Why the <Emphasis Type="Italic">Euler</Emphasis> scheme in particle tracking is not enough: the shallow-sea pycnocline test case

During the last decades, the Euler scheme was the common “workhorse” in particle tracking, although it is the lowest-order approximation of the underlying stochastic differential equation. To convince the modelling community of the need for better methods, we have constructed a new test case that will show the shortcomings of the Euler scheme. We use an idealised shallow-water diffusivity profile that mimics the presence of a sharp pycnocline and thus a quasi-impermeable barrier to vertical diffusion. In this context, we study the transport of passive particles with or without negative buoyancy. A semi-analytic solutions is used to assess the performance of various numerical particle-tracking schemes (first- and second-order accuracy), to treat the variations in the diffusivity profile properly. We show that the commonly used Euler scheme exhibits a poor performance and that widely used particle-tracking codes shall be updated to either the Milstein scheme or second-order schemes. It is further seen that the order of convergence is not the only relevant factor, the absolute value of the error also is.     

Ionic Liquid Modified Resin for the Adsorptive Removal of Dibutyl Phthalate: Equilibrium,Kinetic, and Thermodynamic Studies

This study evaluated the adsorptive properties of dibutyl phthalate (DBP) on room temperature ionic liquid (RTIL) modified XAD‐4 resin. The modified RTIL‐XAD 4 sorbent was characterized by FTIR. Effect of varying experimental conditions such as pH, contact time, temperature, shaking speed, concentrations, and interfering species were investigated by batch adsorption experiments. Adsorption was found to be most favorable at pH 6 within 30 min. Experimental data were evaluated in terms of kinetic, equilibrium, and thermodynamic modeling. Kinetics of the sorption was found to follow pseudo second order rate equation whereas Freundlich and D–R isotherms were the most suitable models to explain sorption phenomenon. Thermodynamically sorption was endothermic, irreversible, and spontaneous in nature.     

Episodic Performance and Sensitivity of the Urbanized MM5 (uMM5) to Perturbations in Surface Properties in Houston Texas

We present an application of a fine-resolution, meso-urban meteorological model (urbanized MM5; uMM5) to a multi-day episode in August 2000 in the Houston-Galveston Texas, USA region. The model’s episodic performance and its response to small changes in land-cover and surface physical properties in the area, e.g., scenarios of urban heat island mitigation, are evaluated. The model formulation is reviewed along with its parameterizations, data needs, and fine-resolution geometrical input. Development of scenarios of increased urban albedo and vegetative cover is also discussed. This initial application of the uMM5 to the Houston-Galveston region serves as a basis for future model improvements, evaluation of newer data and parameterization applications, testing more aggressive surface modification scenarios, and performing fine-resolution photochemical modelling. It also provides data for comparison of model results with those from previous studies of this region.     

Role of organic matter in uranium mineralisation in Vempalle dolostone; Cuddapah basin,India

Dolostone of Vempalle Formation near Tummalapalle hosts large uranium deposit (>100,000 tonnes with an average grade of 0.045%U₃O₈). It is a unique type of uranium deposit because carbonate formations have been considered to be among the least uraniferous of all the rocks of the Earth’s crust due to mobility of uranium in aqueous fluid in the presence of carbonate and bicarbonate ions. Vempalle dolostone hosts syn-sedimentary uranium mineralization in the form of discrete uranium phases (pitchblende and coffinite) associated with collophane, and adsorbed uranium in organic matter. The organic matter has played dual role of concentrating uranium from solution and also chemically reducing it to pitchhblende and coffinite.     

