Evaluation of ferrous and ferric Mössbauer fractions

The Mössbauer fractions f for various ferrous- and/or ferric-containing oxides and oxyhydroxides, silicates and carbonates were evaluated from the experimental temperature dependence of their center shifts, using the Debye approximation for the second-order Doppler shift. It is concluded that ferrous ions exhibit a lower fraction as compared to ferric ions. Using standard mixtures of -Fe₂O₃ with selected Fe²⁺ or Fe³⁺ compounds, it is found that the calculated Fe³⁺ f values are somewhat overestimated with respect to those of Fe²⁺. Possible explanations for this shortcoming are discussed and it is suggested that a different temperature dependence of the intrinsic isomer shift is the most likely reason. This suggestion is corroborated by analyses of hematite and hedenbergite data which are available for temperatures up to 900 K and 800 K respectively.     

Sunspot nests

For the period August 1959–December 1964 the Greenwich Photoheliographic Results were searched for sunspot nests. Such a nest is a sequence of sunspot groups that appear within a small area on the solar surface and that last for several months. The search procedure is described and data for 41 probable sunspot nests are given. At least three quarters of these nests appear to be real, and not chance clusters.The nests are the same type of activity sequences as the Fleckenherde discovered by Becker (1955) and the complexes of activity pointed out by Gaizauskas et al. (1983). The complexes of activity as defined by Bumba and Howard (1965) are different patterns, however; the relation between complexes and the nests is shown.Some properties of the nests are: (i) many nests appear as double structures; (ii) single nests and components of double nests are quite compact: the effective areas are comparable to those of medium-large sunspot groups; (iii) each nest rotates at its own steady rate about the Sun; (iv) the intrinsic scatter in the rotation rates is much larger than the trend in the differential rotation; (v) displacements in latitude are less than a few meters per second; (vi) many nests live for 6 to 15 Carrington rotation periods, the minimum lifetime is not yet determined; (vii) the fraction of the sunspot groups that are members of nests is large (at least 30%).     

Accuracy of close binary mass determinations from parallaxes

Absolute masses for W Ursae Majoris and Algol-type close binaries can be determined from their parallax, if observed, and the relative sizes of the stars and their mass ratio, obtained from a light curve solution. An error propagation study compares the typical order of magnitude of the various terms involved, and shows how accurate parallaxes have to be in order to make the procedure work, i.e., making the parallax term not larger than the combined non-parallax terms, and producing reasonably low mass errors. Some comments are made on the possibilities with respect to the HIPPARCOS program.Communication presented at the International Conference on Astrometric Binaries, held on 13–15 June, 1984, at the Remeis-Sternwarte Bamberg, Germany, to commemorate the 200th anniversary of the birth of Friedrich Wilhelm Bessel (1784–1846).     

Emission features in the solar corona after the perihelion passage of Comet 1979 XI

On the coronograph spectrophotographic records taken on 31.372 UT, August 1979, some faint emission features were found which can be ascribed to Siii and Niii. These emissions were obviously a transient phenomena which were detected only 10 hr after the supposed fall of Comet 1979 XI in the Sun's photosphere. It cannot be excluded that the appearance of Si and Ni lines was triggered by the evaporation of dust particles with a high abundance of heavier elements in the solar corona. This assumption is also supported by intensity distribution of the Fex coronal line around the Sun's limb. The maximum coincide with the position angle of the projected path of the comet.     

A dynamo theory of solar flares

It is proposed that the solar flare phenomenon can be understood as a manifestation of the electrodynamic coupling process of the photosphere-chromosphere-corona system as a whole. The system is coupled by electric currents, flowing along (both upward and downward) and across the magnetic field lines, powered by the dynamo process driven by the neutral wind in the photosphere and the lower chromosphere. A self-consistent formulation of the proposed coupling system is given. It is shown in particular that the coupling system can generate and dissipate the power of 10²⁹ erg s^#X2212;1 and the total energy of 10³² erg during a typical life time (10³ s) of solar flares. The energy consumptions include Joule heat production, acceleration of current-carrying particles along field lines, magnetic energy storage and kinetic energy of plasma convection. The particle acceleration arises from the development of field-aligned potential drops of 10–150 kV due to the loss-cone constriction effect along the upward field-aligned currents, causing optical, X-ray and radio emissions. The total number of precipitating electrons during a flare is shown to be of order 10³⁷–10³⁸.     

