Nonequilibrium thermodynamics of pressure solution

This paper is concerned with the thermodynamic theory of solution and precipitation processes in wet crustal rocks and with the mechanism of steady pressure-solution slip in contact zones, such as grain-to-grain contacts, fracture surfaces, and permeable gouge layers, that are infiltrated by a mobile aqueous solution phase. A local dissipation jump condition at the phase boundary is fundamental to identifying the thermodynamic force driving the solution and precipitation process and is used here in setting up linear phenomenological relations to model near-equilibrium phase transformation kinetics. The local thermodynamic equilibrium of a stressed pure solid in contact with its melt or solution phase is governed by Gibbs's relation, which is rederived here, in a manner emphasizing its independence of constitutive assumptions for the solid while neglecting surface tension and diffusion in the solid. Fluid-infiltrated contact zones, such as those formed by rough surfaces, cannot generally be in thermodynamic equilibrium, especially during an ongoing process of pressure-solution slip, and the existing equilibrium formulations are incorrect in overlooking dissipative processes tending to eliminate fluctuations in superficial free energies due to stress concentrations near asperities, defects, or impurities. Steady pressure-solution slip is likely to exhibit a nonlinear dependence of slip rate on shear stress and effective normal stress, due to a dependence of the contact-zone state on the latter. Given that this dependence is negligible within some range, linear relations for pressure-solution slip can be derived for the limiting cases of diffusion-controlled and interface-reaction-controlled rates. A criterion for rate control by one of these mechanisms is set by the magnitude of the dimensionless quantityk/2C _pD, wherek is the interfacial transfer coefficient, is the mean diffusion path length,C _p is the solubility at pressurep, andD is the mass diffusivity.     

Synergy and fusion of optical and synthetic aperture radar satellite data for underwater topography estimation in coastal areas

A method to obtain underwater topography for coastal areas using state-of-the-art remote sensing data and techniques worldwide is presented. The data from the new Synthetic Aperture Radar (SAR) satellite TerraSAR-X with high resolution up to 1 m are used to render the ocean waves. As bathymetry is reflected by long swell wave refraction governed by underwater structures in shallow areas, it can be derived using the dispersion relation from observed swell properties. To complete the bathymetric maps, optical satellite data of the QuickBird satellite are fused to map extreme shallow waters, e.g., in near-coast areas. The algorithms for bathymetry estimation from optical and SAR data are combined and integrated in order to cover different depth domains. Both techniques make use of different physical phenomena and mathematical treatment. The optical methods based on sunlight reflection analysis provide depths in shallow water up to 20 m in preferably calm weather conditions. The depth estimation from SAR is based on the observation of long waves and covers the areas between about 70- and 10-m water depths depending on sea state and acquisition quality. The depths in the range of 20 m up to 10 m represent the domain where the synergy of data from both sources arises. Thus, the results derived from SAR and optical sensors complement each other. In this study, a bathymetry map near Rottnest Island, Australia, is derived. QuickBird satellite optical data and radar data from TerraSAR-X have been used. The depths estimated are aligned on two different grids. The first one is a uniform rectangular mesh with a horizontal resolution of 150 m, which corresponds to an average swell wavelength observed in the 10 × 10-km SAR image acquired. The second mesh has a resolution of 150 m for depths up to 20 m (deeper domain covered by SAR-based technique) and 2.4 m resolution for the shallow domain imaged by an optical sensor. This new technique provides a platform for mapping of coastal bathymetry over a broad area on a scale that is relevant to marine planners, managers, and offshore industry.     