On the fog variability over south Asia

An increasing trend in fog frequencies over south Asia during winter in the last few decades has resulted in large economical losses and has caused substantial difficulties in the daily lives of people. In order to better understand the fog phenomenon, we investigated the climatology, inter-annual variability and trends in the fog occurrence from 1976 to 2010 using observational data from 82 stations, well distributed over India and Pakistan. Fog blankets large area from Pakistan to Bangladesh across north India from west to east running almost parallel to south of the Himalayas. An EOF analysis revealed that the fog variability over the whole region is coupled and therefore must be governed by some large scale phenomenon on the inter-annual time scale. Significant positive trends were found in the fog frequency but this increase is not gradual, as with the humidity, but comprises of two distinct regimes shifts, in 1990 and 1998, with respect to both mean and variance. The fog is also detected in ERA-Interim 3 hourly, surface and model level forecast data when using the concept of “cross-over temperature” combined with boundary layer stability. This fog index is able to reproduce the regime shift around 1998 and shows that the method can be applied to analyze fog over south Asia. The inter-annual variability seems to be associated with the wave train originating from the North Atlantic in the upper troposphere that when causing higher pressure over the region results in an increased boundary layer stability and surface-near relative humidity. The trend and shifts in the fog occurrence seems to be associated with the gradual increasing trend in relative humidity from 1990 onwards.     

Study of the global and regional climatic impacts of ENSO magnitude using SPEEDY AGCM

ENSO is considered as a strong atmospheric teleconnection that has pronounced global and regional circulation effects. It modifies global monsoon system, especially, Asian and African monsoons. Previous studies suggest that both the frequency and magnitude of ENSO events have increased over the last few decades resulting in a need to study climatic impacts of ENSO magnitude both at global and regional scales. Hence, to better understand the impact of ENSO amplitude over the tropical and extratropical regions focussing on the Asian and African domains, ENSO sensitivity experiments are conducted using ICTPAGCM (‘SPEEDY’). It is anticipated that the tropical Pacific SST forcing will be enough to produce ENSO-induced teleconnection patterns; therefore, the model is forced using NINO3.4 regressed SST anomalies over the tropical Pacific only. SPEEDY reproduces the impact of ENSO over the Pacific, North and South America and African regions very well. However, it underestimates ENSO teleconnection patterns and associated changes over South Asia, particularly in the Indian region, which suggests that the tropical Pacific SST forcing is not sufficient to represent ENSO-induced teleconnection patterns over South Asia. Therefore, SST forcing over the tropical Indian Ocean together with air–sea coupling is also required for better representation of ENSO-induced changes in these regions. Moreover, results obtained by this pacemaker experiment show that ENSO impacts are relatively stronger over the Inter-Tropical Convergence Zone (ITCZ) compared to extratropics and high latitude regions. The positive phase of ENSO causes weakening in rainfall activity over African tropical rain belt, parts of South and Southeast Asia, whereas, the La Niña phase produces more rain over these regions during the summer season. Model results further reveal that ENSO magnitude has a stronger impact over African Sahel and South Asia, especially over the Indian region because of its significant impact over the tropical Atlantic and the Indian Ocean through Walker circulation. ENSO-induced negative (positive) NAO-like response and associated changes over Southern Europe and North Africa get significantly strong following increased intensity of El Niño (La Niña) in the northern (southern) hemisphere in the boreal winter (summer) season. We further find that ENSO magnitude significantly impacts Hadley and Walker circulations. The positive phase of ENSO (El Niño) overall strengthens Hadley cell and a reverse is true for the La Niña phase. ENSO-induced strengthening and weakening of Hadley cell induces significant impact over South Asian and African ITCZ convective regions through modification of ITCZ/monsoon circulation system.     

Satellite-based rainfall estimation and discharge measurement of Middle Indus River,Pakistan

The impacts of floods and droughts are intensified by climate change, lack of preparedness, and coordination. The average rainfall in study area is ranging from 200 to 400 mm per year. Rain gauge generally provides very accurate measurement of point rain rates and the amounts of rainfall but due to scarcity of the gauge locations provides very general information of the area on regional scale. Recognizing these practical limitations, it is essential to use remote sensing techniques for measuring the quantity of rainfall in the Middle Indus. In this research, Tropical Rainfall Measuring Mission (TRMM) estimation can be used as a proxy for the magnitude of rainfall estimates from classical methods (rain gauge), quantity, and its spatial distribution for Middle Indus river basin. In order to use TRMM satellite data for discharge measurement, its accuracy is determined by statistically comparing it with in situ gauged data on daily and monthly bases. The daily R ² value (0.42) is significantly lower than monthly R ² value (0.82), probably due to the time of summation of TRMM 3-hourly precipitation data into daily estimates. Daily TRMM data from 2003 to 2012 was used as input forcing in Soil and Water Assessment Tool (SWAT) hydrological model along with other input parameters. The calibration and validation results of SWAT model give R ² = 0.72 and 0.73 and Nash-Sutcliffe coefficient of efficiency = 0.69 and 0.65, respectively. Daily and monthly comparison graphs are generated on the basis of model discharge output and observed data.     