Extensional Late Paleozoic deformation on the western margin of Pangea, Patlanoaya area, Acatlán Complex, southern Mexico

New mapping in the northern part of the Paleozoic Acatlán Complex (Patlanoaya area) records several ductile shear zones and brittle faults with normal kinematics (previously thought to be thrusts). These movement zones separate a variety of units that pass structurally upwards from: (i) blueschist-eclogitic metamorphic rocks (Piaxtla Suite) and mylonitic megacrystic granites (Columpio del Diablo granite ≡ Ordovician granites elsewhere in the complex); (ii) a gently E-dipping, listric, normal shear zone with top to the east kinematic indicators that formed under upper greenschist to lower amphibolite conditions; (iii) the Middle–Late Ordovician Las Minas quartzite (upper greenschist facies psammites with minor interbedded pelites intruded by mafic dikes and a leucogranite dike from the Columpio del Diablo granite) unconformably overlain by the Otate meta-arenite (lower greenschist facies psammites and pelites): roughly temporal equivalents are the Middle–Late Ordovician Mal Paso and Ojo de Agua units (interbedded metasandstone and slate, and metapelite and mafic minor intrusions, respectively) — some of these units are intruded by the massive, 461 ± 2 Ma, Palo Liso megacrystic granite: decussate, contact metamorphic muscovite yielded a ⁴⁰Ar/³⁹Ar plateau age of 440 ± 4 Ma; (iv) a steeply-moderately, E-dipping normal fault; (v) latest Devonian–Middle Permian sedimentary rocks (Patlanoaya Group: here elevated from formation status). The upward decrease in metamorphic grade is paralleled by a decrease in the number of penetrative fabrics, which varies from (i) three in the Piaxtla Suite, through (ii) two in the Las Minas unit (E-trending sheath folds deformed by NE-trending, subhorizontal folds with top to the southeast asymmetry, both associated with a solution cleavage), (iii) one in the Otate, Mal Paso, and Ojo de Agua units (steeply SE-dipping, NE–SW plunging, open-close folds), to (iv) none in the Patlanoaya Group. ⁴⁰Ar/³⁹Ar analyses of muscovite from the earliest cleavage in the Las Minas unit yielded a plateau age of 347 ± 3 Ma and show low temperature ages of  260 Ma. Post-dating all of these structures and the Patlanoaya Group are NE-plunging, subvertical folds and kink bands. An E–W, vertical normal fault juxtaposes the low-grade rocks against the Anacahuite amphibolite that is cut by megacrystic granite sheets, both of which were deformed by two penetrative fabrics. Amphibole from this unit has yielded a ⁴⁰Ar/³⁹Ar plateau age of 299 ± 6 Ma, which records cooling through  490 °C and is probably related to a Permo-Carboniferous reheating event during exhumation. The extensional deformation is inferred to have started in the latest Devonian ( 360 Ma) during deposition of the basal Patlanoaya Group, lasting through the rapid exhumation of the Piaxtla Suite at  350–340 Ma synchronous with cleavage development in the Las Minas unit, deposition of the Patlanoaya Group with active fault-related exhumation suggested by Mississippian and Early Permian conglomerates ( 340 and 300 Ma, respectively), and continuing at least into the Middle Permian (≡ 260 Ma muscovite ages). The continuity of Mid-Continent Mississippian fauna from the USA to southern Mexico suggests that this extensional deformation occurred on the western margin of Pangea after closure of the Rheic Ocean.     

He–Ar and Nd–Sr isotopic compositions of late Pleistocene felsic plutonic back arc basin rocks from Ulleungdo volcanic island, South Korea: Implications for the genesis of young plutonic rocks in a back arc basin

We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. ⁴⁰Ar/³⁹Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K₂O + Na₂O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (⁸⁷Sr/⁸⁶Sr = 0.70454–0.71264, ¹⁴³Nd/¹⁴⁴Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (⁸⁷Sr/⁸⁶Sr = 0.70466–0.70892, ¹⁴³Nd/¹⁴⁴Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial ⁸⁷Sr/⁸⁶Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (³He/⁴He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.     

