11 million years of Oligocene geomagnetic field behaviour

An 11 million year long record of the Oligocene geomagnetic field has been obtained from pelagic sediments of DSDP Hole 522 An average sample spacing of 4 cm yielded approximately one specimen per 4 to 8 kyr. The rock magnetics are remarkabh consistent across the entire interval. Previous work demonstrated a magnetic mineralogy dominated by magnetically stable magnetite. The natural remanent magnetism (NRM) carries an Oligocene polarity timescale that is in excellent agreement with the Oligocene reversal record as determined from marine magnetic anomalies (MMAs), including many of the so-called 'crypto-chrons'. Normalized NRM intensities from the undisturbed portions of the record yield a time series of variations with features consistent with a number of other palaeointensity time series derived from both sedimentary and lava sequences. These features include consistent, major decreases in palaeointensity (DIPs) at reversal boundaries, and occasional DIPs between reversal boundaries that could correspond to lineated 'tiny wiggles' in the MMA records. The data set suggests that the overall field strength was 40 per cent higher in the first half of the Oligocene when the average reversal frequency was 1.6 Myr^-1 than in the second half when the reversal frequency was 4 Myr^-1. There is also a weak dependence of average field strength on length of polarity interval. Finally, in the three cores suited to spectral analysis (of coherent polarity and relative intensity independent of lithological contamination), there is a persistent ca. 30–50ka periodicity in the variations of the relative intensity, suggesting that the geomagnetic field 'pulses' at about this frequency, not only during the Brunhes (as demonstrated by Tauxe & Shackleton 1994), but in the Oligocene as well.     

Large-Eddy Simulation of Turbulent Flow Over a Rough Surface

A family of wall models is proposed that exhibits moresatisfactory performance than previousmodels for the large-eddy simulation (LES) of the turbulentboundary layer over a rough surface.The time and horizontally averaged statistics such asmean vertical profiles of windvelocity, Reynolds stress, turbulent intensities, turbulentkinetic energy and alsospectra are compared with wind-tunnel experimental data.The purpose of the present study is to obtain simulatedturbulent flows that are comparable with wind-tunnelmeasurements for use as the wind environment for thenumerical prediction by LES of source dispersion in theneutral atmospheric boundary layer.     

Fresh snow chemistry from high mountain regions in central himalayas

Investigations of atmospheric composition in the Himalayas has been limited in both temporal and spatial scales, mainly due to difficult logistics. Ideal sites for monitoring atmospheric composition and its evolution should be free from local pollution and representative of the remote troposphere (HUEBERT et al., 1980). As the Himalayas are far removed from highly industrialized regions they provide suitable locations to monitor the chemistry of the remote troposphere and to study the evolu…     

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.