Aqueous alteration affecting the irregular outer planets satellites: Evidence from spectral reflectance

The surface reflectance properties of the irregular outer planets satellites are probed for evidence for the presence of aqueous alteration products on their surfaces using the strong correlation between the 3.0-μm water of hydration absorption feature and the 0.7-μm Fe²⁺ → Fe³⁺ oxidized iron feature seen in low-albedo asteroid reflectances, in an effort to expand our understanding of the composition of the precursor bodies from which the dynamical satellite clusters are derived. Equations converting Johnson V and Kron-Cousins RI photometry to Eight Color Asteroid Survey v (0.550 μm), w (0.701 μm), and x (0.853 μm) photometry are derived from relationships defined by Howell (1995, Ph.D. thesis), and coupled with an algorithm previously defined to detect the presence of the 0.7-μm absorption feature in ECAS asteroid photometry [Vilas, F., 1994. Icarus 111, 456-467]. Broadband VRI photometry of Ch-class Asteroid 19 Fortuna acquired during 2004 confirms the efficacy of this method of identifying the presence of the 0.7-μm feature. Photometric observations of many recently discovered irregular outer jovian, saturnian, uranian, and neptunian satellites, coupled with limited asteroid spectroscopy, were examined for the presence of aqueous alteration. The dynamical clusters of outer irregular jovian satellites are mixed between objects that do and do not show this absorption feature. Multiple observations of some objects test both positively and negatively, similar to the surface variegation that has been observed among many C-class asteroids in the main asteroid belt. Evidence for aqueous alteration on these jovian satellites augers for an origin in or near the same location as the asteroids now occupying the aqueous alteration zone (2.6-3.5 AU), at heliocentric distances internal to Jupiter's orbit. Among the saturnian irregular satellites, only S IX Phoebe shows limited evidence of aqueous alteration from ground-based observations. The other satellites show no sign of this feature, and have general reflectance properties very similar to the D-class asteroids, supporting an origin for their precursor bodies in the outer Solar System, perhaps the Centaur region. Only two uranian satellites were tested: U XVII Caliban tests positively for the feature. The differences in surface reflectance properties support the idea that Caliban and U XVI Sycorax derive from separate parent bodies. One observation of neptunian satellite N II Nereid shows no sign of this absorption feature.     

Using geochemistry as a tool for correlating proximal andesitic tephra: case studies from Mt Rainier (USA) and Mt Ruapehu (New Zealand)

Volcanic hazards assessments at andesite stratovolcanoes rely on the assessment of frequency and magnitude of past events. The identification and correlation of proximal and distal andesitic tephra, which record the explosive eruptive history, are integral to such assessments. These tephra are potentially valuable stratigraphic marker beds useful to the temporal correlation and age dating of Quaternary volcanic, volcaniclastic and epiclastic sedimentary deposits with which they are interbedded. At Mt Ruapehu (New Zealand) and Mt Rainier (USA), much of the detail of the recent volcanic record remains unresolved because of the difficulty in identifying proximal tephra. This study investigates the value of geochemical methods in discriminating andesitic tephra. Our dataset comprises petrological and geochemical analyses of tephra that span the late Quaternary eruptive record of each volcano. Our data illustrate that andesitic tephra are remarkably heterogeneous in composition. Tephra compositions fluctuate widely over short time intervals, and there are no simple or systematic temporal trends in geochemistry within either eruptive record. This complexity in tephra geochemistry limits the application of geochemical approaches to tephrostratigraphic studies, beyond a general characterisation useful to provenance assignation. Petrological and geochemical data suggest that the products of andesite systems are inherently variable and therefore intractable to discrimination by simple geochemical methods alone. Copyright © 2006 John Wiley & Sons, Ltd.     

The H i opacity of the intergalactic medium at redshifts 1.6 < z < 3.2

We use high-quality echelle spectra of 24 quasi-stellar objects to provide a calibrated measurement of the total amount of Lyα forest absorption (DA) over the redshift range  2.2 < z < 3.2  . Our measurement of DA excludes absorption from metal lines or the Lyα lines of Lyman-limit systems and damped Lyα systems. We use artificial spectra with realistic flux calibration errors to show that we are able to place continuum levels that are accurate to better than 1 per cent. When we combine our results with our previous results between  1.6 < z < 2.2  , we find that the redshift evolution of DA is well described over  1.6 < z < 3.2  as   A (1 + z )^γ  , where   A = 0.0062  and  γ= 2.75  . We detect no significant deviations from a smooth power-law evolution over the redshift range studied. We find less H  i absorption than expected at   z = 3  , implying that the ultraviolet background is  ∼40  per cent higher than expected. Our data appears to be consistent with an H  i ionization rate of  Γ∼ 1.4 × 10⁻¹² s⁻¹  .     