Chemical weathering of carbonates and silicates in the Han River basin,South Korea

A detailed investigation of the fluvial geochemistry of the Han River system allows to estimate the rates of chemical weathering and the consumption of CO₂. The Han River drains approximately 26,000 km² and is the largest river system in South Korea in terms of both water discharge and total river length. It consists of two major tributaries: the North Han River (NHR) and the South Han River (SHR). Distinct differences in basin lithology (silicate vs. carbonate) between the NHR and SHR provide a good natural laboratory in which to examine weathering processes and the influence of basin geology on water quality. The concentrations of major elements and the Sr isotopic compositions were obtained from 58 samples collected in both summer and winter along the Han River system in both 2000 and 2006. The concentrations of dissolved loads differed considerably between the NHR and SHR; compared with the SHR, the NHR had much lower total dissolved solids (TDS), Sr, and major ion concentrations but a higher Si concentration and ⁸⁷Sr/⁸⁶Sr ratio. A forward model showed that the dissolved loads in the NHR came primarily from silicate weathering (55 ± 11%), with a relatively small portion from carbonates (30 ± 14%), whereas the main contribution to the dissolved loads in the SHR was carbonate weathering (82 ± 3%), with only 11 ± 4% from silicates. These results are consistent with the different lithologies of the two drainage basins: silicate rocks in the NHR versus carbonate rocks in the SHR. Sulfuric acid derived from sulfide dissolution in coal-containing sedimentary strata has played an important role in carbonate weathering in the SHR basin, unlike in the NHR basin. The silicate weathering rate (SWR) was similar between the NHR and SHR basins, but the rate of CO₂ consumption in the SHR basin was lower than in the NHR basin due to an important role of sulfuric acid derived from pyrite oxidation.     

Using ALSM to map sinkholes in the urbanized covered karst of Pinellas County,Florida—1, methodological considerations

Comparison of a database of interpreted sinkholes made using airborne laser swath mapping (ALSM) with databases of sinkholes made from interpretation of aerial photographs reveals substantial disagreement. The discrepancies involve the location, number, areas, and circularity of interpreted sinkholes. Methodological factors that contribute to the discrepancies include blockage of ALSM laser returns in thick vegetation, multi-path reflections, and misrepresentation of the true extent of sinkholes. Comparison of two ALSM-derived databases made (1) independently from versus (2) in combination with earlier air photo analysis in undeveloped regions had the following result: one-fourth of the sinkholes interpreted by using the composite method were missed by the independent analysis, and one-third of the sinkholes that were interpreted from the independent analysis were not interpreted as sinkholes using the composite method. Subjective interpretation leads to a high level of uncertainty such that the results of the remote sensing studies are suspect, if not invalid.     

Estimation of groundwater recharge using the soil moisture budget method and the base-flow model

A detailed characterization of the site is crucial to designing an efficient method of managing the risks associated with tailings from abandoned mines. Therefore, samples collected from various depths within tailings in Guryong mine, Korea, were analyzed for their chemical, physical and mineralogical characteristics. All samples of the Guryong tailings had acid-generating potential. However, in the oxidation zone, the net acid generation (NAG) was low (30 kg H₂SO₄ t⁻¹) although the acid neutralization potential (ANP) was less than zero. The ANP values in the unoxidation zone were higher (> −56.0 kg CaCO₃ t⁻¹) than in the other zones. As a result, the amount of alkali ions that are needed to neutralize the acid needs to be considered. In this experiment G3, G4 and G6 drill cores containing fine tailings particles near the unoxidation zone were observed to contain calcite (CaCO₃) with acid-neutralizing capacity. A low pH (2−4) in the oxidation zone of the tailings changed to a neutral pH in the unoxidation zone of the tailings. These results suggest that the acid-neutralizing capacity of the tailings was controlled by particle and mineral composition of tailings.