Evidence of polycyclic aromatic hydrocarbon (PAH) exposure in fish from the Antarctic peninsula

PAH exposure was assessed in fish from Arthur Harbor, Antarctica and sites remote from human activities by measuring the concentrations of polycyclic aromatic hydrocarbon (PAH) metabolites in bile and PAH in tissues and stomach contents. The highest concentrations of biliary metabolites and tissue PAH were present in fish captured near an Argentine supply ship (Bahia Paraiso) that ran aground in Arthur Harbor in 1989. The presence of biliary PAH metabolites in fish collected near Palmer Station, a small US scientific station in Arthur Harbor, suggests low level exposure to contaminants. However, PAH tissue concentrations in fish from Palmer Station were similar to those from remote sites. Both tissue PAH and metabolite concentrations were low in fish captured at sites remote from human activities. The confirmation of PAH metabolites in the bile of fish from Arthur Harbor is direct evidence that the presence of humans has resulted in Antarctic fish being exposed to petroleum-derived PAH.     

Comparison of polar mesospheric cloud measurements from the Cloud Imaging and Particle Size experiment and the solar backscatter ultraviolet instrument in 2007

We compare measurements from the Aeronomy of Ice in the Mesosphere (AIM) Cloud Imaging and Particle Size (CIPS) experiment to the NOAA-17 solar backscatter ultraviolet (SBUV/2) instrument during the 2007 Northern Hemisphere polar mesospheric cloud (PMC) season. Daily average Rayleigh scattering albedos determined from identical footprints from the CIPS nadir camera and SBUV/2 agree to better than ～5% throughout the season. Average PMC brightness values derived from the two instruments agree to within ±10%. PMC occurrence frequencies are on average ～5% to nearly a factor of two higher in CIPS, depending on latitude. Agreement is best at high latitudes where clouds are brighter and more frequent. The comparisons indicate that AIM CIPS data are valid for scientific analyses. They also show that CIPS measurements can be linked to the long time series of SBUV/2 data to investigate long-term variability in PMCs.     

Topography and morphodynamics in the German Bight using SAR and optical remote sensing data

Morphological changes in coastal areas, especially in river estuaries, are of high interest in many parts of the world. Satellite data from both optical and radar sensors can help to monitor and investigate these changes. Data from both kinds of sensors being available for up to 30 years now, allow examinations over large timescales, while high resolution sensors developed within the last decade allow increased accuracy. So the creation of digital elevation models (DEMs) of, for example, the wadden sea from a series of satellite images is already possible. ENVISAT, successfully launched on March 1, 2002, continues the line of higher resolution synthetic aperture radar (SAR) imaging sensors with its ASAR instrument and now also allows several polarization modes for better separation of land and water areas. This article gives an overview of sensors and algorithms for waterline determination as well as several applications. Both optical and SAR images are considered. Applications include morphodynamic monitoring studies and DEM generation.

HST/STIS observations of the high-velocity interstellar cloud HVC 291.2−41.2+80: a warm, mainly ionized high-velocity cloud

We present intermediate-resolution HST /STIS spectra of a high-velocity interstellar cloud ( v _LSR=+80 km s⁻¹) towards DI 1388, a young star in the Magellanic Bridge located between the Small and Large Magellanic Clouds. The STIS data have a signal-to-noise ratio (S/N) of 20–45 and a spectral resolution of about 6.5 km s⁻¹ (FWHM). The high-velocity cloud absorption is observed in the lines of C  ii , O  i , Si  ii , Si  iii , Si  iv and S  iii . Limits can be placed on the amount of S  ii and Fe  ii absorption that is present. An analysis of the relative abundances derived from the observed species, particularly C  ii and O  i , suggests that this high-velocity gas is warm ( T _k∼10³–10⁴ K) and predominantly ionized. This hypothesis is supported by the presence of absorption produced by highly ionized species, such as Si  iv . This sightline also intercepts two other high-velocity clouds that produce weak absorption features at v _LSR=+113 and +130 km s⁻¹ in the STIS spectra.     