Red spruce canopy response to acid fog exposure

The health of red spruce is adversely affected by exposure to acid fog. Epicuticular wax structure over epistomatal chambers, mesophyll membrane calcium and changes in redox state of glutathione are affected in both chamber and field studies and are correlated with leaf exposure to acid fog, but not with soil or total leaf calcium concentrations. Experiments tracking fog deposition under conditions of illumination or darkness, with or without a metabolic inhibitor, support the mechanism of diffusiophoresis linked with photosynthetic gas exchange. Based on deposition pattern and leaf morphology, a stomatal pathway for water and hydrogen ion penetration to leaf interior is proposed. Ecophysiological parameters are discussed in relation to differential sensitivities of red spruce and white pine to ozone and acid fog.     

Influence of Physical Manipulations on Short-Term Salt Marsh Morphodynamics: Examples from the North and Mid-Atlantic Coast,USA

Along the mid- and north Atlantic coasts of the USA, over 90 % of salt marshes have been ditched. Ditching was largely abandoned by the mid-twentieth century; however, techniques that create permanent shallow water pools for mosquito control and bird habitat are increasingly being applied to marshes of the USA and elsewhere. Salt marshes in Plum Island Sound, Massachusetts, and Barnegat Bay, New Jersey, were used to examine differences between areas that have been ditched and those altered to increase the density of shallow pools in water table dynamics, salinity, soil and porewater chemistry, as well as short-term sedimentation, accretion, and elevation change rates. We found that the area with plugged ditches, berms, and pools in Plum Island had less drainage, higher salinity and porewater sulfide and ammonium concentrations, and higher soil organic matter than the adjacent ditched area. Despite averaging 8 cm lower in elevation, the Plum Island ditched area had less sediment deposition and was composed of higher elevation plant species than the area with plugged ditches, berms, and shallow pools. Elevation increased in the ditched area at a rate of 3.2 ± 0.5 mm/year, but elevation change was variable in the area with pools. In Barnegat Bay, the marsh area with pools and ditches had less sediment deposition and surface accretion than the ditch-only area, associated, in part, with the higher elevation. An average elevation difference of 4.5 cm was associated with a sixfold difference in mineral sediment deposition. Temporal sediment deposition and surface accretion was important in the ditch-only area but was absent or muted in the area with numerous pools. Elevation increased in both marsh areas at an average rate of 1.8 ± 0.8 mm/year, less than half the long-term average local rate of sea-level rise. Our results illustrate how physical manipulations including changes to tidal hydrology and surface topography interact with elevation to influence short-term biophysical feedbacks.     

The Effect of Submerged Aquatic Vegetation Expansion on a Declining Turbidity Trend in the Sacramento-San Joaquin River Delta

Submerged aquatic vegetation (SAV) has well-documented effects on water clarity. SAV beds can slow water movement and reduce bed shear stress, promoting sedimentation and reducing suspension. However, estuaries have multiple controls on turbidity that make it difficult to determine the effect of SAV on water clarity. In this study, we investigated the effect of primarily invasive SAV expansion on a concomitant decline in turbidity in the Sacramento-San Joaquin River Delta. The objective of this study was to separate the effects of decreasing sediment supply from the watershed from increasing SAV cover to determine the effect of SAV on the declining turbidity trend. SAV cover was determined by airborne hyperspectral remote sensing and turbidity data from long-term monitoring records. The turbidity trends were corrected for the declining sediment supply using suspended-sediment concentration data from a station immediately upstream of the Delta. We found a significant negative trend in turbidity from 1975 to 2008, and when we removed the sediment supply signal from the trend it was still significant and negative, indicating that a factor other than sediment supply was responsible for part of the turbidity decline. Turbidity monitoring stations with high rates of SAV expansion had steeper and more significant turbidity trends than those with low SAV cover. Our findings suggest that SAV is an important (but not sole) factor in the turbidity decline, and we estimate that 21–70 % of the total declining turbidity trend is due to SAV expansion.