to as waste Ascophyllum product (WAP)) from the processing of Ascophyllum nodosum as biosorbent, demonstrated high removal efficiencies (RE) for a variety of heavy metals including Ni(II), Zn(II) and Al(III), with 90, 90 and 74% RE achieved from initial 10 mg/L metal solutions, respectively. The presence of Sb(III) in multi component metal solutions suppressed the removal of Ni(II), Zn(II) and Al(III), reducing the RE to 28, 17 and 24%, respectively. The use of Polysiphonia lanosa as a biosorbent showed a 67% RE for Sb(III), both alone and in combination with other metals. Potentiometric and conductometric titrations, X‐ray photoelectron and mid‐infrared spectroscopic analysis demonstrated that carboxyl, alcohol, sulfonate and ether groups were heavily involved in Sb(III) binding by P. lanosa. Only carboxyl and sulfonate groups were involved in Sb(III) binding by WAP. Furthermore, a greater amount of weak acidic groups (mainly carboxylic functions) were involved in Sb(III) binding by P. lanosa, compared to WAP which involved a greater concentration of strong acidic groups (mainly sulfonates).     

Balance characteristics of multivariate background error covariances and their impact on analyses and forecasts in tropical and Arctic regions

For variational data assimilation, the background error covariance matrix plays a crucial role because it is strongly linked with the local meteorological features, and is especially dominated by error correlations between different analysis variables. Multivariate background error (MBE) statistics have been generated for two regions, namely the Tropics (covering Indonesia and its neighborhood) and the Arctic (covering high latitudes). Detailed investigation has been carried out for these MBE statistics to understand the physical processes leading to the balance (defined by the forecasts error correlations) characteristics between mass and wind fields for the low and high latitudes represented by these two regions. It is found that in tropical regions, the unbalanced (full balanced) part of the velocity potential (divergent part of wind) contributes more to the balanced part of the temperature, relative humidity, and surface pressure fields as compared with the stream function (rotational part of wind). However, the exact opposite happens in the Arctic. For both regions, the unbalanced part of the temperature field is the main contributor to the balanced part of the relative humidity field. Results of single observation tests and six-hourly data assimilation cycling experiments are consistent with the respective balance part contributions of different fields in the two regions. This study provides an understanding of the contrasting dynamical balance relationship that exists between the mass and wind fields in high- and low-latitude regions. The study also examines the impact of MBE on Weather Research and Forecasting model forecasts for the two regions.     

Geology and Genesis of Barite Deposits of Lasbela and Khuzdar Districts, Balochistan, Pakistan

Abstract: Geology and genesis of the sediment-hosted barite deposits in the Lasbela and Khuzdar districts of Balochistan, Pakistan have been studied and described. Hot solutions generated in rifting environments during the initial stage of separation of the continental crustal block related to the Gondwanaland fragmentation subsequently reposed in Jurassic rocks, most probably played an important role on barite formation.
Paragenetic relationships indicate that the period of barite mineralization was distinctly later than that of zinc-lead sulphide mineralization in the Lasbela and Khuzdar districts. The barite deposits occur on top and in peripheral to the zinc-lead sulphides. The earliest barite mineralization took place in the clastic rock sequence of the lower Spingwar Formation as cross cutting veins. Younger mineralization as stratabound-replacement type occurred within the platform limestones of Loralai Formation, just above the Spingwar Formation. The youngest mineralization as stratiform is hosted within black shales, mudstones and argillaceous limestones of Anjira Formation at the top of Loralai Formation. In the light of the evidences gathered from field and laboratory investigations a genetic model has been deduced.     

A comprehensive study on the surface chemistry of particulate matter collected from Jeddah,Saudi Arabia

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.     

Characterization of carbon monoxide,methane and nonmethane hydrocarbons in emerging cities of Saudi Arabia and Pakistan and in Singapore

We investigate the composition of 63 C₂-C₁₀ nonmethane hydrocarbons (NMHCs), methane (CH₄) and carbon monoxide (CO), in Jeddah, Mecca, and Madina (Saudi Arabia), in Lahore, (Pakistan), and in Singapore. We established a database with which to compare and contrast NMHCs in regions where ambient levels and emissions are poorly characterized, but where conditions are favorable to the formation of tropospheric ozone, and where measurements are essential for improving emission inventories and modeling. This dataset will also serve as a base for further analysis of air pollution in Western Saudi Arabia including, but not limited to, the estimation of urban emissions and long range pollution transport from these regions. The measured species showed enhanced levels in all Saudi Arabian cities compared to the local background but were generally much lower than in Lahore. In Madina, vehicle exhaust was the dominant NMHC source, as indicated by enhanced levels of combustion products and by the good correlation between NMHCs and CO, while in Jeddah and Mecca a combination of sources needs to be considered. Very high NMHC levels were measured in Lahore, and elevated levels of CH₄ in Lahore were attributed to natural gas. When we compared our results with 2010 emissions from the MACCity global inventory, we found discrepancies in the relative contribution of NMHCs between the measurements and the inventory. In all cities, alkenes (especially ethene and propene) dominated the hydroxyl radical (OH) reactivity (k _OH) because of their great abundance and their relatively fast reaction rates with OH.     

Production and Emissions of Atomic Carbon and Oxygen in the Inner Coma of Comet Halley: Role of Electron Impact

A coupled chemistry–transport model is developed to study the production and loss of neutral atomic carbon and oxygen in the inner coma (≤10⁴km) of Comet Halley. Subsequently, the generation of OI 1304 Å and OI 1356 Å and CI 1561 Å and CI 1657 Å emissions is studied. Calculations are performed utilizing solar EUV, utilizing photoelectrons, and assuming the precipitation of high energy “auroral” electrons of solar wind origin, the evidence for which has been inferred from many observations, as the sources for the production of these atoms and emissions, including only the gas phase species in the cometary coma. It is revealed that the electron impact dissociation of parent species could be a potentially important source of C and O production and their emissions in the inner cometary coma. Our calculated O density profile is in agreement with that calculated by R. R. Hodges, Jr. (1990,Icarus83, 410–433). The present study has demonstrated the importance of contributions from sources other than the solar fluorescence for deriving the O and C production rates from their emission line brightness. It is found that the electron impact and solar fluorescence contribute 34 and 66%, respectively, to the OI 1304 Å emission. However, when the auroral electrons are also included, the relative contributions of electron impact and solar fluorescence are 72 and 28%, respectively. In the case of CI 1657 Å the electron impact contribution amounts to 24 (18)% with (without) inclusion of auroral electrons.     

Statistical analysis of different chemical elements in groundwater of northwestern Saudi Arabia

A total of 72 water samples were collected from the sub-surface aquifer system in the Midyan basin and analyzed for 24 major, minor and trace elements. Histograms and normal quantile plots were used to delineate the sub-populations of the chemical constituents in the studied groundwater samples. Some of the elements such as Al, K, Ca, Mg, Na and Cl have concentrations that could be linked to the weathering of the surface rock strata. On the other hand, the elements like As, Pb and Sb have concentration, that can be linked to agricultural practices in the area. The use of simple statistical analysis, frequency histograms, and Q-Q plots were useful for the detection and evaluation of elemental constituents in the groundwater of the study area.