Scales of perception: public awareness of regional and neighborhood climates

Understanding public perceptions of climate is critical for developing an effective strategy to mitigate the effects of human activity on the natural environment and reduce human vulnerability to the impacts of climate change. While recent climate assessments document change among various physical systems (e.g., increased temperature, sea level rise, shrinking glaciers), environmental perceptions are relatively under-researched despite the fact that there is growing skepticism and disconnect between climate science and public opinion. This study utilizes a socio-ecological research framework to investigate how public perceptions compared with environmental conditions in one urban center. Specifically, air temperature during an extreme heat event was examined as one characteristic of environmental conditions by relating simulations from the Weather Research and Forecast (WRF) atmospheric model with self-reported perceptions of regional and neighborhood temperatures from a social survey of Phoenix, AZ (USA) metropolitan area residents. Results indicate that: 1) human exposure to high temperatures varies substantially throughout metropolitan Phoenix; 2) public perceptions of temperature are more strongly correlated with proximate environmental conditions than with distal conditions; and 3) perceptions of temperature are related to social characteristics and situational variables. The social constructionist paradigm explains public perceptions at the regional scale, while experience governs attitude formation at the neighborhood scale.     

Impaired osmoregulation in the shrimp Palaemon adspersus exposed to crude oil extract

Palaemon adspersus is a hyper- and hypo-osmoregulating shallow-water shrimp. For a maximum period of 34 days P. adspersus were exposed to 20, 70, 100 and 200 ppb WSF of North Sea crude oil. The osmotic concentration of the haemolymph was measured by freezing point depression once a week. The ability to maintain hyper-osmolality was significantly decreased (p<0.05) after one, two and three weeks exposure to 200, 70 and 100 ppb, respectively. No effect was observed in 20 ppb. After an accidental exposure of shrimps to 24 h acute oil pollution, they were placed in pure sea water. The ability to maintain hyper-osmolality was reduced one week after the accidental oil exposure, but was regained within three weeks.     

Storm observations by remote sensing and influences of gustiness on ocean waves and on generation of rogue waves

The impact of the gustiness on surface waves under storm conditions is investigated with focus on the appearance of wave groups with extreme high amplitude and wavelength in the North Sea. During many storms characterized by extremely high individual waves measured near the German coast, especially in cold air outbreaks, the moving atmospheric open cells are observed by optical and radar satellites. According to measurements, the footprint of the cell produces a local increase in the wind field at sea surface, moving as a consistent system with a propagation speed near to swell wave-traveling speed. The optical and microwave satellite data are used to connect mesoscale atmospheric turbulences and the extreme waves measured. The parameters of open cells observed are used for numerical spectral wave modeling. The North Sea with horizontal resolution of 2.5?km and with focus on the German Bight was simulated. The wind field “storm in storm,” including moving organized mesoscale eddies with increased wind speed, was generated. To take into account the rapid moving gust structure, the input wind field was updated each 5?min. The test cases idealized with one, two, and four open individual cells and, respectively, with groups of open cells, with and without preexisting sea state, as well the real storm conditions, are simulated. The model results confirm that an individual-moving open cell can cause the local significant wave height increase in order of meters within the cell area and especially in a narrow area of 1–2?km at the footprint center of a cell (the cell's diameter is 40–90?km). In a case of a traveling individual open cell with 15?m·s^?1 over a sea surface with a preexisting wind sea of and swell, a local significant wave height increase of 3.5?m is produced. A group of cells for a real storm condition produces a local increase of significant wave height of more than 6?m during a short time window of 10–20?min (cell passing). The sea surface simulation from modeled wave spectra points out the appearance of wave groups including extreme individual waves with a period of about 25?s and a wavelength of more than 350?m under the cell's footprint. This corresponds well with measurement of a rogue wave group with length of about 400?m and a period of near 25?s. This has been registered at FiNO-1 research platform in the North Sea during Britta storm on November 1, 2006 at 04:00 UTC. The results can explain the appearance of rogue waves in the German Bight and can be used for ship safety and coastal protection. Presently, the considered mesoscale gustiness cannot be incorporated in present operational wave forecasting systems, since it needs an update of the wind field at spatial and temporal scales, which is still not available for such applications. However, the scenario simulations for cell structures with appropriate travel speed, observed by optical and radar satellites, can be done and applied for warning messages.