Fishery stock assessment of Kiddi shrimp (Parapenaeopsis stylifera) in the Northern Arabian Sea Coast of Pakistan by using surplus production models

Pakistani marine waters are under an open access regime.Due to poor management and policy implications,blind fishing is continued which may result in ecological as well as economic losses.Thus,it is of utmost importance to estimate fishery resources before harvesting.In this study,catch and effort data,1996-2009,of Kiddi shrimp Parapenaeopsis stylifera fishery from Pakistani marine waters was analyzed by using specialized fishery software in order to know fishery stock status of this commercially important shrimp.Maximum,minimum and average capture production of P.stylifera was observed as 15 912 metric tons(mt)(1997),9 438 mt(2009) and 11 667 mt/a.Two stock assessment tools viz.CEDA(catch and effort data analysis) and ASPIC(a stock production model incorporating covariates) were used to compute MSY(maximum sustainable yield) of this organism.In CEDA,three surplus production models,Fox,Schaefer and Pella-Tomlinson,along with three error assumptions,log,log normal and gamma,were used.For initial proportion(IP) 0.8,the Fox model computed MSY as 6 858 mt(CV=0.204,R~2=0.709) and 7 384 mt(CV=0.149,R~2=0.72) for log and log normal error assumption respectively.Here,gamma error produced minimization failure.Estimated MSY by using Schaefer and Pella-Tomlinson models remained the same for log,log normal and gamma error assumptions i.e.7 083 mt,8 209 mt and 7 242 mt correspondingly.The Schafer results showed highest goodness of fit R~2(0.712) values.ASPIC computed MSY,CV,R~2,F_(MSY)and B_(MSY) parameters for the Fox model as 7 219 mt,0.142,0.872,0.111 and 65 280,while for the Logistic model the computed values remained 7 720 mt,0.148,0.868,0.107 and 72 110 correspondingly.Results obtained have shown that P.stylifera has been overexploited.Immediate steps are needed to conserve this fishery resource for the future and research on other species of commercial importance is urgently needed.     

Paleomagnetic evidence for post-Cretaceous internal deformation of the Chuan Dian Fragment in the Yangtze block: a consequence of indentation of India into Asia

Paleomagnetic samples of Paleocene–Eocene red sandstones were collected at 36 sites from the Jiangdihe-4 and Zhaojiadian formations around the Yongren (26.1°N, 101.7°E) and Dayao areas (25.7°N, 101.3°E). These areas are located in the Chuxiong basin of the Chuan Dian Fragment, southwestern part of the Yangtze block. After stepwise thermal demagnetization, a high-temperature component with unblocking temperature of about 680 °C is isolated from 26 sites. The primary nature of this magnetization is ascertained through positive fold and reversal tests at 95% confidence level. The tilt-corrected mean paleomagnetic directions for the Yongren and Dayao areas are D=17.2°, I=26.6° with α₉₅=5.8° and D=16.5°, I=31.1° with α₉₅=4.8, respectively. Easterly deflected declinations from this study are consistent with those reported from other areas of the Chuxiong basin, indicating its wide presence in the Cretaceous–Eocene formations of the said basin. Comparison with declination values expected from the Cretaceous–Eocene APWP of Eurasia indicates that the magnitude of clockwise rotation systematically increases toward the southeast within the Chuxiong basin as well as in the Chuan Dian Fragment. This trend of the differential tectonic rotation in the Chuan Dian Fragment is consistent with curvature of the Xianshuihe–Xiojiang fault system. Deformation of the Chuxiong basin can fairly be associated with the formation of eastward bulge in the southern part of the Chuan Dian fragment. During southward displacement, the Chuan Dian Fragment was probably subjected to tectonic stresses as a result interaction with the Yangtze and Indochina blocks, which resulted into east–west extension and north–south shortening.